Effect of Preparation Conditions on the Catalytic Activity of CuMnOx Catalysts for CO Oxidation
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
The hopcalite (CuMnOx) catalyst is a well-known catalyst for oxidation of CO at ambient temperature. It has prepared by co-precipitation method and the preparation parameters were like Copper/Manganese (Cu:Mn) molar ratios, drying temperature, drying time, calcination temperature and calcination time has an influence on activity of the resultant catalyst. The activity of the catalyst was measured in flowing air calcinations (FAC) conditions. The reaction temperature was increased from ambient to a higher value at which complete oxidation of CO was achieved. The particle size, weight of catalyst and CO flow rate in the air were also influenced by the activity of the catalyst for CO oxidation. The characterizations of the catalysts were done by several techniques like XRD, FTIR, BET, SEM-EDX and XPS. These results were interpreted in terms of the structure of the active catalyst. The main aim of this paper was to identify the optimum preparation conditions of CuMnOx catalyst with respect to the performance of catalyst for CO oxidation. Copyright © 2017 BCREC Group. All rights reserved
Received: 9th January 2017; Revised: 24th May 2017; Accepted: 25th May 2017; Available online: 27th October 2017; Published regularly: December 2017How to Cite: Dey, S., Dhal, G.C., Mohan, D., Prasad, R. (2017). Effect of Preparation Conditions on the Catalytic Activity of CuMnOx Catalysts for CO Oxidation. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (3): 431-451 (doi:10.9767/bcrec.12.3.900.437-451)
- Blumenthal, I. (2001). Carbon Monoxide Poisoning. Journal of the Royal Society of Medicine, 94: 270-272.
- Rattan, G., Prasad, R., Katyal, R.C. (2012). Effect of Preparation Methods on Al2O3 Supported CuO-CeO2-ZrO2 Catalysts for CO Oxidation. Bulletin of Chemical Reaction Engineering & Catalysis, 7(2): 112-123.
- Touger, M., Gallagher, E.J., Tyrrel, J. (1995). Relationship between Venous and Arterial Carboxy-Hemoglobin Levels in Patients with Suspected Carbon Monoxide Poisoning. Journal of Annals Emergency Medicine, 25: 481-483.
- Taylor, S.H., Rhodes, C. (2005). Ambient Temperature Oxidation of Carbon Monoxide Using a Cu2Ag2O3 Catalyst. Catalysis Letter, 101: 31-33.
- Badr, O., Probert, S.D. (1994). Carbon Monoxide Concentration in the Earth’s Atmosphere. Applied Energy, 49: 99-143.
- Pardiwala, J.M., Patel, F., Patel, S. (2011), Review Paper on Catalytic Converter for Automotive Exhaust Emission, International Conference on Current Trends in Technology, Nuicone, 08-10.
- Tanaka, Y., Utaka, T., Kikuchi, R., Takeguchi, T., Sasaki, K., Eguchi K. (2003). Water Gas Shift Reaction for the Reformed Fuels over Cu/MnO Catalysts Prepared via Spinel-Type Oxide. Journal of Catalysis, 215: 271-278.
- Du, P., Wang, W., Jia, C., Song, Q., Huang, Y., Si, R. (2016). Effect of Strongly Bound Copper Species in Copper-Ceria Catalyst for Preferential Oxidation of Carbon Monoxide. Applied Catalysis A: General, 518: 87-101.
- Mishra, A., Prasad, R. (2011). A Review on Preferential Oxidation of Carbon Monoxide in Hydrogen Rich Gases. Bulletin of Chemical Reaction Engineering & Catalysis, 6(1): 1-14.
- Njagi, E.C., Chen, C., Genuino, H., Galindo, H., Huang, H., Suib, S.L. (2010), Total Oxidation of CO at Ambient Temperature Using Copper Manganese Oxide Catalysts Prepared by a Redox Method. Applied Catalysis B: Environmental, 99: 103-110.
- Schwab, G.M., Kanungo, S.B. (1977). Efficient Stable Catalyst for Low-Temperature Carbon Monoxide Oxidation. Journal of Catalysis, 107: 109-120.
- Hasegawa, Y., Maki, R., Sano, M., Miyake, T., (2009). Preferential Oxidation of CO on Copper-Containing Manganese Oxides. Applied Catalysis A: General, 371: 67-72.
- Narasimharao, K., Al-Shehi, A., Al-Thabaiti, S. (2015). Porous Ag-Fe2O3 Nano Composite Catalysts for the Oxidation of Carbon Monoxide. Applied Catalysis A: General, 505: 431-440.
- Qian, K., Qian, Z., Hua, Q., Jiang, Z., Huang, W. (2013). Structure Activity Relationship of CuO/MnO2 Catalysts in CO Oxidation. Applied Surface Science, 273: 357-363.
