Development of Chitosan/Glutaraldehyde Cross-Linked Film with Silica Addition as Membrane Material for SLS Rejection in Detergent Wastewater

Fivi Fatwa Illiana; Hermawan Dwi Ariyanto

doi:10.14710/jvsar.v6i1.22145

DOI: https://doi.org/10.14710/jvsar.v6i1.22145

Development of Chitosan/Glutaraldehyde Cross-Linked Film with Silica Addition as Membrane Material for SLS Rejection in Detergent Wastewater

*Fivi Fatwa Illiana - Department of Industrial Technology, Vocational School of Diponegoro University, Jalan Gurbenur Mochtar, Tembalang, Semarang, 50275, Indonesia, Indonesia

Hermawan Dwi Ariyanto - Department of Industrial Technology, Vocational School of Diponegoro University, Jalan Gurbenur Mochtar, Tembalang, Semarang, 50275, Indonesia, Indonesia

Citation Format:

Abstract

Abstract – The pollution resulting from domestic waste has increased with the growing population density, and one of the potential contributors to groundwater contamination is detergent waste. Sodium Lauryl Sulphate (SLS) serves as a common active ingredient in detergent formulations. By leveraging membrane technology, SLS can be processed to reduce its concentration in water to environmentally safe levels. Chitosan, a promising material for membrane composition, is considered as the base material. Exploiting the hydrophilic characteristics of chitosan, silica is introduced to enhance membrane selectivity by reducing pore size through cross-linking between chitosan and silica molecules. The performance of the silica-modified membrane is then evaluated through tests measuring the rejection coefficient against SLS, membrane swelling degree, morphological profiling of functional groups using FTIR, and tensile strength measured with a Universal Testing Machine. Subsequently, the membrane's efficiency in rejecting SLS in detergent waste is assessed based on rejection coefficients using an SLS solution model.

Fulltext View|Download

Keywords: chitosan; detergent; membrane; silica; SLS

Article Metrics:

Article Info

Section: Articles

Language : EN

In Volume 6, Issue 1, Year 2024 (April 2024)

Recent articles

Effectiveness of Avocado Seed Extract on the Detergent Production Process Production of Analog Rice From Composite Flour : Mocaf, Corn, and Porang Flour Managing University Accreditation Documents with an Online-Based Data Collection System More recent articles

Alshahrani, A. A., Algamdi, M. S., Alsohaimi, I. H., Nghiem, L. D., Tu, K. L., Al-Rawajfeh, A. E., & in het Panhuis, M. (2020). The rejection of mono- and di-valent ions from aquatic environment by MWNT/chitosan buckypaper composite membranes: Influences of chitosan concentrations. Separation and Purification Technology, 234. https://doi.org/10.1016/j.seppur.2019.116088
Bokau, S., (2013), Sintesis Membran Kitosan Termodifikasi Silika Abu Sekam Padi untuk Proses Dekolorisasi, Undergraduate Thesis, Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Semarang, Indonesia
Bokau, N. S., Susatyo, E. B. and Alauhdin, M. (2014) Sintesis Membran Kitosan Termodifikasi Silika Abu Sekam Padi untuk Proses Dekolorisasi, Indonesian Journal of Chemical Science, 3(1)
Boricha, A. G., Murthy, Z. V. P., 2010, Preparation of N,O-carboxymethyl Chitosan/Cellulose Acetate Blend Nanofiltration Membrane and Testing Its Performance in Treating Industrial Wastewater, Chemical Enginering Journal. Sci, 157: 393–400
Ella Kusumastuti, Fadila Mauliani, F. Widhi Mahatmanti, Jumaeri1, Lukman Atmaja and Nurul Widiastuti, (2021), Characterization of Chitosan Membrane Modified with Silane-Coupled Nanosilica for Polymer Electrolyte, Intechopen, Available at: https://doi.org/10.5772/intechopen.95580
Erviana, D., Mariyamah, M., (2019). Perbandingan Daya Serap Membran Kitosan dan Membran Kitosan-Silika terhadap Penurunan Kadar Fosfat pada Limbah Detergen, Prosiding Seminar Nasional Sains dan Teknologi Terapan, 13(2), pp. 55-66
Fathanah, U., Machdar, I., Riza, M., Arahman, N., Lubis, M. R., & Yusuf, M. (2020). The Improvement of Hydrophilic Property of Polyethersulfone Membrane with Chitosan as Additive. Jurnal Rekayasa Kimia & Lingkungan, 15(1), 53–61. https://doi.org/10.23955/rkl.v15i1.15916
Hidayat, T., (2015), Sintesis Membran Kitosan – Peg (Polietilen Glikol) dan Aplikasinya Sebagai Adsorben Ion Cr6+ dan Ion Ni2+ dalam Larutan, Undergraduate Thesis, Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Semarang, Indonesia
Liu, Y. et al., (2019) Influence of nanosilica on inner structure and performance of chitosan-based films, Carbohydrate Polymers, 212(October 2018), pp. 421–429. Available at: https://doi.org/10.1016/j.carbpol.2019.02.079
Puji, S., (2012), Pembuatan dan Karakterisasi Membran Komposit Kitosan – Selulosa Diasetat – Tio2 Untuk Pengolahan Limbah, Undergraduate Thesis, Program Studi S-1 Kimia, Departemen Kimia, Fakultas Sains dan Teknologi, Universitas Airlangga, Indonesia
Ramachandran, S., Nandhakumar, S. and Dhanaraju, M.D., (2011), Formulation and characterization of glutaraldehyde cross-linked chitosan biodegradable microspheres loaded with famotidine, Tropical Journal of Pharmaceutical Research, 10(3), pp. 309–316. Available at: https://doi.org/10.4314/tjpr.v10i3.13
Spoială, A., Ilie, C. I., Ficai, D., Ficai, A., & Andronescu, E. (2021). Chitosan-based nanocomposite polymeric membranes for water purification—a review. In Materials (Vol. 14, Issue 9). MDPI AG. https://doi.org/10.3390/ma14092091
Sugiyo, W., Mahatmanti, F.W. and Alauhdin, M., (2011), Sintesis Komposit Kitosan-Silika dan Aplikasinya Sebagai Adsorben Zat Warna Tektil, Sainteknol, 1(9)
Thongngam, M., & McClements, D. J. (2005). Influence of pH, ionic strength, and temperature on self-association and interactions of sodium dodecyl sulfate in the absence and presence of chitosan. Langmuir, 21(1), 79–86. https://doi.org/10.1021/la048711o
Watkins, C. (2001). All eyes are on Texas. INFORM-CHAMPAIGN-, 12(12), 1152-1160
Yunarsih, N. M., Manurung, M., Gede, K., & Putra, D., (2013). Efektifitas Membran Khitosan dari Kulit Udang Galah (Macrobanchium rosenbergii) untuk Menurunkan Fosfat dalam Air Limbah Laundry. In Cakra Kimia (Indonesian E-Journal of Applied Chemistry), 2(1)
Zhang, W., Zhou, W., Zhang, Z., Zhang, D., Guo, Z., Ren, P., & Liu, F. (2023). Effect of Nano-Silica and Sorbitol on the Properties of Chitosan-Based Composite Films. Polymers, 15(19), 1–16. https://doi.org/10.3390/polym15194015
Zulti, F., Dahlan, K., & Sugita, P. (2012). Adsorption of Waste Metal Cr (VI) with Composite Membranes (Chitosan-Silica Rice Husks). Makara Journal of Science, 16(3), 163–168. https://doi.org/10.7454/mss.v16i3.1477/Makara

