DOI: https://doi.org/10.9767/bcrec.11.2.551.200-209

Carbon Dioxide Dry Reforming of Glycerol for Hydrogen Production using Ni/ZrO2 and Ni/CaO as Catalysts

1Faculty of Chemical Engineering & Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pahang,, Malaysia

2Department of Chemical Engineering, Faculty of Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak Darul Ridzuan,, Malaysia

3Centre of Excellence for Advanced Research in Fluid Flow (CARIFF),Universiti Malaysia Pahang, 26300 Gambang, Pahang,, Malaysia

Received: 21 Jan 2016; Revised: 24 Feb 2016; Accepted: 29 Feb 2016; Available online: 30 Jun 2016; Published: 20 Aug 2016.
Editor(s): BCREC JM
Open Access Copyright (c) 2016 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

Glycerol, byproduct from the biodiesel production can be effectively utilized as the promising source of synthesis gas (syngas) through a dry reforming reaction. Combination of these waste materials with greenhouse gases which is carbon dioxide (CO2) will help to reduce environmental problem such as global warming. This dry reforming reaction has been carried out in a fixed bed batch reactor at 700 °C under the atmospheric pressure for 3 hours. In this experiment, reforming reaction was carried out using Nickel (Ni) as based catalyst and supported with zirconium (ZrO2) and calcium (CaO) oxides. The catalysts were prepared by wet impregnation method and characterized using Bruanaer-Emmett-Teller (BET) surface area, Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), Thermo Gravimetric (TGA), and Temperature Programmed Reduction (TPR) analysis. Reaction studies show that 15% Ni/CaO give the highest hydrogen yield and glycerol conversion that peaked at 24.59% and 30.32%, respectively. This result is verified by XRD analysis where this catalyst shows low crystallinity and fine dispersion of Ni species resulted in high specific surface area which gives 44.93 m2/g that is validated by BET.  

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Keywords: Biodiesel; Glycerol; Dry reforming; Syngas; Ni-based catalyst; Ni/ZrO2; Ni/CaO

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Section: The International Conference on Fluids and Chemical Engineering (FluidsChE 2015)
Language : EN
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  17. Zhang, Y., Zhang, G., Zhang, B., Guo, F., Sun, Y. (2011). Effects of Pressure on CO2 Reforming of CH4 over Carbonaceous Catalyst. Chemical Engineering Journal, 173(2): 592-597
  18. Dantas, S.C., Escritori, J.C., Soeres, R.R., Hori, C.E. (2010). Effect of Different Promoters on Ni/CeZrO2 Catalyst for Autothermal Reforming and Partial Oxidation of Methane. Chemical Engineering Journal, 156(2): 380-387
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  20. Liu, S., Xiong, G., Yang, W., Xiu, L., Xiong, G., Li, C. (1999). Partial Oxidation of Ethane to Syngas over Nickel-based Catalysts Modified by Alkali Metal Oxide and Rare Earth Metal Oxide. Catalysis Letter, 63: 167-171
  21. Wei, J.M., Xu, B.Q., Li, J.L., Cheng, Z.X., Zhu Q.M. (2000). Highly Active and Stable Ni/ZrO2 Catalyst for Syngas Production by CO2 Reforming of Methane. Applied Catalyst, 196(2): 167-172
  22. Chang, J.S. Park, S.E., Yoo, J.W. , Park, J.N. (2000). Catalytic Behavior of Supported KNiCa Catalyst and Mechanistic Consideration for Carbon Dioxide Reforming of Methane, Journal of Catalysis. 195(1): 1-11
  23. Dias, J.A.C., Assaf, J.M. (2003). Influence of Calcium Content in Ni/CaO/g-Al2O3 catalysts for CO2- reforming of methane. Catalysis Today, 85(1): 60-68
  24. Ranjbar, A., Rezaei, M. (2012). Preparation of Nickel Catalysts Supported on CaO.2Al2O3 for Methane Reforming with Carbon Dioxide. International Journal of Hydrogen Energy, 37(8): 6362:6356
  25. Quincoces, C., Dicundo, S., Alvarez, A.M., Gonzalez M.G. (2001). Effect of Addition of CaO on Ni/Al2O3 Catalysts over CO2 Reforming of Methane. Materials Letters, 50(1):21-27
  26. Sheng, W, Jun, K.W., Roh, H.S., Liu, Z.W., Park, S.E. (2002). Comparative Study on Partial Oxidation of Methane over Ni/ZrO2, Ni/CeO2 and Ni/Ce-ZrO2 Catalysts. Catalysis Letter, 78(4): 215–22
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  36. Berko, A., Majzik, Z., Kiss, A.M. (2007). Low Temperature CO Oxidation on Differently Prepared TiO2 (110) supported Au catalysts. Journal of Physics: Conference Series, 61: 110-114
  37. Goula, M.A., Lemonidou, A.A., Efstathiou, A.M. (1996). Characterization of Carbonaceous Species formed during Reforming of CH4 with CO2 over Ni/CaO-Al2O3 Catalysts Studied by Various Transient Techniques. Journal of Catalysis, 161: 626-640
  38. Lee, H.C., Siew, K.H., Gimbun, J., Cheng C. K. (2014). Synthesis and Characterisation of Cement Clinker-supported Nickel Catalyst for Glycerol Dry Reforming. Chemical Engineering Journal, 255: 245-256

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