Synthesis, Structural Characterization and Catalytic Activity of A Cu(II) Coordination Polymer Constructed from 1,4-Phenylenediacetic Acid and 2,2’-Bipyridine

*Wang Li-Hua  -  College of Information and Engineering, Weifang University, Weifang 261061,, China
Liang Lei  -  School of Harbin Light Industry, Harbin 150040,, China
Wang Xin  -  Department of Chemistry, Qinghai Normal University, Xining 810008, China
Received: 21 Oct 2016; Revised: 17 Nov 2016; Accepted: 22 Nov 2016; Published: 30 Apr 2017; Available online: 13 Feb 2017.
Open Access Copyright (c) 2017 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

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Abstract

In order to study the catalytic activity of Cu(II) coordination polymer material, a novel 1D chained Cu(II) coordination polymer material, [CuL(bipy)(H2O)5]n (A1) (H2L = 1,4-phenylenediacetic acid, bipy = 2,2’-bipyridine), has been prepared by the reaction of 1,4-phenylenediacetic acid, 2,2’-bipyridine, Cu(CH3COO)2·H2O and NaOH. The composition of A1 was determined by elemental analysis, IR spectra and single crystal X-ray diffraction. The results of characterization show that each Cu(II) atom adopts six-coordination and forms a distorted octahedral configuration. The catalytic activity and reusability of A1 catalyst for A3 coupling reaction of benzaldehyde, piperidine, and phenylacetylene have been investigated. And the results show that the Cu(II) complex catalyst has good catalytic activity with a maximum yield of 54.3% and stability. Copyright © 2017 BCREC GROUP. All rights reserved

Received: 21st October 2016; Revised: 17th November 2016; Accepted: 22nd November 2016

How to Cite: Li-Hua, W., Lei, L., Xin, W. (2017). Synthesis, Structural Characterization and Catalytic Activity of A Cu(II) Coordination Polymer Constructed from 1,4-Phenylenediacetic Acid and 2,2’-Bipyridine. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (1): 113-118 (doi:10.9767/bcrec.12.1.735.113-118)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.12.1.735.113-118

 

Keywords: Cu(II) coordination polymer; Preparation; Structural characterization; Catalytic activity
Funding: Wang Li-Hua, Weifang University

Article Metrics:

