Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts

Nur Nabillah Mohd Arif  -  Faculty of Chemical Engineering & Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pahang,, Malaysia
Dai-Viet N. Vo  -  Faculty of Chemical Engineering & Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pahang,, Malaysia
Mohammad Tazli Azizan  -  Department of Chemical Engineering, Faculty of Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak Darul Ridzuan,, Malaysia
*Sumaiya Zainal Abidin  -  Faculty of Chemical Engineering & Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pah, Malaysia
Received: 19 Jun 2016; Published: 20 Aug 2016.
Open Access Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

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Abstract

Glycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as global warming. This dry reforming reaction has been carried out in a fixed bed batch reactor at 700 °C under the atmospheric pressure for 3 hours. In this experiment, reforming reaction was carried out using Nickel (Ni) as based catalyst and supported with zirconium (ZrO2) and calcium (CaO) oxides. The catalysts were prepared by wet impregnation method and characterized using Bruanaer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Thermo Gravimetric (TGA), and Temperature Programmed Reduction (TPR) analysis. Reaction studies show that 15% Ni/CaO give the highest hydrogen yield and glycerol conversion that peaked at 24.59% and 30.32%, respectively. This result is verified by XRD analysis where this catalyst shows low crystallinity and fine dispersion of Ni species resulted in high specific surface area which gives 44.93 m2/g that is validated by BET.  Copyright © 2016 BCREC GROUP. All rights reserved

Received: 21st January 2016; Revised: 24th February 2016; Accepted: 29th February 2016

How to Cite: Arif, N.M.M., Vo, D.V.N., Azizan,M.T., Abidin S.Z. (2016). Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2): 200-209 (doi:10.9767/bcrec.11.2.551.200-209)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.2.551.200-209

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Keywords: Biodiesel; Glycerol; Dry reforming; Syngas; Ni-based catalyst; Ni/ZrO2; Ni/CaO

