Hydrocracking of Calophyllum inophyllum Oil Employing Co and/or Mo Supported on γ-Al2O3 for Biofuel Production

*Wega Trisunaryanti  -  Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Indonesia
Triyono Triyono  -  Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Indonesia
Mohammad Ali Ghoni  -  Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Indonesia
Dyah Ayu Fatmawati  -  Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Indonesia
Puspa Nindro Mahayuwati  -  Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Indonesia
Endah Suarsih  -  Chemistry Department, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Indonesia
Received: 2 Aug 2020; Revised: 28 Sep 2020; Accepted: 29 Sep 2020; Published: 28 Dec 2020; Available online: 1 Oct 2020.
Open Access Copyright (c) 2020 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

Citation Format:
Cover Image
Abstract

Cobalt and/or Molybdenum based catalysts were simply dispersed on γ-Al2O3 through wet impregnation. The set of prepared monometallic and bimetallic catalysts of aCoO/γ-Al2O3, aMoO/γ-Al2O3, aCoOaMoO/γ-Al2O3, and bCoObMoO/γ-Al2O3 were investigated and evaluated in the hydrocracking of Calophyllum inophyllum (CIO) which is not a food crop as well as rich in unsaturated fatty acid that potential to be converted into biofuel. Out of the prepared catalysts, aCoOaMoO/γ-Al2O3 with total   metal content, acidity, and specific surface area of 13.62 wt%, 5.01 mmol.g-1, and 107.67 m2.g-1, respectively, showed the best catalytic performance. The high metal loading of aCoOaMoO/γ-Al2O3 is favorable by producing 65.56 wt% liquid fraction through carbocation formation mechanism. It was selective to produce 8.61 wt% gasoline and 5.01 wt% diesel. Copyright © 2020 BCREC Group. All rights reserved

 

Keywords: Cobalt; Molybdenum; γ-Al2O3; hydrocracking; Calophyllum inophyllum
Funding: Faculty Mathematics and Natural Sciences, Universitas Gadjah Mada, Lecturer Research Grant 2020 under contract Contract number: 56/J01.1.28/PL.06.02/2020

Article Metrics:

Article Info
Section: Original Research Articles
Language: EN
In 2020: BCREC Volume 15 Issue 3 Year 2020 (SCOPUS and Web of Science Indexed,December 2020)
Statistics: 300 150
Others articles
Fe/Indonesian Natural Zeolite as Hydrodeoxygenation Catalyst in Green Diesel Production from Palm Oil Catalytic Properties of Alumina-Supported Ruthenium, Platinum, and Cobalt Nanoparticles towards the Oxidation of Cyclohexane to Cyclohexanol and Cyclohexanone A Review Paper on Heterogeneous Fenton Catalyst: Types of Preparation, Modification Techniques, Factors Affecting the Synthesis, Characterization, and Application in the Wastewater Treatment A Review on Catalytic Membranes Production and Applications Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts Liquid-phase Hydrogenation of Phenol to Cyclohexanone over Supported Palladium Catalysts
  1. Woo, Y., Cho, S., Kim, J., Kim, B.S. (2016). Optimization-based approach for strategic design and operation of a biomass-to-hydrogen supply chain. International Journal Hydrogen Energy, 41, 5405–5418.
  2. Iakovou, E., Karagiannidis, A., Vlachos, D., Toka, A., Malamakis, A. (2010). Waste biomass-to-energy supply chain management: a critical synthesis. Waste Management, 30, 1860-1870.
  3. Chambost, V., Stuart, P.R. (2007). Selecting the most appropriate products for the forest biorefinery. Industrial Biotechnology, 3, 112-119.
  4. Dui, N., Guzovi, Z., Cosi, B., Stani, Z. (2011). Geographic distribution of economic potential of agricultural and forest biomass residual for energy use: case study Croatia. Energy, 36, 2017-2028.
  5. Perego, C., Bosetti, A. (2011). Biomass to fuels: The role of zeolite and mesoporous materials. Microporous Mesoporous Materials, 144, 28–39.
  6. Priyanto, U., Suprapto, S., Roesyadi, A., Rosyadi, E., Nurunnabi, M., Hanaoka, T., Miyazawa, T., Sakanishi, K. (2011). Biofuel Production by Hydrocracking of Biomass FT Wax over NiMo/Al2O3-SiO2 Catalyst. Journal of the Japan Institute of Energy, 90, 1171-1176.
  7. Zhou, Z., Zhang, W., Sun, D., Chu, L., Jiang, J. (2016). Renewable biofuel production from hydrocracking of soybean biodiesel with a commercial petroleum Ni-W catalyst. International Journal of Green Energy, 13, 1185-1192.
  8. Ssrihanun, N., Dujjanutat, P., Muanruksa, P., Kaewkannetra, P. (2020). Biofuels of Green Diesel–Kerosene–Gasoline Production from Palm Oil: Effect of Palladium Cooperated with Second Metal on Hydrocracking Reaction. Catalysts, 10:241.
  9. Said, T., Dutot, M., Martin, C., Beaudeux, J. L., Boucher, C., Enee, E., Baudoin, C., Warnet, J-M., Rat, P. (2007). Cytoprotective effect against UV-induced DNA damage and oxidative stress: role of new biological UV filter. European Journal of Pharmaceutical Sciences, 30, 203–210.
  10. Ong, C.H., Mahlia, I.M.T., Masjuki, H.H., Norhasyima, R.S. (2011). Comparison of palm oil Jatrophacurcas and Calophyllum inophyllum for biodiesel. Renewable Sustainable Energy Review, 15, 3501-3515.
  11. Venkanna, B.K., Reddy, C.V. (2009) Biodiesel production and optimization from Calophyllum inophyllum Linn oil (honne oil) – a three stage method. Bioresource Technology, 100, 5122–5125.
  12. Sahoo, P.K., Das, L.M. (2009). Process optimization for biodiesel production from Jatropha Karanja and Polanga oils. Fuel, 88, 1588–1594.
  13. Sahoo, P.K., Das, L.M., Babu, M.K.G., Naik, S.N. (2007). Biodiesel development from high acid value polanga seed oil and performance evaluation in a CI engine. Fuel., 86, 448–454.
  14. Maki-Arvela, P., Rozmyszowicz, B., Lestari, S., Simakova, O., Eranen, K., Salmi, T., Murzin, D.Y. (2011). Catalytic deoxygenation of tall oil fatty acid over palladium supported on mesoporous carbon. Energy & Fuel, 25, 2815–2825.
  15. Murata, K., Liu, Y., Inaba, M., Takahara, I. (2010). Production of synthetic diesel by hydrotreatment of jatropha oils using Pt−Re/H-ZSM-5 catalyst. Energy Fuel, 24, 2404–2409.
  16. Sotelo-Boyas, R., Liu, Y., Minowa, T. (2011). Renewable diesel production from the hydrotreating of rapeseed oil with zeolitic and NiMo/Al2O3 catalysts. Industrial & Engineering Chemistry, 50, 2791–2799.
  17. Yang, R., Du, X., Zhang, X., Xin, H., Zhou, K., Li, D., Hu, C. (2019). Transformation of Jatropha Oil into High-Quality Biofuel over Ni-W Bimetallic Catalysts. ACS Omega, 4, 10580–10592.
  18. Albayanti, T.M., Doyle, A.M. (2014). SBA-15 supported bimetallic catalysts for enhancement isomers production during n-heptane decomposition. International Journal of Chemical Reactor Engineering, 12, 345–354.
  19. Grilc, M., Likozar, B., Levec, J. (2014). Hydrodeoxygenation and hydrocracking using different catalyst. Applied Catalysis B: Environmental, 150–151, 275–287.
  20. Rianto, L. B., Amalia, S., Khalifah, S.N. (2012). Effect of metal impregnation on natural zeolite towards zeolite surface area. Alchemy, 2, 58–67.
  21. Li, X., Qiao, K., Subhan, F., Xing, W., Liu, X., Yan, Z. (2015). Preparation and hydrodesulfurization properties of cobalt–molybdenum–phosphorous catalysts for removal of dibenzothiophene. Applied Petrochemical Research, 5, 405–411.
  22. Li, G., Yue, L., Fan, R., Liu, D., Li, X. (2017) Synthesis of a Co-Mo sulfide catalyst with a hollow structure for highly efficient hydrodesulfurization of dibenzothiophene. Catalysis Science & Technology, 7, 5505-5509.
  23. Yamada, S., Qian, W., Ishihara, A., Ichinoseki, M., Kabe, T. (2001). Methods of Activating Catalysts for Hydrodesulfurization of Light Gas Oil (Part 1) Catalytic Activity of CoMo/Al2O3 Catalyst Presulfided with Polysulfides for Hydrodesulfurization of Dibenzothiophene. Sekiyu Gakkaishi, 44, 217-224.
  24. Pongsendana, M., Trisunaryanti, W., Artanti, F.W., Falah, I.I., Sutarno, S. (2017), Hydrocracking of waste lubricant into gasoline fraction over CoMo catalyst supported on mesoporous carbon from bovine bone gelatin. Korean Journal of Chemical Engineering, 34, 2591-2596.
  25. Al-Zeghayer, Y., Sunderland, P., Al-Masry, W., Al-Mubaddel, F., Ibrahim, A., Bhartiya, B.K., Jibril, B. (2005). Activity of CoMo/γ-Al2O3 as a catalyst in hydrodesulfurization: effects of Co/Mo ratio and drying condition. Applied Catalysis A: General, 282, 163–171.
  26. Trisunaryanti, W., Kartika, I.A., Mukti, R.R., Hartati, H., Triyono, T., Widyawati, R., Suarsih, E. (2019), Preparation of Ni- and Mo-based catalysts supported on γ-Al2O3 for hydrocracking for Calophyllum inophyllum oil, Biofuels., doi: 10.1080/17597269.2019.1669871
  27. Trisunaryanti, W., Suarsih, E., Falah, I.I., Triyono, T. (2019) Well-dispersed nickel nanoparticles on the external and internal surface of SBA-15 for hydrocracking of pyrolyzed a-cellulose. RSC Advances, 9, 1230–1237.
  28. Khowatimy, F.A., Priastomo, Y., Febriyanti, E., Riyantoko, H., Trisunaryanti, W. (2014). Study of waste lubricant hydrocracking into fuel fraction over the combination of Y-zeolite and ZnO catalyst, Procedia Environmental Sciences, 20, 225–234.
  29. Wijaya, K., Syoufian, A., Ariantika, S.D. (2014). Hydrocracking of used cooking oil into biofuel catalyzed by nickel-bentonite. Asian Journal of Chemistry, 26, 3785–3789.
  30. Rasyid, R., Prihartantyo, A., Mahfud, Roesyadi, A. (2015). Hydrocracking of Nyamplung Oil (Calophyllum inophyllum oil) Using CoMO/γ-Al2O3 and CoMo/SiO2 Catalysts. Modern Applied Sciences, 9, 43-47.

