Optical Response of Various Heavy Metal Ions-Based Carbon Dots Photoluminescent Quenching Effect

Iyon Titok Sugiarto; Nursidik Yulianto; Wildan Panji Tresna; Ismira Wahyu Lestari Lewa; Isnaeni Isnaeni

doi:10.14710/jpa.v6i1.18755

DOI: https://doi.org/10.14710/jpa.v6i1.18755

Optical Response of Various Heavy Metal Ions-Based Carbon Dots Photoluminescent Quenching Effect

*Iyon Titok Sugiarto - Research center for Photonics, National Research and Innovation Agency, Banten, Indonesia

Nursidik Yulianto - Research center for Photonics, National Research and Innovation Agency, Banten, Indonesia

Wildan Panji Tresna - Research center for Photonics, National Research and Innovation Agency, Banten, Indonesia

Ismira Wahyu Lestari Lewa - Research center for Photonics, National Research and Innovation Agency, Banten, Indonesia

Isnaeni Isnaeni - Research center for Photonics, National Research and Innovation Agency, Banten, Indonesia

Received: 13 Jun 2023; Revised: 9 Nov 2023; Accepted: 13 Nov 2023; Available online: 30 Nov 2023; Published: 30 Nov 2023.

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

BibTex Citation Data :

@article{JPA18755,
    author = {Iyon Titok Sugiarto and Nursidik Yulianto and Wildan Panji Tresna and Ismira Wahyu Lestari Lewa and Isnaeni Isnaeni},
    title = {Optical Response of Various Heavy Metal Ions-Based Carbon Dots Photoluminescent Quenching Effect},
    journal = {Journal of Physics and Its Applications},
  volume = {6},
    number = {1},
    year = {2023},
    keywords = {Carbon dots; Heavy metal ions; Photoluminescence; Quenching effect.},
    abstract = { Carbon nanodots (Cdots) are a type of semiconductor carbon-based nanomaterial that is gaining popularity due to its excellent characteristics (e.g., biocompatibility, unique optical properties, low cost, eco-friendly, and high stability). In terms of physicochemical properties for an environmentally friendly sensor application, this material also has an excellent ability to detect heavy metal ions in the biosphere. In this study, we proposed a comprehensive optical characterization to examine the sensitivity of the Cdots probe for three heavy metal ions (i.e., Mn, Pb, and Cr ions) and compare the performance. The results of the experiment revealed that each heavy metal ion reacted differently to the physical properties of Cdots. With the addition of Cr, Mn, and Pb metal ions from the original Cdot solution, which is only 1.45 ns, the lifetime of quenched Cdots is 2.55 ns, 3.15 ns, and 2.15 ns, respectively, according to the TRPL experiments. With additional Cr, Mn, and Pb discovered, the intensity of PL dropped by 5.7%, 14.2%, and 21.4%, respectively. Among these various heavy metal ions, Pb ions show the most affected by the quenching effect in Cdots-based photoluminescence, FTIR, and ultraviolet-visible light absorption characterization. Based on the results of three heavy metal ion experiments, this study can be implemented as the heavy metal ion sensor-based luminescence quenching effect of Cdots. },
   issn = {2622-5956},   pages = {11--17}  doi = {10.14710/jpa.v6i1.18755},
    url = {https://ejournal2.undip.ac.id/index.php/jpa/article/view/18755}
}

Citation Format:

Abstract

Carbon nanodots (Cdots) are a type of semiconductor carbon-based nanomaterial that is gaining popularity due to its excellent characteristics (e.g., biocompatibility, unique optical properties, low cost, eco-friendly, and high stability). In terms of physicochemical properties for an environmentally friendly sensor application, this material also has an excellent ability to detect heavy metal ions in the biosphere. In this study, we proposed a comprehensive optical characterization to examine the sensitivity of the Cdots probe for three heavy metal ions (i.e., Mn, Pb, and Cr ions) and compare the performance. The results of the experiment revealed that each heavy metal ion reacted differently to the physical properties of Cdots. With the addition of Cr, Mn, and Pb metal ions from the original Cdot solution, which is only 1.45 ns, the lifetime of quenched Cdots is 2.55 ns, 3.15 ns, and 2.15 ns, respectively, according to the TRPL experiments. With additional Cr, Mn, and Pb discovered, the intensity of PL dropped by 5.7%, 14.2%, and 21.4%, respectively. Among these various heavy metal ions, Pb ions show the most affected by the quenching effect in Cdots-based photoluminescence, FTIR, and ultraviolet-visible light absorption characterization. Based on the results of three heavy metal ion experiments, this study can be implemented as the heavy metal ion sensor-based luminescence quenching effect of Cdots.

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Keywords: Carbon dots; Heavy metal ions; Photoluminescence; Quenching effect.

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In Vol 6, No 1 (2023): November 2023

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