Effects of Cobalt and Chromium Loadings to The Catalytic Activities of Supported Metal Catalysts in Methane Oxidation

*Mardwita Mardwita scopus  -  Chemical Engineering Department, Faculty of Engineering, Universitas Muhammadiyah Palembang, Indonesia
Eka Sri Yusmartini  -  Chemical Engineering Department, Faculty of Engineering, Universitas Muhammadiyah Palembang, Indonesia
Nidya Wisudawati  -  Industrial Engineering Department, Faculty of Engineering, Universitas Muhammadiyah Palembang, Indonesia
Received: 14 Nov 2019; Revised: 13 Jan 2020; Accepted: 15 Jan 2020; Published: 1 Apr 2020; Available online: 28 Feb 2020.
Open Access Copyright (c) 2020 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

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Abstract

A series of alumina supported cobalt and chromium catalysts with different metal loadings were prepared by impregnation method. Six types of alumina supported cobalt and chromium catalysts contained 5 wt%, 10 wt%, and 15 wt% loadings were produced and tested in methane oxidation. The catalysts were characterized by using x-ray diffraction (XRD) and carbon monoxide chemisorption (CO chemisorption). The XRD results do not confirmed any features of cobalt and chromium metal. The metal sizes for both catalysts were larger in high loading as shown by CO chemisorption results. Methane conversion results showed that the conversion increases with increasing the metal loading, however supported chromium catalysts were higher in activities compared to supported cobalt catalysts. Thermal stability tests on 15 wt% Co/Al and 15 wt% Cr/Al catalyst showed that supported chromium catalyst is more stable and maintain the particle size due to its strong interaction with support, while supported cobalt catalyst decrease in methane conversion due to deactivation of the catalyst. Copyright © 2020 BCREC Group. All rights reserved

 