Last update: 2021-01-18 05:39:32

No citation recorded.

Last update: 2021-01-18 05:39:32

No citation recorded.
Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis License URL: http://creativecommons.org/licenses/by-sa/4.0

Journal Author(s) Rights

In order for BCREC Group to publish and disseminate research articles, we need publishing rights (transfered from author(s) to publisher). This is determined by a publishing agreement between the Author(s) and BCREC Group. This agreement deals with the transfer or license of the copyright of publishing to BCREC Group, while Authors still retain significant rights to use and share their own published articles. BCREC Group supports the need for authors to share, disseminate and maximize the impact of their research and these rights, in any databases.

As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including:

  • use for classroom teaching by Author or Author's institution and presentation at a meeting or conference and distributing copies to attendees; 
  • use for internal training by author's company; 
  • distribution to colleagues for their reseearch use; 
  • use in a subsequent compilation of the author's works; 
  • inclusion in a thesis or dissertation; 
  • reuse of portions or extracts from the article in other works (with full acknowledgement of final article); 
  • preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article); 
  • voluntary posting on open web sites operated by author or author’s institution for scholarly purposes, 
(but it should follow the open access license of Creative Common CC-by-SA License).

Authors/Readers/Third Parties can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (the name of the creator and attribution parties (authors detail information), a copyright notice, an open access license notice, a disclaimer notice, and a link to the material), provide a link to the license, and indicate if changes were made (Publisher indicates the modification of the material (if any) and retain an indication of previous modifications using a CrossMark Policy and information about Erratum-Corrigendum notification).

Authors/Readers/Third Parties can read, print and download, redistribute or republish the article (e.g. display in a repository), translate the article, download for text and data mining purposes, reuse portions or extracts from the article in other works, sell or re-use for commercial purposes, remix, transform, or build upon the material, they must distribute their contributions under the same license as the original Creative Commons Attribution-ShareAlike (CC BY-SA).

Copyright Transfer Agreement for Publishing (Publishing Right)

The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright for publishing (publishing right) of the article shall be assigned/transferred to Publisher of Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) (or BCREC Group).

Upon acceptance of an article, authors will be asked to complete a 'Copyright Transfer Agreement for Publishing (CTAP)'. An e-mail will be sent to the Corresponding Author confirming receipt of the manuscript together with a 'Copyright Transfer Agreement for Publishing' form by online version of this agreement.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia-Indonesian Catalyst Society (MKICS), the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of copyright for publishing (CTAP), our journal Author(s) retain (or are granted back) significant scholarly rights as mentioned before.

The Copyright Transfer Agreement for Publishing (CTAP) Form can be downloaded here: [Copyright Transfer Agreement for Publishing (CTAP) Form BCREC 2020] 


The copyright form should be signed electronically and send to the Editorial Office in the form of original e-mail below:  

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering & Catalysis
Laboratory of Plasma-Catalysis (R3.5), UPT Laboratorium Terpadu, Universitas Diponegoro
Jl. Prof. Soedarto, Semarang, Central Java, Indonesia 50275
Telp/Whatsapp: +62-81-316426342
E-mail: bcrec[at]live.undip.ac.id

(This policy statements has been updated at 24th December 2020)