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Synthesis and Characterization of Bi13B0.48V0.49-xPxO21.45 and Efficient Catalyst for the Synthesis of 2,3-dihydroquinazolin-4(1H)-ones Derivatives Synthesis

Laboratory of Organic, Inorganic Chemistry, Electrochemistry and Environment, Faculty of Science, University of Ibn Tofail, B.P. 133, 14000 Kenitra, Morocco

Received: 20 Oct 2020; Revised: 2 Dec 2020; Accepted: 3 Dec 2020; Available online: 19 Dec 2020; Published: 28 Dec 2020.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2020 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

A new compound has been found in the system Bi13B0.48V0.49-x PxO21.45 (with 0≤x≤0.34), were prepared by the direct solid-state reaction of Bi2O3, (NH4)2HPO4, V2O5, and B2O3. This material melts congruently and it crystallize with the sillenite structure (space group I23) and form a solid solution with the cubic lattice parameter increasing from with a = 10.1568 Å to 10.1436 Å with increasing of P2O5 molar. Consequently, the new composites belong to g-variety of solid state. The samples have been characterized by Fourier transform infrared spectroscopy (FT-IR), diffraction XRD and scanning electron microscopy (SEM) coupled to the EDX. On the other hand, the valorization of the prepared composites was performed by using them as heterogeneous catalyst in the 2,3-dihydroquinazolin-4(1H)-ones derivatives synthesis. The catalyst is stable (as a bench top catalyst) and reusable. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

 

 

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Keywords: Bi13B0.48V0.49-x PxO21.45; Heterogeneous catalyst; 2,3-dihydroquinazolin-4(1H)-ones; γ-Bi2O3; Solid state
Funding: University of Ibn Tofail

Article Metrics:

  1. Gaya, U.I. (2013). Heterogeneous Photocatalysis Using Inorganic Semiconductor Solids. Springer Science & Business Media
  2. Pan, C., Li, X., Wang, F., Wang, L. (2008). Synthesis of bismuth oxide nanoparticles by the polyacrylamide gel route. Ceram. Int., 34, 439−441
  3. Xiaohong, W., Wei, Q., Weidong, H. (2007). Thin bismuth oxide films prepared through the sol–gel method as photocatalyst. J. Mol. Catal. A: Chem., 261, 167−171
  4. Huang, Q., Wang, Q., Tao, T., Zhao, Y., Wang, P., Ding, Z., Chen, M. (2019). Controlled Synthesis of Bi2O3/TiO2 Catalysts with Mixed Alcohols for the Photocatalytic Oxidation of HCHO. Environ. Technol., 40, 1937–1947
  5. Al Wazny, M.S., Salim, E.T., Bader, B.A., Fakhry, M.A. (2018). Synthesis of Bi2O3 Films, Studying Their Optical, Structural, and Surface Roughness Properties. IOP Conf. Ser. Mater. Sci. Eng., 454, 012160
  6. Zhu, G., Yang, W., Lv, W., He, J., Wen, K., Huo, W., Hu, J., Waqas, M., Dickerson, J.H., He, W. (2017). Facile Electrophoretic Deposition of Functionalized Bi2O3 Nanoparticles. Mater. Des., 116, 359–364
  7. Bandoli, G., Barreca, D., Brescacin, E., Rizzi, G.A., Tondello, E. (1996). Pure and Mixed Phase Bi2O3 Thin Films Obtained by Metal Organic Chemical Vapor Deposition. Chem. Vap. Depos., 2, 238–242
  8. Polat, Y., Arı, M., Dağdemir, Y. (2017). Thermal, Electrical and Structural Properties of (Bi2O3)1−x−y(Sm2O3)x(CeO2)y Electrolytes for Solid Oxide Fuel Cells. Phase Transit., 90, 387–398
  9. Shi, Y., Luo, L., Zhang, Y., Chen, Y., Wang, S., Li, L., Long, Y., Jiang, F. (2017). Synthesis and characterization of α/β-Bi2O3 with enhanced photocatalytic activity for 17α-ethynylestradiol. Ceram. Int., 43, 7627−7635
  10. Chen, R., Shen, Z.R., Wang, H., Zhou, H.J., Liu, Y.P., Ding, D.T., Chen, T.H. (2011). Fabrication of mesh-like bismuth oxide single crystalline nanoflakes and their visible light photocatalytic activity. J. Alloys Compd., 509, 2588–2596
  11. Wang, F., Jiang, J., Wang, B. (2019). Recent In Situ/Operando Spectroscopy Studies of Heterogeneous Catalysis with Reducible Metal Oxides as Supports. Cat., 9, 477
  12. Arfaoui, J., Ghorbel, A., Petitto, C., Delahay, G. (2017). Novel Vanadium Supported onto Mixed Molybdenum-Titanium Pillared Clay Catalysts for the Low Temperature SCR-NO by NH3. Chem. Eng. J., 356, 598−608
  13. Bokuniaeva, A.O., Vorokh, A.S. (2019). Estimation of Particle Size Using the Debye Equation and the Scherrer Formula for Polyphasic TiO2 Powder. J. Phys. Conf. Ser., 1410, 012057
  14. Pandya, S.G., Corbett, J.P., Jadwisienczak, W.M., Kordesch, M.E. (2016). Structural Characterization and X-Ray Analysis by Williamson–Hall Method for Erbium Doped Aluminum Nitride Nanoparticles, Synthesized Using Inert Gas Condensation Technique, Physica E Low Dimens. Syst. Nanostruct., 79, 98–102
  15. Bourja, L., Bakiz, B., Benlhachemi, A., Ezahri, M., Villain, S., Gavarri, J.R. (2010). Synthesis and characterization of nanosized Ce1-xbixo2-δ solid solutions for catalytic applications. Journal of Taibah University for Science, 4, 1–8
  16. Ai, Z., Huang, Y., Lee, S., Zhang, L. (2011). Monoclinic α-Bi2O3 Photocatalyst for Efficient Removal of Gaseous NO and HCHO under Visible Light Irradiation. J. of Alloys and Compd., 509, 2044–2049
  17. Rajyasree, C., Rao, D.K. (2011). Spectroscopic investigations on alkali earth bismuth borate glasses doped with CuO. J. Non-Cryst. Solids, 357, 836–841
  18. Hayakawa, S., Yoko, T., Sakka, S. (1995). IR and NMR structural studies on lead vanadate glasses. J. Non-Cryst. Solids, 183, 73–84
  19. Doweidar, H., Saddeek, Y.B. (2009). FTIR and ultrasonic investigations on modified bismuth borate glasses. J. Non-Cryst. Solid, 355, 348–354
  20. Jermoumi, T., Hafid, M., Toreis, N. (2002). Thermaland FTIR analysis of (50−x)BaO-x Fe2O3-50P2O5 glasses. Phys. Chem. Glasses, 43, 129−132
  21. Subbalakshimi, P., Sastry, P.S., Veeraiah, N. (2001). Dielectric relaxation and ac conduction phenomena in PbO-WO3-P2O5 glass system. Phys. Chem. Glasses, 42: 307-314
  22. Khawaja, E.E., Durrani, S.M.A., Al-Adel, F.F., Salim, M.A., Hussain, M.S. (1995). X-ray photoelectron spectroscopy and Fourier transform-infrared studies of transition metal phosphate. J. Mater. Sci., 30, 225–234
  23. Shih, P.Y., Chin, T.S. (1999). Effect of redox state of copper on the properties of P2O5-Na2O-CuO glasses. Mater. Chem. Phys., 60, 50–57
