Green Synthesis of Cationic Polyacrylamide Composite Catalyzed by An Ecologically Catalyst Clay Called Maghnite-H+ (Algerian MMT) Under Microwave Irradiation

*Rahmouni Abdelkader -  Laboratory of Polymer Chemistry, Départment of Chemistry, Faculty of Sciences, Oran University, BP 1524.El M’nouar. 31000 Oran,, Algeria
Belbachir Mohammed -  Laboratory of Polymer Chemistry, Départment of Chemistry, Faculty of Sciences, Oran University, BP 1524.El M’nouar. 31000 Oran,, Algeria
Received: 14 Jun 2016; Published: 20 Aug 2016.
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Section: Original Research Articles
Language: EN
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In 2016: BCREC Volume 11 Issue 2 Year 2016 (SCOPUS and Web of Science Indexed, August 2016)
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Abstract

In this study, a novel green cationic hydrogel of cationic polyacrylamide composite have been prepared and investigated. The synthesis of green cationic polyacrylamide composite was evaluated for its solubility in water. The reactions were performed using acrylamide monomer, solvent, catalyst (clay fin called maghnite) and solution of  H2SO4 (0.25 M), with the system under microwave irradiation (160 ºC) for 4 min. Major factors affecting the polymerization reaction were studied with a view to discover appropriate conditions for preparation of the composite. The cationic polyacrylamide obtained is the subject of future studies of modification and transformation. The resulting polymer has been characterized by a variety of characterization techniques, such as: Fourier Transform Infrared Spectra and 1H NMR spectra.  Copyright © 2016 BCREC GROUP. All rights reserved

Received: 10th June 2015; Revised: 2nd September 2015; Accepted: 5th January 2016

How to Cite: Abdelkader, R., Mohammed, B. (2016). Green Synthesis of Cationic Polyacrylamide Composite Catalyzed by An Ecologically  Catalyst Clay Called Maghnite-H+ (Algerian MMT) Under Microwave Irradiation. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2): 170-175 (doi:10.9767/bcrec.11.2.543.170-175)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.2.543.170-175

 

Keywords
Cationic polyacrylamide; hydrogel; Maghnite-H+; green chemistry; Microwave irradiation

Article Metrics:

  1. Ye, Q., Zhang, Z.C., Ge, X.W. (2003). Formation of monodisperse polyacrylamide particles by dispersion polymerization. I.Synthesis and polymer ization kinetics, Journal of Macromolecular Science - Pure and Applied Chemistry 39A(6): 545-556
  2. Cho, M.S., Yoon, K.J., Song, B.K. (2002). Dispersion polymerization of acrylamide in aqueous solution of ammonium sulfate: Synthesis and characterization. Journal of Applied Polymer Science, 83: 1397-1405.
  3. Chen, J., Park, H., Park, K. (1999). Synthesis of Superporous Hydrogels: Hydrogels with Fast Swelling and Superabsorbent Properties, Journal of Biomedical Materials Research, 44: 53-62.
  4. Liu, S.J., Lin, W.F., Chang, B.C., Wu, G.M., Hung, S.W. (1999). Optimizing the Joint Strength of Ultrasonically Welded Thermoplastics, Advances in Polymer Technology, 18: 125-135.
  5. Ye, Q., Zhang, Z.C., and Ge, X.W. (2003). Highly efficient flocculant synthesized through the dispersion copolymerization of water-soluble monomers induced by -ray irradiation: Synthesis and polymerization kinetics. J. Appl. Polym. Sci. 89(8): 2108-2115.
  6. Gemeinhart, R.A., Park, H., Park, K. (2000). Pore Structure of Superporous Hydrogels, Polymers for Advanced Technologies, 11: 617-625.
  7. Ye, Q., Zhang, Z., Ge, X. (2003). Highly efficient flocculant synthesized through the dispersion copolymerization of water-soluble monomers induced by γ-ray irradiation: Synthesis and polymerization kinetics. Journal of Applied Polymer Science, 89: 2108-2115.
  8. Colombani, D. (1997). Chain-growth control in free radical polymerization. Progress in Polymer Science, 22: 1649-1720.
  9. Shan, G.R., Cao, Z.H. (2009). A new polymerization method and kinetics for acrylamide: Aqueous two-phase polymerization. Journal of Applied Polymer Science, 111:1409-1416.
  10. Fang, D.B., Guo, R.W., Ha, R.H. (2006). Acrylamide polymer. Chemical Industry Press, Beijing.
  11. Rahmouni, A., Harrane, A., Belbachir, M. (2012). Thermally stable forms of pure polyaniline catalyzed by an acid-exchanged MMT clay called Maghnite-H+ as an effective catalyst. International Journal of Polymer Science. 846710 (doi:10.1155/2012/846710,2012)
  12. Liu, S.J., Chen, C.F. (2000). Optimization of Bubble Size in Rotationally Moulded Parts, Plastics Rubber & Composites, 29: 411-416.
  13. Gemeinhart, R.A., Park, H., Park, K. (2000). Pore Structure of Superporous Hydrogels, Polymers for Advanced Technologies, 11: 617-625.
  14. Belbachir, M., Bensaoula, A. (2006). US. Patent 7,094,823 B2 .
  15. Yahiaoui, A., Belbachir, M., Hachemaoui, A. (2003). Cationic Polymerization of 1,2-Epoxypropane by an Acid Exchanged Montmorillonite Clay in the Presence of Ethylene Glycol. Int. J. Mol. Sci. 4: 572-585.
  16. Hwang, S.J., Park, H., Park, K. (1998). Gastric Retentive Drug-delivery Systems, Critical Reviews in Therapeutic Drug Carrier Systems, 15: 243-284.
  17. Rahmouni, A, Harrane, A, Belbachir, M (2013). Maghnite-H+, an eco-catalyst layered (Algerian Montmorillonite) for synthesis of polyaniline/Maghnite clay nano-composites. Int. J. Chem. Mater. Sci. 1(6): 175-181.
  18. Ferrahi, M.I, Belbachir, M. (2003). Polycondensation of Tetrahydrofuran with Phthalic Anhydride Induced By a Proton Exchanged Montmorillonite Clay. Int. J. Mol. Sci. 4: 312-325

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