Catalytic Hydrodeoxygenation of Fatty Acids for Biodiesel Production

*Аntonina A. Stepacheva  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Valentin N. Sapunov  -  D. Mendeleyev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow,, Russian Federation
Esther M. Sulman M. Sulman  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,
Linda Zh. Nikoshvili  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Mikhail G. Sulman  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Alexander I. Sidorov  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Galina N. Demidenko  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Valentina G. G. Matveeva  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Received: 13 Jun 2016; Published: 20 Aug 2016.
Open Access Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

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Abstract

This paper is devoted to the production of second generation biodiesel via catalytic hydrodeoxygenation of fatty acids. Pd/C catalysts with different metal loading were used. The palladium catalysts were characterized using low-temperature nitrogen physisorption and X-ray photoelectron spectroscopy. It was revealed that the most active and selective catalyst was 1%-Pd/C which allowed reaching up 97.5% of selectivity (regarding to n-heptadecane) at 100% conversion of substrate. Moreover, the chosen catalyst is more preferable according to lower metal content that leads the decrease of the process cost. The analysis of the catalysts showed that 1%-Pd/C had the highest specific surface area compared with 5%-Pd/C. Copyright © 2016 BCREC GROUP. All rights reserved

Received: 31st July 2015; Revised: 9th December 2015; Accepted: 30th December 2015

How to Cite: Stepacheva, A.A., Sapunov, V.N., Sulman, E.M., Nikoshvili, L.Z., Sulman, M.G., Sidorov, A.I., Demidenko, G.N., Matveeva, V.G. (2016). Catalytic Hydrodeoxygenation of Fatty Acids for Biodiesel Production. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2): 125-132 (doi:10.9767/bcrec.11.2.538.125-132)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.2.538.125-132

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Keywords: Fatty Acids; Catalytic Hydrodeoxygenation; Palladium Catalyst; Biodiesel

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