The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil

Amalia Putri Purnamasari; Meyga E. F. Sari; Desy T. Kusumaningtyas; Suprapto Suprapto; Abdul Hamid; Didik Prasetyoko

doi:10.9767/bcrec.12.3.802.329-336

DOI: https://doi.org/10.9767/bcrec.12.3.802.329-336

The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil

Amalia Putri Purnamasari¹, Meyga E. F. Sari¹, Desy T. Kusumaningtyas¹, Suprapto Suprapto¹, Abdul Hamid¹, Didik Prasetyoko^{1, 2}

¹Department of Chemistry, Institut Teknologi Sepuluh Nopember, Surabaya 60111, Indonesia

²Laboratory of Energy, Center for Energy Studies, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia

Received: 21 Nov 2016; Revised: 8 Mar 2017; Accepted: 9 Mar 2017; Available online: 27 Oct 2017; Published: 1 Dec 2017.

Editor(s): Istadi Istadi, Yuly Kusumawati

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Abstract

Transesterification of used cooking oil was carried out over calcium oxide supported on mesoporous H-ZSM-5 prepared from kaolin as solid base catalysts. Solid basic catalysts investigated in this study were characterized by XRD, FTIR spectroscopy, and N₂ adsorption-desorption techniques. The XRD pattern showed peaks corresponding to the CaO and mesoporous ZSM-5 in the sample. The peak intensity of the CaO increased as CaO loading in ZSM-5 was increased. The characterization based on FTIR spectroscopy revealed that CaO/H-ZSM-5 solids have functional groups characteristics of both CaO and mesoporous H-ZSM-5 which appeared in the band at around 550 cm^-1and 480 cm^-1. The isotherm of N₂ adsorption-desorption of CaO/H-ZSM-5 indicated the type IV isotherm with the presence of hysteresis loop. For the catalytic activity, the biodiesel yield using catalyst of 10 % CaO/HZSM-5 (100 %), 30 % CaO/HZSM-5 (100 %), 50 % CaO/HZSM-5 (100 %) were 24.34, 27.37, and 29.73 %, respectively. It also related with the basic active site, when loading CaO increased, the basic active site also increased.

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Keywords: CaO/H-ZSM-5; Zeolite; Mesoporous; Cooking Oil; Transesterification

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Section: The 2nd International Seminar on Chemistry (ISoC 2016) (Surabaya, 26-27 July 2016)

Language : EN

In 2017: BCREC Volume 12 Issue 3 Year 2017 (December 2017)

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