Keywords: Methane Oxidation; Cobalt Catalyst; Chromium Catalyst; Deactivation

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  1. Farrauto, R.J. (2012). Low-Temperature Oxidation of Methane. Science, 337, 769-660.
  2. Stakheev, A.Y., Batkin, A.M., Teleguina, N.S., Bragina, G.O., Zaikovsky, V.I., Prosvirin, I.P., Khudorozhkov, A.K., Bukhtiyarov, V.I. (2013). Particle Size Effect on CH4 Oxidation over Noble Metals: Comparison of Pt and Pd Catalysts. Topics in Catalysis, 56(1-8), 306-310.
  3. Geng, H., Zhang. L., Yang, Z., Yan, Y., Ran, J. (2018). Effect of Pd/Pt Ratio on the Reactivity of Methane Catalytic Combustion in Bumetallic Pd-Pt Catalyst. International Journal of Hydrogen Energy, 43(24), 11069-11078.
  4. Cihlar, J.Jr., Vrba, R., Castkova, K., Cihlar, J. (2017). Effect of Transition Metal on Stability and Activity of La-Ca-M-(Al)-O (M = Co, Cr, Fe and Mn) Perovskite Oxides during Partial Oxidation of Methane. International Journal of Hydrogen Energy, 42(31), 19920-19934.
  5. Lucre¢dio, A.F., Jerkiewicz, G., Assaf, E.M. (2008). Cobalt Catalysts Promoted with Cerium and Lanthanum Applied to Partial Oxidation of Methane Reactions. Applied Catalysis B: Environmental, 84, 106-111.
  6. Yasuda, S., Iwakura, A., Hirata, J., Kanno, M., Ninomiya, W., Otomo, R., Kamiya, Y. (2019). Strong Bronsted Acid-Modified Chromium Oxide as an Efficient Catalyst for the Selective Oxidation of Methacrolein to Methacrylic Acid. Catalysis Communications, 125, 43-47.
  7. Troiani, A., Rosi, M., Garoli, S., Salvitti, C., de Petris, G. (2019). Effective Redox Reactions by Chromium Oxide Anions: Sulfur Dioxide Oxidation in the Gas Phase. International Journal of Mass Spectrometry, 436, 18-22.
  8. Jiang, Z., Yu, J., Cheng, J., Xiao, T., Jones, M.O. (2010). Catalytic Combustion of Methane Over Mixed Oxides Derived from Co-Mg/Al Ternary Hydrotalcites. Fuel Processing Technology, 91, 97-102.
  9. Santos, M.S., Neto, R.C.R., Noronha, F.B., Bargiela, P., Carneiro da Rocha, M.G., Resini, C., Carbo-Argibay, E., Frety, R., Brandao, S.T. (2017). Perovskite as Catalyst Precursors in the Partial Oxidation of Methane: The Effect of Cobalt, Nickel and Pretreatment. Catalysis Today, 299, 229-241.
  10. Fakeeha, A.H., Al-Fatesh, A.S., Khan, W.U., Ibrahim, A.A., Al-Otaibi, R.L., Abasaeed, A.E. (2016). Suitability of Titania and Magnesia as Support for Methane Decomposition Catalyst Using Iron as Active Materials. Journal of Chemical Engineering of Japan, 49(6), 552-562.
  11. Tauster, S.J., Fung, S.C., Baker, R.T.K., Horsley, J.A. (1982). Strong Interactions in Supported-Metal Catalysts. Science, New Series, 211(4487), 1121-1125.
  12. Tauster, S.J. (1987). Strong Metal-Support Interactions. Accounts of Chemical Research, 20(1), 389-394.
  13. Coq, B., Figueras, F., Hub, S., Tournigant, D. (1995). Effect of the Metal-Support Interaction on the Catalytic Properties of Palladium for the Conversion of Difluorodichloromethane with Hydrogen: Comparison of Oxides and Fluorides as Supports. The Journal of Physical Chemistry, 99, 11159-11166.
  14. Bonanni, S., Ait-Mansour, K., Brune, H., Harbich, W. (2011). Overcoming the Strong Metal-Support Interaction State: CO Oxidation on TiO2(110)-Supported Pt Nanoclusters. ACS Catalysis, 1, 385-389.
  15. Najafishirtari, S., Guglieri, C., Marras, S., Scarpellini, A., Brescia, R., Prato, M., Righi, G., Franchini, A., Magri, A., Manna, L., Colombo, M. (2018). Metal-Support Interaction in Catalysis: The Influence of the Morphology of A Nano-Oxide Domain on Catalytic Activity. Applied Catalysis B: Environmental, 237, 753-762.
  16. Lee, K., Burt, S.P., Carrero, C.A., Alba-Rubio, A.C., Ro, I., O’Neill, B.J., Kim., H.J., Jackson, D.H.K., Kuech, T.F., Hermans, I., Dumesic, J.A., Huber, G.W. (2015). Stabilizing Cobalt Catalysts for Aqueous-Phase Reactions by Strong Metal-Support Interaction. Journal of Catalysis, 330, 19-27.
  17. Dey, S., Dhal, G.C., Mohan, D., Prasad, R. (2017). Effect of Preparation Conditions on the Catalytic Activity of CuMnOx Catalysts for CO Oxidation. Bulletin of Chemical Reaction Engineering & Catalysis, 12(3), 431-451.
  18. Anggoro, D.D., Hidayati, N., Buchori, L., Mundriyastutik, Y. (2016). Effect of Co and Mo Loading by Impregnation and Ion Exchange Methods on Morphological Properties of Zeolite Y Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 11(1), 75-83.
  19. Darda, S., Pachatouridou, E., Lappas, A., Lliopoulou, E. (2019). Effect of Preparation Method of Co-Ce Catalysts on CH4 Combustion. Catalysts, 9(3), 219-306.
  20. Mardwita, M., Yusmartini, E.S., Wisudawati, N. (2019). Effects of Calcination Temperatures on the Catalytic Activities of Alumina Supported Cobalt and Chromium Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis, 14(3), 654-659.
