Synthesis, Structural Characterization, and Catalytic Property of A Zn(II) Complex with 5-Bromosalicylaldehyde Ligand

DOI: https://doi.org/10.9767/bcrec.12.3.876.364-369
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Submitted: 25-12-2016
Published: 28-10-2017
Section: Original Research Articles
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The study on catalytic activity of complex materials has been one of the hot spots in coordination  chemistry. In order to extensively study the catalytic activity of complexes, a new six-coordination Zn(II) complex material, [ZnL2(H2O)2] (C1) (HL = 5-bromosalicylaldehyde), has been prepared with 5-bromosalicylaldehyde, NaOH, and Zn(CH3COO)2·2H2O as raw materials. The structure of C1 was determined by elemental analysis, IR spectra, and single crystal X-ray diffraction. The Zn(II) complex shows a moderate catalytic activity for A3 coupling reaction of benzaldehyde, piperidine, and phenylacetylene with the benzaldehyde conversion reached 54.6 %. Furthermore, the Zn(II) complex catalyst exhibited 54.8 %, 53.8 %, and 54.4 % conversions of benzaldehyde in the second, third, and fourth cycles, respectively.  In addition, the Zn(II) complex features a selectivity of 100 % to the     product of propargylamine for the A3 coupling reaction. Copyright © 2017 BCREC Group. All rights reserved

Received: 25th December 2016; Revised: 10th March 2017; Accepted: 10th March 2017; Available online: 273th October 2017; Published regularly: December 2017

How to Cite: Tai, X.S., Li, P.F., Wang, X., Liu, L.L. (2017). Synthesis, Structural Characterization, and Catalytic Property of A Zn(II) Complex with 5-Bromosalicylaldehyde Ligand. Bulletin of Chemical Reaction Engineering & Catalysis, 12(3): 364-369 (doi:10.9767/bcrec.12.3.876.364-369)

 

Keywords

Zn(II) complex material; Synthesis; Structural characterization; Catalytic property; Ligand

  1. Xi Shi Tai 
    College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061,, China
  2. Peng Fei Li 
    College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266061,, China
  3. Xin Wang 
    Department of Chemistry, Qinghai Normal University, Xining 810008,, China
  4. Li Li Liu 
    College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061,, China
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