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Synthesis of Ag3PO4 using Hydrophylic Polymer and Their Photocatalytic Activities under Visible Light Irradiation

1Department of Chemistry, Jenderal Soedirman University, Jl. Dr. Soeparno, Purwokerto 53123, Indonesia

2Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan

Received: 13 Nov 2016; Revised: 10 Feb 2017; Accepted: 10 Feb 2017; Published: 1 Aug 2017; Available online: 8 May 2017.
Open Access Copyright (c) 2017 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

The highly active Ag3PO4 photocatalysts were successfully synthesized using the hydrophylic polymer of PVA (polyvinyl alcohol), PEG (polyethylene glycol) and PVP (polyvinyl pyrrolidone). The products were characterized using X-ray diffraction (XRD), Diffuse reflection spectroscopy (DRS), Field emission scanning electron microscope (FE-SEM), Brunauer–Emmett–Teller (BET) specific surface area, and X-ray photoelectron spectroscopy (XPS). Photocatalytic activities were evaluated using decomposition of Rhodamine B (RhB) under visible light irradiation. The results showed that the PVA, PEG, and PVP increased the specific surface area and enhanced the photocatalytic activity of Ag3PO4. The highest photocatalytic activity could be observed in Ag3PO4 synthesized with PVA, mainly due to an increase in electron excitation induced by PVA chemically adsorbed on the surface. 

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Keywords: Ag3PO4; Photocatalyst; Polyvinyl alcohol; Polyethylene glycol; Polyvinyl pyrrolidone

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Section: The 2nd International Seminar on Chemistry (ISoC 2016) (Surabaya, 26-27 July 2016)
Language : EN
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