  21. Laugel, G., Arichi, J., Bernhardt, P., Moliere, M., Kiennemann, A., Garin, F., Louis, B. (2009). Preparation and Characterisation of Metal Oxides Supported on SBA-15 as Methane Combustion Catalysts. Comptes Rendus Chimie, 12, 731-739.
  22. Vedyagin, A., Volodin, A.M., Kenzhin, R.M., Stoyanovskii, V.O., Shubin, Y.V., Plusnin, P.E., Mishakov, I.V. (2017). Effect of Metal-Metal and Metal-Support Interaction on Activity and Stability of Pd-Rh/Alumina in CO Oxidation. Catalysis Today, (293-294), 73-81.
  23. Zhang, J., Zhang, S., Cai, W., Zhong, Q. (2013). Effect of Chromium Oxide as Active Site over TiO2-PILC For Selective Catalytic Oxidation of NO. Journal of Environmental Science, 25(12), 2492-2497.
  24. Sharma, S., Sharma, N.D., Choudhary, N., Verma, M.K., Singh, D. (2017). Chromium Incorporated Nanocrystalline Cobalt Ferrite Synthesized by Combustion Method: Effect of Fuel and Temperature. Ceramics International, 43(16), 13401-13410.
  25. Nguyen, B.N.T., Leclerc, C.A. (2007). Metal Oxide as Combustion Catalysts for A Stratified, Dual Bed Partial Oxidation Catalyst. Journal of Power Sources, 163(2), 623-629.
  26. Prates, L.M., Ferreira, G.B., Cameiro, J.W.M., De Almeida, W.B., Cruz, M.T.M. (2017). Effect of the Metal-Support Interaction on the Adsorption of NO on Pd4/g-Al2O3: A Density Functional Theory and Natural Bond Orbital Study. The Journal of Physical Chemistry C, 121(26), 14147-14155.
  27. Wu, Y., Li, G., Hu, W., Huang F., Chen, J., Zhong, L., Chen, Y. (2018). Effect of Mox (M = Ce, Ni, Co, Mg) on Activity and Hydrothermal Stability of Pd Supported on ZrO2-Al2O3 Composite for Methane Lean Combustion. Journal of the Taiwan Institute of Chemical Engineers, 85, 176-185.
  28. Das, T., Deo, G. (2012). Effect of Metal Loading and Support for Supported Cobalt Catalyst. Catalysis Today, 198, 116-124.
  29. Araujo, J.C.S., Oton, L.F., Oliveira, A.C., Lang, R., Otubo, L., Bueno, J.M.C. (2019). On the Role of Size Controlled Pt Particles in Nanostructured Pt-Containing Al2O3 Catalysts for Partial Oxidation of Methane. International Journal of Hydrogen Energy, 44(50), 27329-27342.
  30. Muraya, K., Mahara, Y., Ohyama, J., Yamamoto, Y., Arai, S., Satsuma, A. (2017). The Metal-Support Interaction Concerning the Particle Size Effect of Pd/Al2O3 on Methane Combsution. Angewandte International Edition Chemie, 56(50), 15993-15997.
  31. Pradier, C.M., Rodrigues, F., Marcus, P., Landau, M.V., Kaliys, M.L., Gutman, A., Herskowitz, M. (2000). Supported Chromia Catalysts for Oxidation of Organic Compounds The State of Chromia Phase and Cataytic Performance. Applied Catalysis B: Environmental, 27, 73-85.
  32. Zhao, J., Matsune, H., Takenaka, S., Kishida, M. (2017). Rapid and Efficient Catalytic Oxidation of As(III) with Oxygen over a Pt Catalyst at Increased Temperature. Chemical Engineering Journal, 325, 270-278.
  33. Chen, J., Zhang, X., Arandiyan, H., Peng, Y., Chang, H., Li, J. (2013). Low Temperature Complete Combustion of Methane over Cobalt Chromium Oxides Catalysts. Catalysis Today, 201, 12-18.
  34. Camus, E., Wanderka, N., Welzel, S., Materna-Morris, E., Wollenberger, H. (1998). Chromium Redistribution in Thermally Aged and Irradiated Ferritic-Martensitic Steels. Materials Science and Engineering A, 250, 37-42.
  35. Zavyalova, U., Scholz, P., Ondruschka, B. (2007). Influence of Cobalt Precursor and Fuels on the Performance of Combustion Synthesized Co3O4/g-Al2O3 Catalysts for Total Oxidation of Methane. Applied Catalysis A: General, 323, 226-233.
  36. Pelaez, R., Bryce, E., Marin, P., Ordonez, S. (2018). Catalyst Deactivation in the Direct Synthesis of Dimethyl Ether from Syngas Over CuO/ZnO/Al2O3 and g-Al2O3 Mechanical Mixtures. Fuel Processing Technology, 179, 378-386.
  37. Istadi, I., Anggoro, D.D., Amin, N.A.S., Ling, D.H.W. (2011). Catalyst deactivation simulation through carbon deposition in carbon dioxide reforming over Ni/CaO-Al2O3 catalyst. (2011). Bulletin of Chemical Reaction Engineering & Catalysis, 6(2), 129-136. doi: 10.9767/bcrec.6.2.1213.129-136
  38. Fu, Q., Wagner, T., Olliges, S., Carstanjen, H.D. (2005). Metal-Oxide Interfacial Reactions: Encapsulation of Pd on TiO2(110). The Journal of Physical Chemistry B, 109(2), 944-951.
  39. Li, Y., Lousada, C.M., Korzhavyi, P.A. (2014). The Nature of Hydrogen in g-Alumina. Journal of Applied Physics, 115(20), 203514-1-203514-11.
  40. Yokoo, K., Matsune, H., Kishida, M., Tatebayashi, J., Yamamoto, T. (2019). Promoting Effect of Water Vapor on Particle Matter Combustion in A Low-Temperature Continuous Regeneration Type PM Removal Device Using Fluidized Bed. Power Technology, 355, 657-666.

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