Last update:

No citation recorded.

Last update:

No citation recorded.

Journal of Vocational Studies on Applied Research are published under the terms of the Creative Commons Attribution-ShareAlike. Authors retain the copyright to their work. Users may read, copy and distribute the work in any medium provided the authors and the journal are appropriately credited.

Below you may find the full text of the license signed by authors.

LICENSE TO PUBLISH

1. License
The non-commercial use of the article will be governed by the Creative Commons Attribution-ShareAlike license as currently displayed on http://creativecommons.org/licenses/by-sa/4.0/. Without prejudice to the foregoing, the author hereby grants Journal of Vocational Studies on Applied Research the exclusive license for commercial use of the article according to section 2 below, and sections 4 through 9 below, throughout the world, in any form, in any language, for the full term of copyright, effective upon acceptance for publication.

2. Author’s Warranties
The author warrants that the article is original, written by stated author/s, has not been published before, contains no unlawful statements, does not infringe the rights of others, is subject to copyright that is vested exclusively in the author and free of any third party rights, and that any necessary written permissions to quote from other sources have been obtained by the author/s.

3. User Rights
Under the Creative Commons Attribution-ShareAlike license, the author(s) and users are free to share (copy, distribute and transmit the contribution).

4. Rights of Authors
Authors retain the following rights:

copyright, and other proprietary rights relating to the article, such as patent rights,
the right to use the substance of the article in future own works, including lectures and books,
the right to reproduce the article for own purposes, provided the copies are not offered for sale,
the right to self-archive the article.

5. Co-Authorship
If the article was prepared jointly with other authors, the signatory of this form warrants that he/she has been authorized by all co-authors to sign this agreement on their behalf, and agrees to inform his/her co-authors of the terms of this agreement.

6. Termination
This agreement can be terminated by the author or Journal of Vocational Studies on Applied Research upon two months’ notice where the other party has materially breached this agreement and failed to remedy such breach within a month of being given the terminating party’s notice requesting such breach to be remedied. No breach or violation of this agreement will cause this agreement or any license granted in it to terminate automatically or affect the definition of Journal of Vocational Studies on Applied Research.

7. Royalties
This agreement entitles the author to no royalties or other fees. To such extent as legally permissible, the author waives his or her right to collect royalties relative to the article in respect of any use of the article by Journal of Vocational Studies on Applied Research or its sublicensee.

8. Miscellaneous
Journal of Vocational Studies on Applied Research will publish the article (or have it published) in the Journal, if the article’s editorial process is successfully completed and Journal of Vocational Studies on Applied Research or its sublicensee has become obligated to have the article published. Journal of Vocational Studies on Applied Research may conform the article to a style of punctuation, spelling, capitalization and usage that it deems appropriate. The author acknowledges that the article may be published so that it will be publicly accessible and such access will be free of charge for the readers. Journal of Vocational Studies on Applied Research will be allowed to sublicense the rights that are licensed to it under this agreement.