DOI: https://doi.org/10.9767/bcrec.15.2.6693.348-366

One-Pot Access to Diverse Functionalized Pyran Annulated Heterocyclic Systems Using SCMNPs@BPy-SO3H as a Novel Magnetic Nanocatalyst

1Hunan Polytechnic of Enviroment and Biology, Hunan, 421005, China

2Department of Chemistry, College of Education, University of Al-Qadisiyah, Iraq

Received: 10 Dec 2019; Revised: 18 Mar 2020; Accepted: 24 Mar 2020; Available online: 30 Jul 2020; Published: 1 Aug 2020.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2020 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

The SCMNPs@BPy-SO3H catalyst was prepared and characterized using Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Vibrating Sample Magnetometry (VSM), Energy Dispersive X-ray Spectroscopy (EDX), X-ray Diffraction (XRD), and Scanning Electron Microscopy (SEM). Afterwards, its capability was efficiently used to promote the one-pot, three-component synthesis of pyrano[2,3-c]pyrazole and 2-amino-3-cyano-pyrano[3,2-c]chromen-5(4H)-one derivatives. The strategy resulted in the desired products with excellent yields and short reaction times. The SCMNPs@BPy-SO3H catalyst was readily recovered using a permanent magnetic field and it was reused in six runs with a slight decrease in catalytic activity. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

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Keywords: Multicomponent reaction; Solvent-free conditions; Magnetic nanocatalyst; SCMNPs@BPy-SO3H, pyrano[2,3-c]pyrazole; 2-amino-3-cyano-pyrano[3,2-c]chromen-5(4H)-one
Funding: Hunan Polytechnic of Enviroment and Biology

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