Development of Chitosan/Glutaraldehyde Cross-Linked Film with Silica Addition as Membrane Material for SLS Rejection in Detergent Wastewater

Fivi Fatwa Illiana; Hermawan Dwi Ariyanto

doi:10.14710/jvsar.v6i1.22145

DOI: https://doi.org/10.14710/jvsar.v6i1.22145

Development of Chitosan/Glutaraldehyde Cross-Linked Film with Silica Addition as Membrane Material for SLS Rejection in Detergent Wastewater

*Fivi Fatwa Illiana - Department of Industrial Technology, Vocational School of Diponegoro University, Jalan Gurbenur Mochtar, Tembalang, Semarang, 50275, Indonesia, Indonesia

Hermawan Dwi Ariyanto - Department of Industrial Technology, Vocational School of Diponegoro University, Jalan Gurbenur Mochtar, Tembalang, Semarang, 50275, Indonesia, Indonesia

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Abstract

Abstract – The pollution resulting from domestic waste has increased with the growing population density, and one of the potential contributors to groundwater contamination is detergent waste. Sodium Lauryl Sulphate (SLS) serves as a common active ingredient in detergent formulations. By leveraging membrane technology, SLS can be processed to reduce its concentration in water to environmentally safe levels. Chitosan, a promising material for membrane composition, is considered as the base material. Exploiting the hydrophilic characteristics of chitosan, silica is introduced to enhance membrane selectivity by reducing pore size through cross-linking between chitosan and silica molecules. The performance of the silica-modified membrane is then evaluated through tests measuring the rejection coefficient against SLS, membrane swelling degree, morphological profiling of functional groups using FTIR, and tensile strength measured with a Universal Testing Machine. Subsequently, the membrane's efficiency in rejecting SLS in detergent waste is assessed based on rejection coefficients using an SLS solution model.

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Keywords: chitosan; detergent; membrane; silica; SLS

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In Volume 6, Issue 1, Year 2024 (April 2024)

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Hidayat, T., (2015), Sintesis Membran Kitosan – Peg (Polietilen Glikol) dan Aplikasinya Sebagai Adsorben Ion Cr6+ dan Ion Ni2+ dalam Larutan, Undergraduate Thesis, Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Semarang, Indonesia
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Thongngam, M., & McClements, D. J. (2005). Influence of pH, ionic strength, and temperature on self-association and interactions of sodium dodecyl sulfate in the absence and presence of chitosan. Langmuir, 21(1), 79–86. https://doi.org/10.1021/la048711o
Watkins, C. (2001). All eyes are on Texas. INFORM-CHAMPAIGN-, 12(12), 1152-1160
Yunarsih, N. M., Manurung, M., Gede, K., & Putra, D., (2013). Efektifitas Membran Khitosan dari Kulit Udang Galah (Macrobanchium rosenbergii) untuk Menurunkan Fosfat dalam Air Limbah Laundry. In Cakra Kimia (Indonesian E-Journal of Applied Chemistry), 2(1)
Zhang, W., Zhou, W., Zhang, Z., Zhang, D., Guo, Z., Ren, P., & Liu, F. (2023). Effect of Nano-Silica and Sorbitol on the Properties of Chitosan-Based Composite Films. Polymers, 15(19), 1–16. https://doi.org/10.3390/polym15194015
Zulti, F., Dahlan, K., & Sugita, P. (2012). Adsorption of Waste Metal Cr (VI) with Composite Membranes (Chitosan-Silica Rice Husks). Makara Journal of Science, 16(3), 163–168. https://doi.org/10.7454/mss.v16i3.1477/Makara

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