The Composite of ZrO2-TiO2 Produced from Local Zircon Sand Used as A Photocatalyst for The Degradation of Methylene Blue in A Single Batik Dye Wastewater

*Ita Permadani -  Research Group of Solid State Chemistry & Catalysis, Chemistry Department, Sebelas Maret University, Jl.Ir. Sutami 36 A Kentingan Surakarta,, Indonesia
Dhini A. Phasa -  Research Group of Solid State Chemistry & Catalysis, Chemistry Department, Sebelas Maret University, Jl.Ir. Sutami 36 A Kentingan Surakarta,, Indonesia
Andini W. Pratiwi -  Research Group of Solid State Chemistry & Catalysis, Chemistry Department, Sebelas Maret University, Jl.Ir. Sutami 36 A Kentingan Surakarta,, Indonesia
Fitria Rahmawati -  Research Group of Solid State Chemistry & Catalysis, Chemistry Department, Sebelas Maret University, Jl.Ir. Sutami 36 A Kentingan Surakarta,, Indonesia
Received: 13 Jun 2016; Published: 20 Aug 2016.
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In 2016: BCREC Volume 11 Issue 2 Year 2016 (SCOPUS and Web of Science Indexed, August 2016)
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Abstract

In this research, a composite of ZrO2-TiO2 was used as a photocatalyst in the degradation of dye wastewater. The dye waste water is a single Methylene Blue, MB, wastewater from Batik industry. Meanwhile, the ZrO2 was prepared from zircon sand founded from Bangka Island, Indonesia. The composite was prepared at various weight ratio and heat treated at 500 oC. The result shows that the purity of ZrO2 from zircon sand is only 66.46 %. However, the addition of ZrO2 into TiO2 able to increase the photocatalytic activity proven by 88.75 % degradation of MB at a ZrO2-TiO2 weight ratio of 1:1. The result is higher than the degradation with anatase TiO2; that is only 62.67 %. The kinetics study found that the photocatalytic degradation of MB with single TiO2 has the rate constant of 1.85x10-2 minutes-1. Meanwhile, the rate constant of the MB degradation with the composite ZrO2-TiO2 is 16.73x10-2 minutes-1. Copyright © 2016 BCREC GROUP. All rights reserved

Received: 20th August 2015; Revised: 13rd December 2015; Accepted: 30th December 2015

How to Cite: Permadani, I., Phasa, D.A., Pratiwi, A.W., Rahmawati, F. (2016). The Composite of ZrO2-TiO2 Produced from Local Zircon Sand Used as A Photocatalyst for The Degradation of Methylene Blue in A Single Batik Dye Wastewater. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2): 133-139. (doi:10.9767/bcrec.11.2.539.133-139)

 Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.2.539.133-139

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Keywords
Photocatalytic; Methylene Blue; Zirconia; Titania; Batik Waste Water

