Hydrocracking of Non-edible Vegetable Oils with Co-Ni/HZSM-5 Catalyst to Gasoil Containing Aromatics

*Danawati Hari Prajitno  -  Laboratory of Chemical Engineering Reaction, Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology, Surabaya 60111,, Indonesia
Achmad Roesyadi  -  Laboratory of Chemical Engineering Reaction, Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology, Surabaya 60111, Indonesia
Muhammad Al-Muttaqii  -  Laboratory of Chemical Engineering Reaction, Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology, Surabaya 60111,, Indonesia
Lenny Marlinda  -  Laboratory of Chemical Engineering Reaction, Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology, Surabaya 60111,, Indonesia
Received: 21 Nov 2016; Revised: 9 May 2017; Accepted: 20 May 2017; Published: 1 Dec 2017; Available online: 27 Oct 2017.
Open Access Copyright (c) 2017 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

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Abstract

Biofuel has been considered as one of the environmentally friendly energy sources to substitute fossil fuel derived from non-edible vegetable oil. This research aims to investigate the effect of the non-edible vegetable oil composition on a specific hydrocarbons distribution contained in biofuel and the aromatics formation through hydrocracking reaction with the Co-Ni/HZSM-5 catalyst. The formation of aromatics from non-edible vegetable oils, such as: Cerbera manghas, rubber seed, and sunan candlenut oils, containing saturated, mono- and polyunsaturated fatty acids is presented. The hydrocracking reaction was carried out in a pressure batch reactor, a reaction temperature of 350 oC for 2 h, reactor pressure of 15 bar after flowing H2 for 1 hour, and a catalyst/oil ratio of 1 g/200 mL. Liquid hydrocarbon product was analyzed by gas chromatography-mass spectrometry. Based on the GC-MS analysis, hydrocracking on three different oils indicated that polyunsaturated fatty acids were required to produce relatively high aromatics content. The sunan candlenut oil can be converted to gasoil range hydrocarbons containing a small amount of aromatic through hydrocracking reaction. Meanwhile, the aromatics in liquid product from hydrocracking of Cerbera manghas and rubber seed oils were not found. Copyright © 2017 BCREC Group. All rights reserved.

Received: 21st November 2016; Revised: 9th May 2017; Accepted: 20th May 2017; Available online: 27th October 2017; Published regularly: December 2017

How to Cite: Prajitno, D.H., Roesyadi, A., Al-Muttaqii, M., Marlinda, L. (2017). Hydrocracking of Non-edible Vegetable Oils with Co-Ni/HZSM-5 Catalyst to Gasoil Containing Aromatics. Bulletin of Chemical Reaction Engineering & Catalysis, 12(3):318-328 (doi:10.9767/bcrec.12.3.799.318-328)

 

Keywords: hydrocracking; non-edible vegetable oil; aromatics; gasoil; Co-Ni/HZSM-5 catalyst

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