- Tang, Z.R., Jones, C.D., Aldridge, J.K.W., Davies, T.E., Bartley, J.K., Carley, A.F., Taylor, S.H., Allix, M., Dickinson, C., Rosseinsky, M.J., Claridge, J.B., Xu, Z., Crudace, M.J., Hutchings, G.J. (2009). New Nanocrystalline Cu/MnOx Catalysts Prepared from Supercritical Anti Solvent Precipitation. Chem. Cat. Chem. Catalysis, 2: 247-251.
- Hoskins, W.M., Bray, W.C. (1926). The Catalytic Oxidation of Carbon Monoxide and the Adsorption of Carbon Dioxide, Carbon Monoxide and Oxygen by the Catalysts, Manganese Dioxide, Cupric Oxide and Mixture of These Oxides. Journal of American Chemical Society, 48: 1454-1474.
- Hutchings, G.J., Mirzaei, A.A., Joyner, R.W., Siddiqui, M.R.H., Taylor, S.H. (1997). Effect of Preparation Conditions on Catalytic Performance of Copper Manganese Oxide Catalysts for CO Oxidation. Applied Catalysis A: General, 166: 143-152.
- Kramer, M., Schmidt, T., Stowe, K., Maier, W.F. (2006), Structural and Catalytic Aspects of Sol–Gel Derived Copper Manganese Oxides as Low-Temperature CO Oxidation Catalyst. Applied catalysis A: General, 302: 257-263.
- Cai, L., Guo, Y., Lu, A., Branton, P., Li, W. (2012). The Choice of Precipitant and Precursor in the Co-Precipitation Synthesis of Copper Manganese Oxide for Maximizing Carbon Monoxide Oxidation. Journal of Molecular Catalysis A: Chemical, 360: 35-41.
- Wojciechowska, M., Przystajko, W., Zielinski M. (2007). CO Oxidation Catalysts Based on Copper and Manganese or Cobalt Oxides Supported on MgF2 and Al2O3. Catalysis Today, 119: 338-341.
- Shi, L., Hu, Z., Deng, G., Li, W. (2015). Carbon Monoxide Oxidation on Copper Manganese Oxides Prepared by Selective Etching with Ammonia. Chinese Journal of Catalysis, 36: 1920-1927.
- Biemelt, T., Wegner, K., Trichert, J., Lohe, M.R., Martin, J., Grothe, J., Kaskel, S. (2015). Hopcalite Nanoparticle Catalysts with High Water Vapour Stability for Catalytic Oxidation of Carbon Monoxide. Applied Catalysis B: Environmental, 21: 1-26.
- Clarke, T.J., Davies, T.E., Kondrat, S.A., Taylor, S.H. (2015). Mechano Chemical Synthesis of Copper Manganese Oxide for the Ambient Temperature Oxidation of Carbon Monoxide. Applied Catalysis B: Environmental, 165: 222-231.
- Arango-Diaz, A., Cecilia, J.A., Santos-Gomez, L., Marrero-Lopez, D., Losilla, E.R., Jimenez-Jimenez, J., Rodriguez-Castellon, E. (2015). Characterization and Performance in Preferential Oxidation of CO of CuO-CeO2 Catalysts Synthesized Using Polymethyl Metacrylate (PMMA) as Template. International Journal of Hydrogen Energy, 40: 11254-11260.
- Lee, J., Kim, H., Lee, H., Jang, S., Chang, J.H. (2016). Highly Efficient Elimination of Carbon Monoxide with Binary Copper-Manganese Oxide Contained Ordered Nanoporous Silicas. Nanoscale Research Letter, 11(6): 1-6.
- Jones, C., Cole, K.J., Taylor, S.H., Crudace, M.J., Hutchings, G.J. (2009). Copper Manganese Oxide Catalysts for Ambient Temperature Carbon Monoxide Oxidation: Effect of Calcination on Activity. Journal of Molecular Catalysis A: Chemical, 305: 121-124.
- Kondrat, S.A., Davies, T.E., Zu, Z., Boldrin, P., Bartley, J.K., Carley, A.F., Taylor, S.H., Rosseinsky, M.J., Hutchings, G.J. (2011). The Effect of Heat Treatment on Phase Formation of Copper Manganese Oxide: Influence on Catalytic Activity for Ambient Temperature Carbon Monoxide Oxidation. Journal of Catalysis, 281: 279-289.
- Mirzaei, A.A., Shaterian, R.H., Habibi, M., Hutchings, G.J., Taylor, S.H. (2003). Characterization of Copper-Manganese Oxide Catalysts: Effect of Precipitate Ageing upon the Structure and Morphology of Precursors and Catalysts. Applied Catalysis A: General, 253: 499-508.
- Irawan, R.M.B., Purwanto, P., Hadiyanto, H. (2015). Optimum Design of Manganese Coated Copper Catalytic Converter to Reduce Carbon Monoxide Emissions on Gasoline Motor. Journal of Environmental Sciences, 23: 86-92.
