Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol

Norazimah Harun -  Faculty of Chemical Engineering & Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pahang,, Malaysia
Jolius Gimbun -  Faculty of Chemical Engineering & Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pahang, Centre of Excellence for Advanced Research in Fluid Flow (CARIFF), Universiti Malaysia Pahang, 26300 Gambang, Pahang,, Malaysia
Mohammad Tazli Azizan -  Department of Chemical Engineering, Faculty of Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak Darul Ridzuan,, Malaysia
*Sumaiya Zainal Abidin -  Faculty of Chemical Engineering & Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pahang, Centre of Excellence for Advanced Research in Fluid Flow (CARIFF), Universiti Malaysia Pahang, 26300 Gambang, Pahang,, Malaysia
Received: 20 Jun 2016; Published: 20 Aug 2016.
Open Access Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis
Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Citation Format:
Cover Image
Article Info
Section: The International Conference on Fluids and Chemical Engineering (FluidsChE 2015)
Language: EN
Full Text:
In 2016: BCREC Volume 11 Issue 2 Year 2016 (SCOPUS and Web of Science Indexed, August 2016)
Statistics: 781 288
Abstract

The carbon dioxide (CO2) dry reforming of glycerol for syngas production is one of the promising ways to benefit the oversupply crisis of glycerol worldwide. It is an attractive process as it converts carbon dioxide, a greenhouse gas into a synthesis gas and simultaneously removed from the carbon biosphere cycle. In this study, the glycerol dry reforming was carried out using Silver (Ag) promoted Nickel (Ni) based catalysts supported on silicon oxide (SiO2) i.e. Ag-Ni/SiO2. The catalysts were prepared through wet impregnation method and characterized by using Brunauer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), and Thermo Gravimetric (TGA) analysis. The experiment was conducted in a tubular reactor which condition fixed at 973 K and CO2:glycerol molar ratio of 1, under atmospheric pressure. It was found that the main gaseous products are H₂, CO and CH4 with H₂:CO molar ratio < 1.0. From the reaction study, Ag(5)-Ni/SiO2 results in highest glycerol conversion and hydrogen yield, accounted for 32.6% and 27.4%, respectively. Copyright © 2016 BCREC GROUP. All rights reserved

Received: 22nd January 2016; Revised: 22nd February 2016; Accepted: 23rd February 2016

How to Cite: Harun, N., Gimbun, J., Azizan, M.T., Abidin S.Z. (2016). Characterization of Ag-promoted Ni/SiO2 Catalysts for Syngas Production via Carbon Dioxide (CO2) Dry Reforming of Glycerol. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2): 220-229 (doi:10.9767/bcrec.11.2.553.220-229)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.2.553.220-229

Article Metrics: (click on the button below to see citations in Scopus)

cited by count 

Keywords
Glycerol; Dry reforming; Syngas; Nickel-based catalysts; Silicon Oxide

Article Metrics:

  1. Adhikari, S., Fernando, S., Gwaltney, S., Filipto, S., Markbricka, R., Steele, P. and Haryanto, A. (2007). A thermodynamic analysis of hydrogen production by steam reforming of glycerol. International Journal of Hydrogen Energy, 32(14): 2875-2880.
  2. Lin, Y.C. (2013). Catalytic valorization of glycerol to hydrogen and syngas. International Journal of Hydrogen Energy, 38(6): 2678-2700.
  3. Wang, X., Li, M., Wang, M., Wang, H., Li, S., Wang, S. and Ma, X. (2009). Thermodynamic analysis of glycerol dry reforming for hydrogen and synthesis gas production. Fuel, 88(11): 2148-2153.
  4. Lee, H. C., Siew, K. W., Gimbun, J. and Cheng, C. K. (2013). Application of Cement Clinker as Ni-Catalyst Support for Glycerol Dry Reforming. Bulletin of Chemical Reaction Engineering & Catalysis, 8(2): 137-144.
  5. Siew, K.W., Lee, H.C., Gimbun, J. and Cheng, C. K. (2014). Characterization of La-promoted Ni/Al2O3 catalysts for hydrogen production from glycerol dry reforming. Journal of Energy Chemistry, 23(1): 15-21.
  6. Parizotto, N.V., Rocha, K.O., Damyanova, S., Passos, F.B., Zanchet, D., Marques, C.M.P. and Bueno, J.M.C. (2007). Alumina-supported Ni catalysts modified with silver for the steam reforming of methane: Effect of Ag on the control of coke formation. Applied Catalysis A: General, 330:12-22
  7. Yu, M., Zhu, Y., Lu, Y., Tong, G., Zhu, K. and Zhou, X. (2015). The promoting role of Ag in Ni-CeO2 catalyzed CH4-CO2 dry reforming reaction. Applied Catalysis B: Environmental, 165 (2015): 43-56.
  8. Chen, M., Zhang, D., Thompson, L.T. and Ma, Z. (2011). Catalytic properties of Ag promoted ZnO/Al2O3 catalysts for hydrogen production by steam reforming of ethanol. International Journal of Hydrogen Energy, 36: 7516-7522.
  9. Siew, K.W., Lee, H.C., Gimbun, J. and Cheng, C.K. (2013). Hydrogen production via glycerol dry reforming over La-Ni/Al2O3 catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 8(2): 160-166.
  10. Diaz, G.C., Tapanes, N.C.O., Camara, L.D.T and Aranda, D.A.G. (2014). Glycerol conversion in the experimental study of catalytic hydrolysis of triglycerides for fatty acids production using Ni or Pd on Al2O3 or SiO2. Renewable Energy, 64: 113-122
  11. Guo, J., Hou, Z., Gao, J. and Zheng, X. (2008). Syngas production via combined oxy-CO2 reforming of methane over Gd2O3-modified Ni/SiO2 catalysts in a fluidized-bed reactor. Fuel, 87(7): 1348-1354.
  12. Alhassan, F.H., Rashid, U., Al-Qubaisi, M.S., Rasedee, A. and Taufiq-Yap, Y.H. (2014). The effect of sulfate contents on the surface properties of iron–manganese doped sulfated zirconia catalysts. Powder Technology. 253: 809–813
  13. Estellé, J., Salagre, P., Cesteros, Y., Serra, M., Medina, F.,& Sueiras, J.E. (2003). Comparative study of the morphology and surface properties of nickel oxide prepared from different precursors. Solid State Ionics, 156: 233-243.
  14. Acrotumapathy, V., Dai-Viet, N. V., Chesterfield, D., Cao, T. Tin, Siahvashi, A., Lucien, F.P., and Adesina, A.A. (2014). Catalyst design for methane steam reforming. Applied Catalysis A: General. 479: 87-102.
  15. Jeong, H and Kang, M. (2010). Hydrogen production from butane steam reforming over Ni/Ag loaded MgAl2O4 catalyst. Applied Catalysis B: Environmental, 95(3-4): 446-455.
  16. Siew, K.W., Lee, H.C., Gimbun, J. and Cheng, C. K. (2014). Production of CO-rich hydrogen gas from glycerol dry reforming over La-promoted Ni/Al2O3 catalyst. International Journal of Hydrogen Energy, 39: 6927-6936.

Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. 

Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including: use for classroom teaching by Author or Author's institutionand presentation at a meeting or conference and distributing copies to attendees; use for internal training by author's company; distribution to colleagues for their reseearch use; use in a subsequent compilation of the author's works; inclusion in a thesis or dissertation; reuse of portions or extrcats from the article in other works (with full acknowledgement of final article); preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article); voluntary posting on open web sites operated by author or author’s institution for scholarly purposes (follow CC by SA License).

Authors and readers can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (cite to the article or content), provide a link to the license, and indicate if changes were made. If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.

Copyright Transfer Agreement

The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright publishing of the article shall be assigned to Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University as publisher of the journal.

Copyright encompasses exclusive rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations. The reproduction of any part of this journal, its storage in databases and its transmission by any form or media, such as electronic, electrostatic and mechanical copies, photocopies, recordings, magnetic media, etc., will be allowed only with a written permission from Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University, the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of copyright, our journal authors retain (or are granted back) significant scholarly rights.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form BCREC 2016] 


The copyright form should be signed originally and send to the Editorial Office in the form of original mail, scanned document or fax :  

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering and Catalysis
Department of Chemical Engineering, Diponegoro University
Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Telp.: +62-24-7460058, Fax.: +62-24-76480675
E-mail: bcrec[at]live.undip.ac.id