  24. Dayanand, C., Bhikshamaiah, G., Tyagaraju, V.J., Salagram, M., Krishna Murthy, A.S.R. (1996). Structural investigations of phosphate glasses: a detailed infrared study of the x(PbO)-(1−x)P2O5 vitreous system. J. Mater. Sci., 31, 1945–1967
  25. Sreenivasu, D., Chandramouli, V. (200). Spectroscopic and transport properties of Cu2+ ion doped in (40-x)Li2O-xLiF-60Bi2O3 glasses. Bull. Mater. Sci., 23, 509–513
  26. Dimitrov, V., Dimitriev, Y. (1990). Structure of glasses in PbO-V2O5 system. J. Non-Cryst. Solids, 122, 133−138
  27. Dachille, F., Roy, R. (1959). A New High‐pressure Form of B2O3 and Inferences on Cation Coordination from Infrared Spectroscopy. J. American Ceramic Society., 42, 78−80
  28. Iordanova, R., Dimitriev, Y., Dimitrov, V., Kassabov, S., Klissurski, D. (1996). Glass formation and structure in the V2O5Bi2O3Fe2O3 glasses. J. Non-Cryst. Solids, 204, 141–150
  29. Montagne, L., Palavit, G., Mairesse, G. (1996). 31P MAS NMR and FT IR analysis of (50-x/2) Na2O. xBi2O3.(50-x/2) P2O5 glasses. Phys. Chem. Glasses, 37, 206−211
  30. Moustafa, Y.M., El-Egili, K., Doweidar, H., Abbas, I. (2004). Phase equilibria in iron phosphate system. Physica B, 353, 82−91
  31. Baia, L., Stefan, R., Kiefer, W., Simon, S. (2005). Structural characteristics of B2O3–Bi2O3 glasses with high transition metal oxide content. J. Raman Spectrosc., 36, 262−266
  32. Kamitsos, E.I., Chryssikos, G.D., Karakassides, M.A. (1987). Vibrational-spectra of magnesium-sodium-borate glasses. 1. Far-infrared investigation of the cation-site interactions. J. Phys. Chem., 91, 1067−1073
  33. Wang, M., Zhang, T.T., Song, Z.G. (2011). Eco-friendly Synthesis of 2-substituted-2,3-dihydro-4(1H)-quinazolinones in water. Chinese Chem. Lett., 22, 427−430
  34. Safaei‐Ghomi, J., Teymuri, R. (2019). A Three‐component Process for the Synthesis of 2,3‐dihydroquinazolin‐4(1H)‐one Derivatives Using Nanosized Nickel Aluminate Spinel Crystals as Highly Efficient Catalysts. J. Chin. Chem. Soc., 66, 1490−1498
  35. Rostami, A., Tavakoli, A. (2011). Sulfamic acid as a reusable and green catalyst for efficient and simple synthesis of 2-substituted-2,3-dihydroquinazolin-4(1H)-ones in water or methanol. Chinese Chem. Lett., 22, 1317−1320
  36. Benzekri, Z., Serrar, H., Boukhris, S., Souizi, A. (2017). FeCl3/Egg Shell: An effective catalytic system for the synthesis of 2,3-dihydroquinazolin-4(1H)-ones at room temperature. J. Turk Chem. Soc. Sect. A: Chem., 4, 775−786
  37. Merroun, Y., Chehab, S., Ghailane, T., Boukhris, S., Ghailane, R., Habbadi, N., Hassikou, A., Lakhrissi, B., Souizi, A. (2018). An effective method to synthesize 2,3-dihydroquinazolin-4 (1H)-One using phosphate fertilizers (MAP, DAP and TSP) as green heterogeneous catalysts. J. Turk. Chem. Soc. Sect A: Chem., 5, 303−316
  38. Karhale, S., Survase, D., Bhat, R., Ubale, P., Helavi, V. (2017). A Practical and Green Protocol for the Synthesis of 2,3-Dihydroquinazolin-4(1H)-Ones Using Oxalic Acid as Organocatalyst. Res. Chem. Intermed., 43, 3915−3924
  39. Yassaghi, G., Davoodnia, A., Allameh, S., Zare-Bidaki, A., Tavakoli-Hoseini, N. (2012). Preparation, Characterization and First Application of Aerosil Silica Supported Acidic Ionic Liquid as a Reusable Heterogeneous Catalyst for the Synthesis of 2,3-Dihydroquinazolin-4(1H)-Ones. B. Korean Chem. Soc., 33, 2724–2730
  40. Yerram, P., Chowrasia, R., Seeka, S., Tangenda, S.J. (2013). Polyethylene Glycol (PEG-400) as a Medium for Novel and Efficient Synthesis of 2-Phenyl-2,3-Dihydroquinazolin-4(1H)-One Derivatives. Eur. J. Chem., 4, 462–466
  41. Sathe, B.P., Phatak, P.S., Kadam, A.Y., Gulmire, A.V., Narvade, P.R., Haval, K.P. (2018). An Efficient Synthesis of Substituted-2, 3-Dihydroquinazolin-4(1H)-Ones Using Fe3O4@SiO2SO3H Nano-Catalyst. Int. Res. J. Sci. Eng., A5, 99−104
  42. Zaghaghi, Z., Mirjalili, B.B.F., Monfared, A. (2019). Synthesis of 2,3-Dihydroquinazolin -4(1H)-Ones Promoted by Polystyrene Sulfonic Acid. Org. Chem. Res., 5, 80−86
  43. Katla, R., Chowrasia, R., da Silva, C., de Oliveira, A., dos Santos, B., Domingues, N. (2017). Recyclable [Ce(L-Pro)2]2 (Oxa) Used as Heterogeneous Catalyst: One-Pot Synthesis of 2,3-Dihydroquinazolin-4(1H)-Ones in Ethanol. Synthesis, 49, 5143−5148

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