- Snytnikov, P.V., Popova, M.M., Men, Y., Rebrov, E.V., Kolb, G., Hessel, V., Schouten, J.C., Sobyanin, V.A. (2008). Preferential CO Oxidation over a Copper-Cerium Oxide Catalyst in a Micro Channel Reactor. Applied Catalysis A: General, 350: 53-62.
- Dey, S., Dhal, G. C., Prasad, R., Mohan, D. (2016). The Effect of Doping on the Catalytic Activity of CuMnOx Catalyst for CO Oxidation. Journal of Environmental Science, Toxicology and Food Technology, 10(11): 86-94.
- Li, M., Wang, D., Shi, X., Zhang, Z., Dong, T. (2007). Kinetics of Catalytic Oxidation of CO over Copper-Manganese Oxide Catalyst. Separation and Purification Technology, 57: 147-151.
- Meiyi, G., Nan, J., Yuhong, Z., Changjin, X., Haiquan, S., Shanghong, Z. (2016). Copper-cerium Oxides Supported on Carbon Nonmaterial for Preferential Oxidation of Carbon Monoxide. Journal of Rare Earths, 34: 55-60.
- Cole, K.J., Carley, A.F., Crudace, M.J., Clarke, M., Taylor, S.H., Hutchings, G.J. (2010). Copper Manganese Oxide Catalysts Modified by Gold Deposition: The Influence on Activity for Ambient Temperature Carbon Monoxide Oxidation. Catalysis Letters, 138: 143-147.
- Prasad, R., Singh, P. (2013). A Novel Route of Single Step Reactive Calcination of Copper Salts Far below their Decomposition Temperatures for Synthesis of Highly Active Catalysts. RSC Publishing: Catalysis Science and Technology, 3: 3326-3334.
- Hasegawa, Y., Fukumoto, K., Ishima, T., Yamamoto, H., Sano, M., Miyake, T. (2009). Preparation of Copper Containing Mesoporous Manganese Oxides and their Catalytic Performance for CO Oxidation. Applied Catalysis B: Environmental, 89: 420-424.
- Tang, Z.R., Kondrat, S.A., Dickinson, C., Bartley, J.K., Carley, A.F., Taylor, S.H., Davies, T.E., Allix, M., Rosseinsky, M. J., Claridge, J.B., Xu, Z., Romani, S., Crudace, M.J., Hutching, G.J. (2011). Synthesis of High Surface Area CuMn2O4 by Supercritical Anti-Solvent Precipitation for the Oxidation of CO at Ambient Temperature. Journal of Royal Society of Chemistry, 1: 740-746.
- Solsona, B., Hutchings, G.J., Garcia, T., Taylor, S.H. (2004), Improvement of the Catalytic Performance of CuMnOx Catalysts for CO Oxidation by the Addition of Au. New Journal of Chemistry, 28: 708-711.
- Xia, G.G., Yin, Y.G., Willis, W.S., Wang, J.Y., Suib, S.L. (1999). Efficient Stable Catalysts for Low Temperature Carbon Monoxide Oxidation. Journal of Catalysis, 185: 91-105.
- Wang, J., Chernavskii, P.A., Wang, Y., Khodakov, A.Y. (2013). Influence of the Support and Promotion on the Structure and Catalytic Performance of Copper-Cobalt Catalysts for Carbon Monoxide Hydrogenation. Journal of Fuel, 103: 1111-1122.
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission.
Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including: use for classroom teaching by Author or Author's institutionand presentation at a meeting or conference and distributing copies to attendees; use for internal training by author's company; distribution to colleagues for their reseearch use; use in a subsequent compilation of the author's works; inclusion in a thesis or dissertation; reuse of portions or extrcats from the article in other works (with full acknowledgement of final article); preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article); voluntary posting on open web sites operated by author or author’s institution for scholarly purposes (follow CC by SA License).
Authors and readers can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (cite to the article or content), provide a link to the license, and indicate if changes were made. If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.
Copyright Transfer Agreement
The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright publishing of the article shall be assigned to Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University as publisher of the journal.
Copyright encompasses exclusive rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations. The reproduction of any part of this journal, its storage in databases and its transmission by any form or media, such as electronic, electrostatic and mechanical copies, photocopies, recordings, magnetic media, etc., will be allowed only with a written permission from Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University.
Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University, the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.
Remember, even though we ask for a transfer of copyright, our journal authors retain (or are granted back) significant scholarly rights.
The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form BCREC 2016]
The copyright form should be signed originally and send to the Editorial Office in the form of original mail, scanned document or fax :
Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering and Catalysis
Department of Chemical Engineering, Diponegoro University
Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Telp.: +62-24-7460058, Fax.: +62-24-76480675