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Article Info
Section: The International Conference on Fluids and Chemical Engineering (FluidsChE 2015)
Language: EN
In 2016: BCREC Volume 11 Issue 2 Year 2016 (SCOPUS and Web of Science Indexed, August 2016)
Statistics: 1511 724
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  2. Pompeo, F., Nichio, N.N., Ferretti, O.A., Resasco, D. (2005). Study of Ni Catalysts on Different Supports to Obtain Synthesis Gas. International Journal of Hydrogen Energy, 30: 1399-1405.
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  7. Lin, Y. (2013). Catalytic Valorization of Glycerol to Hydrogen and Syngas. International Journal of Hydrogen Energy, 38(6):2678-2700.
  8. Fan, X., Burton, R., Zhou, Y. (2010). Glycerol (Byproduct of Biodiesel Production) as a Source for Fuels and Chemicals - Mini Review. The Open Fuels & Energy Science Journal, 3: 17-22.
  9. Vaidya, P.D., Rodrigues, A.E. (2009). Glycerol Reforming for Hydrogen Production: A Review. Chemical Engineering Technology, 32(10): 1463-1469.
  10. Luo, N., Zhao, X., Cao, F., Xiao, T., Fan, D. (2007). Thermodynamic Study on Hydrogen Generation from Different Glycerol Reforming Processes. Energy Fuels, 21(6): 3505-3512.
  11. Adhikari, S., Fernando, S., Haryanto, A. (2007). A Comparative Thermodynamic and Experimental Analysis on Hydrogen Production by Steam Reforming of Glycerin. Energy Fuels, 21(4): 2306-2310.
  12. Adhikari, S., Fernando, S., Gwaltney, S.R., To, S.D.F., Bricka, R.M., Steele, P.H., Haryanto, A. (2007). A Thermodynamic Analysis of Hydrogen Production by Steam Reforming of Glycerol. International Journal of Hydrogen Energy, 32(14): 2875–2880.
  13. Lee, H.C., Siew, K.H., Gimbun, J., Cheng, C. K. (2013). Application of Cement Clinker as Ni-Catalyst Support for Glycerol Dry Reforming. Bulletin of Chemical Engineering & Catalysis, 8(2): 137-144.
  14. Siew, K., Lee, H., Gimbun, J., Cheng, C. (2014). Production of CO-rich Hydrogen Gas from Glycerol Dry Reforming over La-promoted Ni/Al2O3 Catalyst. International Journal Of Hydrogen Energy, 39(13): 6927-6936.
  15. Wang, X., Li, M., Wang, M., Wang, H., Li, S., Wang, S., Ma, X. (2009). Thermodynamic Analysis of Glycerol Dry Reforming for Hydrogen and Synthesis Gas Production. Fuel, 88(11): 2148-2153.
  16. Bermúdez, J.M., Fidalgo, B., Arenillas, A., Menéndez, J.A. (2012). CO2 Reforming of Coke Oven Gas over a Ni/g-Al2O3 Catalyst to Produce Syngas for Methanol Synthesis. Fuel, 9: 197-203.
  17. Zhang, Y., Zhang, G., Zhang, B., Guo, F., Sun, Y. (2011). Effects of Pressure on CO2 Reforming of CH4 over Carbonaceous Catalyst. Chemical Engineering Journal, 173(2): 592-597.
  18. Dantas, S.C., Escritori, J.C., Soeres, R.R., Hori, C.E. (2010). Effect of Different Promoters on Ni/CeZrO2 Catalyst for Autothermal Reforming and Partial Oxidation of Methane. Chemical Engineering Journal, 156(2): 380-387.
  19. Saad, J.M., Nahil, M.A., Wu, C., Williams, P.T. (2015). Influence of Nickel-based Catalysts on Syngas Production from Carbon Dioxide Reforming of Waste High Density Polyethylene. Fuel Processing Technology, 138: 156-163.
  20. Liu, S., Xiong, G., Yang, W., Xiu, L., Xiong, G., Li, C. (1999). Partial Oxidation of Ethane to Syngas over Nickel-based Catalysts Modified by Alkali Metal Oxide and Rare Earth Metal Oxide. Catalysis Letter, 63: 167-171.
  21. Wei, J.M., Xu, B.Q., Li, J.L., Cheng, Z.X., Zhu Q.M. (2000). Highly Active and Stable Ni/ZrO2 Catalyst for Syngas Production by CO2 Reforming of Methane. Applied Catalyst, 196(2): 167-172.
  22. Chang, J.S. Park, S.E., Yoo, J.W. , Park, J.N. (2000). Catalytic Behavior of Supported KNiCa Catalyst and Mechanistic Consideration for Carbon Dioxide Reforming of Methane, Journal of Catalysis. 195(1): 1-11.
  23. Dias, J.A.C., Assaf, J.M. (2003). Influence of Calcium Content in Ni/CaO/g-Al2O3 catalysts for CO2- reforming of methane. Catalysis Today, 85(1): 60-68.
  24. Ranjbar, A., Rezaei, M. (2012). Preparation of Nickel Catalysts Supported on CaO.2Al2O3 for Methane Reforming with Carbon Dioxide. International Journal of Hydrogen Energy, 37(8): 6362:6356.
  25. Quincoces, C., Dicundo, S., Alvarez, A.M., Gonzalez M.G. (2001). Effect of Addition of CaO on Ni/Al2O3 Catalysts over CO2 Reforming of Methane. Materials Letters, 50(1):21-27.
  26. Sheng, W, Jun, K.W., Roh, H.S., Liu, Z.W., Park, S.E. (2002). Comparative Study on Partial Oxidation of Methane over Ni/ZrO2, Ni/CeO2 and Ni/Ce-ZrO2 Catalysts. Catalysis Letter, 78(4): 215–22.
  27. Pompeo, F., Nichio, N.N., Souza, M.M.V.M., Cesar, D.V., Ferretti, O.A., Schmal, M. (2007). Study on Ni and Pt Catalysts Supported on α-Al2O3 and ZrO2 Applied in Methane Reforming with CO2. Applied Catalysis A: General, 316(2): 175-183.
  28. Therdthianwong, S., Therdthianwong, A., Siangchin, C., Yongprapat, S. (2008). Synthesis Gas Production from Dry Reforming of Methane over Ni/Al2O3 Stabilized by ZrO2. International Journal of Hydrogen Energy, 33(3): 991-999.
  29. Yang, X., Wang, X, Gao, G., Wendurima, Liu, E., Shi, Q., Zhang, J., Han, C., Wang, J., Lu, H., Liu, J., Tong, M. (2013). Nickel on a Macro-mesoporous Al2O3-ZrO2 Core/Shell Nanocomposite as a Novel Catalyst for CO Methanation. International Journal of Hydrogen Energy, 38(32): 13926-13937
  30. Ebshish, A., Yaakob, Z., Narayanan, B., Bshish, A., Wan Daud W R. (2011). The Activity of Ni-based Catalysts on Steam Reforming of Glycerol for Hydrogen Production. International Journal of Integrated Engineering, 3(1): 5-8.
  31. Razaei, M., Alavi, S.M., Sahebdelfar, S., Xinmei L., Qian, L., Yan Z.F. (2007). CO2-CH4 Reforming over Nickel Catalyst Supported on Mesoporous Nanocrystalline Zirconia with High Surface Area. Energy & Fuels, 21(2): 581-589.
  32. Zangouei, M., Moghaddam, A.Z., Arasteh, M. (2010). The Influence of Nickel Loading on Reducibility of NiO/Al2O3 Catalysts Synthesized by Sol-Gel Method. Chemical Engineering Research Bulletin, 14(2): 97-102.
  33. Lucredio, A.F., Jerkiewickz, G., Assaf, E.M. (2007). Nickel Catalysts Promoted with Cerium and Lanthanum to reduce Carbon Formation in Partial Oxidation of Methane Reactions. Applied Catalysis A: General, 333(1): 90-95.
  34. Estelle, J., Salagre, P., Cesteros, Y., Serra, M., Median, F., Sueiras, J.E. (2003). Comparative Study on the Morphology and Surface Properties of Nickel Oxide Prepared from Different Oxides. Solid State Ionics, 156: 233-243.
  35. Pairojpiriyakul, T., Croiset, E., Kiatkittipong, K., Kiatkittipong, W., Arpornwichanop, A., Assabumrungrat, S. (2014). Catalytic Reforming of Glycerol in Supercritical Water with Nickel-based Catalysts. International Journal of Hydrogen Energy, 39(27): 14739-14750.
  36. Berko, A., Majzik, Z., Kiss, A.M. (2007). Low Temperature CO Oxidation on Differently Prepared TiO2 (110) supported Au catalysts. Journal of Physics: Conference Series, 61: 110-114.
  37. Goula, M.A., Lemonidou, A.A., Efstathiou, A.M. (1996). Characterization of Carbonaceous Species formed during Reforming of CH4 with CO2 over Ni/CaO-Al2O3 Catalysts Studied by Various Transient Techniques. Journal of Catalysis, 161: 626-640.
  38. Lee, H.C., Siew, K.H., Gimbun, J., Cheng C. K. (2014). Synthesis and Characterisation of Cement Clinker-supported Nickel Catalyst for Glycerol Dry Reforming. Chemical Engineering Journal, 255: 245-256.

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