  1. You, L.X., Zhu, W.L., Wang, S.J., Xiong, G., Ding, F., Ren, B.Y., Dragutan, I., Dragutan, V., Sun, Y.G. (2016). High Catalytic Activity in Aqueous Heck and Suzuki-Miyaura Reactions Catalyzed by Novel Pd/Ln Coordination Polymers Based on 2,2’-Bipyridine-4,4’-dicarboxylic Acid as a Heteroleptic Ligand. Polyhedron, 115: 47-53
  2. Chen, M.M., Li, H.X., Lang, J.P. (2016). Two Coordination Polymers and Their Silver(I) Doped Species: Synthesis, Characterization, and High Catalytic Activity for the Photodegradation of Various Organic Pollutants in Water. European Journal of Inorganic Chemistry, 2016: 2508-2515
  3. Yuan, F., Zhang, L., Hua, H.M., Bai, C., Xue, G.L. (2017). Four New Coordination Polymers based on Carboxyphenyl- Substituted Dipyrazinylpyridine Ligand: Syntheses, Structures, magnetic and luminescence Properties. Journal of Molecular Structure, 1128: 385-390
  4. Wang, X.P., Han, L.L., Lin, S.J., Li, X.Y., Mei, K., Sun, D. (2016). Synthesis, Structure and photoluminescence of Three 2D Cd(II) Coordination Polymers Based on Varied Dicarboxylate Ligand. Journal of Coordination Chemistry, 69(2): 286-294
  5. Paul, M., Dastidar, P. (2016). Coordination Polymers Derived From Non-Steroidal Anti-inflammatory Drugs for Cell Imaging and Drug Delivery. Chemistry-A European Journal, 22(3): 988-998
  6. Zhao, S.N., Su, S.Q., Song, X.Z., Zhu, M., Hao, Z.M., Meng, X., Song, S.Y., Zhang, H.J. (2013). A Series of Metal-Organic Frameworks Constructed From a V-shaped Tripodal Carboxylate Ligand: Syntheses, Structures, Photoluminescent, and Magnetic Properties. Crystal Growth & Design, 13(7): 2756-2765
  7. Marino, N., Armentano, D., Mastropietro, T.F., Julve, M., Lloret, F., Munno, G. D. (2010). A Copper(II) Cytidine Complex as a Building Unit for the Construction of an Unusual Three Dimensional Coordination Polymer. Crystal Growth & Design, 10(4): 1757-1761
  8. García, F., Perles, J., Zamora, F., Amo-Ochoa, P. (2016). Rhodium and Copper 6-methylpicolinate Complexes, Structural Diversity and Supramolecular. Inorganica Chimica Acta, 453: 574-582
  9. Liu, L.L., Zhang, X., Gao, J.S., Xu, C.M. (2012). Engineering Metal–organic Frameworks Immobilize Gold Catalysts for Highly Efficient One-pot Synthesis of Propargylamines. Green Chemistry, 14: 1710-1720
  10. Li, P., Wang, L. (2007). A Highly Efficient Three-component Coupling of Aldehyde, Terminal Alkyne, and Amine via C-H Activation Catalyzed by Reusable Immobilized Copper in Organic-inorganic Hybrid Materials under Solvent-free Reaction Conditions. Tetrahedron, 63(25): 5455-5459
  11. Dyker, G. (1999). Transition Metal Catalyzed Coupling Reactions under C–H Activation. Angewandte Chemie International Edition, 38: 1698-1712
  12. Liu, L.L., Tai, X.S., Zhang, N.N., Meng, Q.G., Xin, C.L. (2016). Supported Au/MIL-53(Al): A Reusable green solid Catalyst for the Three-component Coupling Reaction of Aldehyde, Alkyne, and Amine. Reaction Kinetics, Mechanisms, and Catalysis, 119: 335-348
  13. Zhang, X., Corma. A. (2008). Efficient Three-component Coupling Reaction. Angewandte Chemie International Edition, 47: 4358-4361
  14. Murai, T., Mutoh, Y., Ohta, Y., Murakami. M. (2004). Synthesis of Tertiary Propargylamines by Sequential Reactions of in Situ Generated Thioiminium Salts with Organolithium and magnesium Reagents. Journal of the American Chemical Society, 126: 5968-5969
  15. Borah, B.J., Borah, S.J., Saikia, K., Dutta, D.K. (2014). Efficient One-pot Synthesis of Propargylamines Catalysed by Gold Nanocrystals Stabilized on Montmorillonite. Catalysis Science & Technology, 4(11): 4001-4009
  16. Berrichi, A., Bachir, R., Benabdallah, M., Choukchou-Braham, N. (2015). Supported Nano Gold Catalyzed Three-component Coupling Reactions of Amines, Dichloromethane and Terminal Alkynes (AHA). Tetrahedron Letters, 56: 1302-1306
  17. Liu, L.L., Tai, X.S., Liu, M.F., Li, Y.F., Feng, Y.M., Sun, X.R. (2015). Supported Au/MOF-5: A Highly Active Catalyst for Three-component Coupling Reactions. CIESC Journal, 66(5): 1738-1747
  18. Villaverde, G., Corma, A., Iglesias, M., Sánchez, F. (2012). Heterogenized Gold Complexes: Recoverable Catalysts for Multicomponent Reactions of Aldehydes, Terminal Alkynes, and Amines. ACS Catalysis, 2(3): 399-406
  19. Wei, C., Li, Z., Li, C.J. (2003). The First Silver-Catalyzed Three-Component Coupling of Aldehyde, Alkyne, and Amine. Organic Letters, 5: 4473-4475
  20. Tai, X.S., Liu, L.L., Yin, J. (2014). Synthesis, Crystal Structure of Tetra-Nuclear Macrocyclic Cu(II) Complex Material and Its Application as Catalysts for A3 Coupling Reaction. Journal of Inorganic and Organometallic Polymers and Materials, 24(6): 1014-1020
  21. Sheldrick, G.M. (1997). SHELXL-97, Program for Crystal Structure Solution. University of Göttingen: Göttingen, Germany
  22. Sheldrick, G.M. (1997). SHELXTL-97, Program for Crystal Structure Refinement. University of Göttingen: Göttingen, Germany
  23. Gaur, A., Klysubun, W., Soni, B., Shrivastava, B.D., Prasad, J., Srivastava, K. (2016). Identification of Different Coordination Geometries by XAFS in Copper(II) Complexes with Trimesic Acid. Journal of Molecular Structure, 1121: 119-127

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