The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil

Amalia Putri Purnamasari -  Department of Chemistry, Institut Tekonologi Sepuluh Nopember, Surabaya 60111,, Indonesia
Meyga E. F. Sari -  Department of Chemistry, Institut Tekonologi Sepuluh Nopember, Surabaya 60111,
Desy T. Kusumaningtyas -  Department of Chemistry, Institut Tekonologi Sepuluh Nopember, Surabaya 60111,, Indonesia
Suprapto Suprapto -  Department of Chemistry, Institut Tekonologi Sepuluh Nopember, Surabaya 60111,, Indonesia
Abdul Hamid -  Department of Chemistry, Institut Tekonologi Sepuluh Nopember, Surabaya 60111,, Indonesia
*Didik Prasetyoko -  (Scopus ID: 6507890461) Department of Chemistry, Institut Teknologi Sepuluh Nopember, Surabaya, 60111 Laboratory of Energy, Center for Energy Studies, Institut Teknologi Sepuluh Nopember, Surabaya,, Indonesia
Received: 21 Nov 2016; Published: 28 Oct 2017.
Open Access Copyright (c) 2017 Bulletin of Chemical Reaction Engineering & Catalysis
Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Citation Format:
Cover Image
Article Info
Section: The 2nd International Seminar on Chemistry (ISoC 2016) (Surabaya, 26-27 July 2016)
Language: EN
Full Text:
In 2017: BCREC Volume 12 Issue 3 Year 2017 (SCOPUS and Web of Science Indexed, December 2017)
Statistics: 615 315
Abstract

Transesterification of used cooking oil was carried out over calcium oxide supported on mesoporous H-ZSM-5 prepared from kaolin as solid base catalysts. Solid basic catalysts investigated in this study were characterized by XRD, FTIR spectroscopy, and N2 adsorption-desorption techniques. The XRD pattern showed peaks corresponding to the CaO and mesoporous ZSM-5 in the sample. The peak intensity of the CaO increased as CaO loading in ZSM-5 was increased. The characterization based on FTIR spectroscopy revealed that CaO/H-ZSM-5 solids have functional groups characteristics of both CaO and mesoporous H-ZSM-5 which appeared in the band at around  550 cm-1 and 480 cm-1. The isotherm of N2 adsorption-desorption of CaO/H-ZSM-5 indicated the type IV isotherm with the presence of hysteresis loop. For the catalytic activity, the biodiesel yield using catalyst of 10 % CaO/HZSM-5 (100 %), 30 % CaO/HZSM-5 (100 %), 50 % CaO/HZSM-5 (100 %) were 24.34, 27.37, and 29.73 %, respectively. It also related with the basic active site, when loading CaO increased, the basic active site also increased. Copyright © 2017 BCREC Group. All rights reserved

Received: 21st November 2016; Revised: 8th March 2017; Accepted: 9th March 2017; Available online: 27th October 2017; Published regularly: December 2017

How to Cite: Purnamasari, A.P., Sari, M.E.F., Kusumaningtyas, D.T., Suprapto, S., Hamid, A., Prasetyoko, D. (2017). The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil. Bulletin of Chemical Reaction Engineering & Catalysis, 12(3): 329-336 (doi:10.9767/bcrec.12.3.802.329-336)

 

Keywords
CaO/H-ZSM-5; Zeolite; Mesoporous; Cooking Oil; Transesterification

Article Metrics:

  1. Kansedo, J., Lee, K.T., Bhatia, S. (2009). Cerbera Odollam (Sea Mango) Oil as A Promising Non-Edible Feedstock for Biodiesel Production. Fuel, 88: 1148-1150.
  2. Holilah, Prasetyoko, D., Oetami, T.P., Santosa, E.B., Zein, Y.M., Bahruji, H., Ediati, R.,Fansuri, H., Juwari. (2015). The Potential of Reutealis Trisperma Seed as A New Non-Edible Source for Biodiesel Production. Biomass Conversion and Biorefinery, 5: 347-353.
  3. Wang, Y., Chou, H., Chen, B., Lee, D. (2013). Optimization of Sodium Loading on Zeolite Support for Catalyzed Transesterification of Triolein with Methanol. Bioresource Technology, 145: 1-6.
  4. Yan, S., Lu, H., Liang, B. (2008). Supported CaO Catalysts Used in the Transesterification of Rapeseed Oil for the Purpose of Biodiesel Production. Energy & Fuels, 22: 646-651.
  5. Witoon, T., Bumrungsale, S., Vathavanichkul, P., Palitsakun, S., Saisriyoot, M., Faungnawakij, K. (2014). Biodiesel Production from Transesterification of Palm Oil with Methanol over CaO Supported on Bimodal Meso-Macroporous Silica Catalyst. Bioresource Technology, 156: 329-334.
  6. Samart, C., Chaiyan, C., Reubroycharoen, P. (2010). Biodiesel Production by Methanolysis of Soybean Oil Using Calcium Supported on Mesoporous Silica Catalyst. Energy Conversion and Management, 51: 1428-1431.
  7. Zabeti, M., Daud, W., Aroua, M.K. (2010). Biodiesel Production Using Alumina-Supported Calcium Oxide: An Optimization Study. Fuel Processing Technology, 91: 243-248.
  8. Demirbas, A. (1998). Fuel Properties and Calculation of Higher Heating Values of Vegetable Oils. Fuel, 771: 117-120.
  9. Schuchardt, U., Sercheli, R., Vargas, R.M. (1998). Transesterification of Vegetable Oils: A Review. Brazilian Chemical Society, 9: 199-210.
  10. Qoniah, I., Prasetyoko, D., Bahruji, H., Triwahyono, S., Jalil, A.A., Suprapto, Hartati, Purbaningtyas, T.E. (2015). Direct Synthesis of Mesoporous Aluminosilicates from Indonesian Kaolin Clay without Calcinations. Applied Clay Science, 118: 290-294.
  11. Zein, Y.M., Anal, A.K., Prasetyoko, D., Qoniah, I. (2016). Biodiesel Production from Waste Palm Oil Catalyzed by Hierarchical ZSM-5 Supported Calcium Oxide. Indonesian Journal of Chemistry, 16: 98-104.
  12. Gonçalves, M.L., Dimitrov, L.D., Jordão, M.H., Wallau, M., Urquieta-González, E.A. (2008). Synthesis of Mesoporous ZSM-5 by Crystallisation of Aged Gels in the Presence of Cetyltrimethylammonium Cations. Catalysis Today, 133-134: 69-79.
  13. Pasupulety, N., Gunda, K., Liu, Y., Rempel, G.L., Flora, T.T.Ng. (2013). Production of Biodiesel from Soybean Oil on CaO/Al2O3 Solid Base Catalysts. Applied Catalysis A General, 452: 189-202.
  14. Granados, M.L., Poves, M.D.Z., Alonso, D.M., Mariscal, R., Galisteo, F.C., Moreno-Tost, R. (2007). Biodiesel from Sunflower Oil by Using Activated Calcium Oxide. Applied Catalysis B: Environmental, 73: 317-326.
  15. Albuquerque, M.C.G., Jimenez-Urbistonde, I., Santamarıa-Gonzalez, J., Merida-Robles, J.M., Moreno-Tost, R., Rodrıguez-Castellon, E., Jimenez-Lopez, A., Azevedo, D.C.S., Cavalcante Jr, C.L., Maireles-Torres, P. (2008). CaO Supported on Mesoporous Silicas as Basic Catalysts for Transesterification Reactions. Applied Catalyst A General, 334: 35-43.

Copyright (c) 2017 Bulletin of Chemical Reaction Engineering & Catalysis Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. 

Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including: use for classroom teaching by Author or Author's institutionand presentation at a meeting or conference and distributing copies to attendees; use for internal training by author's company; distribution to colleagues for their reseearch use; use in a subsequent compilation of the author's works; inclusion in a thesis or dissertation; reuse of portions or extrcats from the article in other works (with full acknowledgement of final article); preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article); voluntary posting on open web sites operated by author or author’s institution for scholarly purposes (follow CC by SA License).

Authors and readers can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (cite to the article or content), provide a link to the license, and indicate if changes were made. If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.

Copyright Transfer Agreement

The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright publishing of the article shall be assigned to Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University as publisher of the journal.

Copyright encompasses exclusive rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations. The reproduction of any part of this journal, its storage in databases and its transmission by any form or media, such as electronic, electrostatic and mechanical copies, photocopies, recordings, magnetic media, etc., will be allowed only with a written permission from Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University, the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of copyright, our journal authors retain (or are granted back) significant scholarly rights.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form BCREC 2016] 


The copyright form should be signed originally and send to the Editorial Office in the form of original mail, scanned document or fax :  

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering and Catalysis
Department of Chemical Engineering, Diponegoro University
Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Telp.: +62-24-7460058, Fax.: +62-24-76480675
E-mail: bcrec[at]live.undip.ac.id