Experimental and Theoretical Studies of Eosin Y Dye as Corrosion Inhibitors for Carbon Steel in Perchloric Acid Solution

*Tarik Attar orcid scopus  -  Laboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Algeria
Abbes Benchadli  -  Laboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Algeria
Boulanouar Messaoudi  -  Laboratory of Applied Thermodynamics and Molecular Modeling, Department of Chemistry, University of Abou Bekr Belkaïd Tlemcen, Algeria
Naceur Benhadria  -  Laboratory of Inorganic Materials Chemistry and Application, Department of Materials Engineering, University of Science and Technology of Oran (USTO M. B), Algeria
Esma Choukchou-Braham  -  Laboratory of Toxicomed, University Abou Beker Belkaid Tlemcen, Algeria
Received: 9 May 2020; Revised: 23 May 2020; Accepted: 25 May 2020; Published: 1 Aug 2020; Available online: 30 Jul 2020.
Open Access Copyright (c) 2020 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

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Abstract

The adsorption behavior and the inhibition performance of Eosin Y Dye for carbon steel corrosion in 1 M perchloric acid solution have been carried using weight loss and scanning electron micrograph (SEM) techniques as well theoretical calculations based on density functional theory (DFT). The studied inhibitor concentrations were between 5´10-5 M and 5´10-3 M. Results obtained revealed that Eosin Y is an effective inhibitor and its inhibition efficiency increases with increasing concentration to attain 96.91% at 5´10-3 M at 30 °C. Thermodynamic parameters such as adsorption heat, adsorption entropy and adsorption free energy were obtained from experimental data of the temperature studies of the inhibition process at five temperatures ranging from 20 to 60 °C. It was found that the adsorption of Eosin Y could prevent steel from weight loss and the adsorption accorded with the Langmuir adsorption isotherm. The free energy of adsorption showed that the corrosion inhibition takes place by spontaneous physicochemical adsorption of inhibitor molecules on the carbon steel surface. SEM and DFT studies confirm the adsorption of Eosin Y on carbon steel surface. Copyright © 2020 BCREC Group. All rights reserved

 

Keywords: Carbon steel; Eosin Y; Weight loss; DFT; Corrosion Inhibitor; perchloric solution

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