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  1. Kapdan, I.K., Kargi, F., McMullan, G., Marchant R. (2000). Decolorization of Textile Dyestuffs by A Mixed Bacterial Consortium. Biotechnology Letters, 22: 1179-1181.
  2. Miyauchi, M., Nakajima, A., Watanabe, T., Hashimoto, K. (2002). Photocatalysis and Photoinduced Hydrophilicity of Various Metal Oxide Thin Films. Chemistry Materials, 14: 2812-2816
  3. Legrini, O., Oliveros, E., Braun, A.M. (1993). Photochemical Processes for Water Treatment. Chemical Reviews, 93(2): 671-698.
  4. Schattka, J.H., Dmitry, G.S., Jianguang, J., Markus, A., Rachel, A.C. (2002). Photocatalytic Activities of Porous Titania and Titania/Zirconia Structures Formed by Using a Polymer Gel Templating Technique. Chemistry Materials, 14: 5103-5108.
  5. Wang, E., Huiyun, Y., Yaan, C. (2009). Photocatalytic Activity of Visible-light-driven Zirconium-Doped TiO2 Photo-catalysts. Acta Chimica Sinica, 67: 2759-2764.
  6. Godlisten, N.S., Imran, S.M., Sun Jeong J., Marion, E., Nadir, A., M. Salman H., Shin Jae K., Hee Taik K. (2014). Sol-Gel Synthesis of Photoactive Zirconia-Titania from Metal Salts and Investigation of Their Photocatalytic Properties in The Photodegradation of Methylene Blue. Powder Technology, 258: 99-109
  7. Rahmawati, F., Permadani, I., Soepriyanto, S., Dani G.S., Heraldi, E. (2014). Double Steps Leaching and Filtration in Caustic Fusion Method to Produce Zirconia from Local Zircon Concentrate. In Proceedings of The 7th International Conference on Physics and Its Application, 55-59. Solo, Indonesia: International Conference on Physics and Its Application, Inc.
  8. Rahmawati, F., Bambang P., Soepriyanto, S., Ismunandar. (2012). SOFC Composite Electrolyte Based On LSGM-8282 And Zirconia or Doped Zirconia From Zircon Concentrate. International Journal of Minerals, Metallurgy and Materials, 19(9): 863-871.
  9. Sayama, K., Arakawa, H. (1993). Photocatalytic Decomposition of Water and Photocatalytic Reduction of Carbon Dioxide over ZrO2. Physical Chemistry, 97: 531-533.
  10. Soepriyanto, S., Korda, A.A., Hidayat T. (2005). The Development of Zircon Base Industrial Product from Zircon-Sand Concentrate of Bangka Tin Processing. In Proceedings of the 3rd International Workshop on Earth Science and Technology. Fukuoka, Japan: International Workshop on Earth Science and Technology, Inc.
  11. Neppolian, B., Qiliang W., Yamashita H., Heechul Choi. (2007). Synthesis and Characterization of ZrO2-TiO2 Binary Oxide Semiconductor Nanoparticles: Application and Interparticle Electron Transfer Process. Applied Catalysis A: General, 333: 264–271
  12. Fu X., Clark, L.A., Yang Q., Anderson M.A. (1996). Enhanced Photocatalytic Perfor-mance of Titania-Based Binary Metal Oxides: TiO2/SiO2 and TiO2/ZrO2. Environmental Science and Technology, 30(2): 647–653.
  13. Wang, X., Yu, J.C., Chen, Y., Wu, L., Fu, X. (2006). ZrO2-Modified Mesoporous Nanocrystalline TiO2-xNx as Efficient Visible Light Photocatalysts. Environmental Science and Technology, 40(7): 2369-2374.
  14. Wang, G. (2007). Hydrothermal Synthesis and Photocatalytic Activity of Nanocrystalline TiO2 Powders in Ethanol-Water Mixed Solution. Journal of Molecular Catalysis A: Chemical, 274: 185-191.
  15. Sahni, S., Reddy, B., Murry, B. (2007). Influence Parameters on The Synthesis of Nano-Titanian by Sol-Gel Route. Materials Science and Engineering: A, 452-453: 758-762.
  16. Jing L., Li S., Song S., Xue L., Fu H. (2008). Investigation on The Electron Transfer Between Anatase and Rutile In Nano-Sized TiO2, by Means of Surface Photovoltage Technique and Its Effects on The Photocatalytic Activity. Solar Energy Materials and Solar Cells, 92: 1030-1036.
  17. Fransisco, M.S.P., Mastelaro, V.R. (2002). Inhibition of The Anatase-Rutile Phase Transformation with Addition of CeO2 to CuO-TiO2 System: Raman spectroscopy, X-Ray diffraction, and textural studies. Chemistry of Materials, 14(6): 2514-2518.
  18. Farag, H.K., Hegab, K.H., Abedin, S.Z.El. (2011). Preparation and Characterization of Zirconia and Mixed Zirconia/Titania in Ionic Liquids. Journal of Materials Science, 46: 3330-3336
  19. Wu J.C., Chung, C.C., Ay C.L., Wang, I. (1984). Nonoxidative Dehydrogenation of Ethylbenzene over TiO2-ZrO2 Catalysts: II. The Effect of Pretreatment on Surface Properties and Catalytic Activities. Journal of Catalysis, 87: 98-107.
  20. Wang I., Wu J.C., Chung C.C. (1985). Dehydrogenation of Ethylbenzene and Ethyl cyclohexane over Mixed Binary Oxide Catalysts Containing Titania. Applied Catalysis, 16: 89-101.
  21. Reddy B.M., Khan A. (2005). Recent Advances on TiO2‐ZrO2 Mixed Oxides as Catalysts and Catalyst Supports. Catalysis Review: Science and Engineering, 47: 257-296.
  22. Das, L., J.K. Basu. (2015). Photocatalytic Treatment of Textile Effluent using Titania–Zirconia Nano 3 Composite Catalyst. Journal of Industrial and Engineering Chemistry, 24: 245-250.

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