Green Synthesis of Cationic Polyacrylamide Composite Catalyzed by An Ecologically Catalyst Clay Called Maghnite-H+ (Algerian MMT) Under Microwave Irradiation

*Rahmouni Abdelkader  -  Laboratory of Polymer Chemistry, Départment of Chemistry, Faculty of Sciences, Oran University, BP 1524.El M’nouar. 31000 Oran,, Algeria
Belbachir Mohammed  -  Laboratory of Polymer Chemistry, Départment of Chemistry, Faculty of Sciences, Oran University, BP 1524.El M’nouar. 31000 Oran,, Algeria
Received: 14 Jun 2016; Published: 20 Aug 2016.
Open Access Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

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Section: Original Research Articles
Language: EN
In 2016: BCREC Volume 11 Issue 2 Year 2016 (SCOPUS and Web of Science Indexed, August 2016)
Statistics: 1147 471
Abstract

In this study, a novel green cationic hydrogel of cationic polyacrylamide composite have been prepared and investigated. The synthesis of green cationic polyacrylamide composite was evaluated for its solubility in water. The reactions were performed using acrylamide monomer, solvent, catalyst (clay fin called maghnite) and solution of  H2SO4 (0.25 M), with the system under microwave irradiation (160 ºC) for 4 min. Major factors affecting the polymerization reaction were studied with a view to discover appropriate conditions for preparation of the composite. The cationic polyacrylamide obtained is the subject of future studies of modification and transformation. The resulting polymer has been characterized by a variety of characterization techniques, such as: Fourier Transform Infrared Spectra and 1H NMR spectra.  Copyright © 2016 BCREC GROUP. All rights reserved

Received: 10th June 2015; Revised: 2nd September 2015; Accepted: 5th January 2016

How to Cite: Abdelkader, R., Mohammed, B. (2016). Green Synthesis of Cationic Polyacrylamide Composite Catalyzed by An Ecologically  Catalyst Clay Called Maghnite-H+ (Algerian MMT) Under Microwave Irradiation. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2): 170-175 (doi:10.9767/bcrec.11.2.543.170-175)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.2.543.170-175

 

Keywords: Cationic polyacrylamide; hydrogel; Maghnite-H+; green chemistry; Microwave irradiation

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  1. Synthesis of block copolymers consists on vinylidene chloride and α- Methylstyrene by cationic polymerization using an acid exchanged motmorillonite clay as heterogeneous catalyst (Algerian MMT)
    Moulkheir Ayat, Mohamed Belbachir, Abdelkader Rahmouni, Journal of Molecular Structure, vol. 1139, pp. 381, 2017. doi: 10.1016/j.molstruc.2017.03.056
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