Catalytic Hydrodeoxygenation of Fatty Acids for Biodiesel Production

*Аntonina A. Stepacheva  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Valentin N. Sapunov  -  D. Mendeleyev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow,, Russian Federation
Esther M. Sulman M. Sulman  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,
Linda Zh. Nikoshvili  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Mikhail G. Sulman  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Alexander I. Sidorov  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Galina N. Demidenko  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Valentina G. G. Matveeva  -  Tver Technical University, Department of Biotechnology and Chemistry, A. Nikitina str., 22, Tver 170026,, Russian Federation
Received: 13 Jun 2016; Published: 20 Aug 2016.
Open Access Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

Citation Format:
Cover Image
Article Info
Section: Original Research Articles
In 2016: BCREC Volume 11 Issue 2 Year 2016 (SCOPUS and Web of Science Indexed, August 2016)
Statistics: 1094 561
Abstract

This paper is devoted to the production of second generation biodiesel via catalytic hydrodeoxygenation of fatty acids. Pd/C catalysts with different metal loading were used. The palladium catalysts were characterized using low-temperature nitrogen physisorption and X-ray photoelectron spectroscopy. It was revealed that the most active and selective catalyst was 1%-Pd/C which allowed reaching up 97.5% of selectivity (regarding to n-heptadecane) at 100% conversion of substrate. Moreover, the chosen catalyst is more preferable according to lower metal content that leads the decrease of the process cost. The analysis of the catalysts showed that 1%-Pd/C had the highest specific surface area compared with 5%-Pd/C. Copyright © 2016 BCREC GROUP. All rights reserved

Received: 31st July 2015; Revised: 9th December 2015; Accepted: 30th December 2015

How to Cite: Stepacheva, A.A., Sapunov, V.N., Sulman, E.M., Nikoshvili, L.Z., Sulman, M.G., Sidorov, A.I., Demidenko, G.N., Matveeva, V.G. (2016). Catalytic Hydrodeoxygenation of Fatty Acids for Biodiesel Production. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2): 125-132 (doi:10.9767/bcrec.11.2.538.125-132)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.2.538.125-132

Article Metrics: (click on the button below to see citations in Scopus)

cited by count 

Keywords: Fatty Acids; Catalytic Hydrodeoxygenation; Palladium Catalyst; Biodiesel

Article Metrics:

  1. Kalnes., T., Marker, T., Shonnard, D.R. (2007). Green diesel: a second generation biofuels. International Journal of Chemical Reactor Engineering, 5: 748-750.
  2. Sooknoi, T., Danuthai, T., Lobban, L.L., Mallinson, R.G., Resasco, D.E. (2008). Deoxygenation of Methyl Esters over CsNaX. Journal of Catalysis, 258: 199-200.
  3. Snäre, M., Kubičkova, I., Mäki-Arvela, P., Eränen, K., Murzin, D.Yu. (2006). Heterogeneous Catalytic Deoxygenation of Stearic Acid for Production of Biodiese. Industrial & Engineering Chemistry Research, 45(16): 5708-5719.
  4. Li, L., Coppola, E., Rine, J., Miller, J.L., Walker, D. (2010). Catalytic hydrothermal conversion of triglycerides to non-ester biofuels. Energy Fuels, 24: 1305-1315.
  5. Holmgren, J., Gosling, C., Couch, K., Kalnes, T., Marker, T., McCall, M., Marinangeli, R. (2007). Biorenewable integration in refineries is evaluated along with work to commercially produce green diesel. Petroleum Technology Quarterly, 3: 119-125.
  6. Immer, J.G., Lamb, H.H. (2010). Fed - Batch Catalytic Deoxygenation of Free Fatty Acids. Energy & Fuels, 24: 5291-5299.
  7. Morgan, T., Grubb, D., Santillan-Jimenez, E., Crocker, M. (2010). Conversion of triglycerides to hydrocarbons over supported metal catalysts. Topics in Catalysis, 53: 820-829.
  8. Do, Ph.T., Chiappero, M., Lobban, L.L., Resasco, D.E. (2009). Catalytic Deoxygenation of Methyl-Octanoate and Methyl-Stearate on Pt/Al2O3. Catalysis Letters, 130: 9-18.
  9. Rar, M., Kovacs, S., Kallo, D., Hancsok, J. (2010). Fuel Purpose Hydrotreating of Sunflower Oil on CoMo/Al2O3 Catalyst. Bioresourse Technology, 101: 9287-9293.
  10. Hoang, T.Q., Zhu, X., Danuthai, T., Lobban L.L., Resasco, D.E., Mallinson, R.G. (2010). Conversion of Glycerol to Alkyl-aromatics over Zeolites. Energy Fuels. 24: 3804-3809.
  11. Danuthai, T., Jongpatiwut, S., Rirksomboon, Th., Osuwan, S., Resasco, D.E. (2009). Conversion of methylesters to hydrocarbons over an H-ZSM5 zeolite catalyst. Applied Catalysis A: General, 361: 99-105.
  12. Dundich, V.O., Khromova, S.A., Ermakov, D.Yu., Lebedev, M.Yu., Novopashina, V.M., Sister, V.G., Yakimchuk, A.I., Yakovlev, V.A. (2010). Nickel catalysts for the hydrodeoxygenation of biodiesel. Kinetics and Catalysis, 51(5): 704-709.
  13. Gregg, S. J., Sing, Kenneth S.W. (1982). Adsorption, Surface Area, & Porosity, Second Edition. Hardcover.
  14. Donohue, M. (2010). A New Classification of Adsorption Isotherms. Citing Internet sources URL http://www.nigelworks.com/mdd/.../NewClass.pdf
  15. NIST X-ray Photoelectron Spectroscopy Database, Version 3.5. (National Institute of Standards and Technology, Gaithersburg, 2003). Citing Internet sources URL http://srdata.nist.gov/xps/
  16. Wu, T., Kaden, W.E., Kunkel, W.A., Anderson, S.L. (2009). Size-dependent oxidation of Pdn (n ≤ 13) on alumina/NiAl(110): Correlation with Pd core level binding energies. Surface Science, 603: 2764-2770.
  17. Penner, S., Bera, P., Pedersen, S., Ngo, L.T, Harris, J.J.W., Charles, T. (2006). Campbell. Interactions of O2 with Pd Nanoparticles on α-Al2O3(0001) at Low and High O2 Pressures. Journal of Physical Chemistry B, 110: 24577-24584.

No citation recorded.

Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis License URL: http://creativecommons.org/licenses/by-sa/4.0

Author(s) Rights

As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including: use for classroom teaching by Author or Author's institutionand presentation at a meeting or conference and distributing copies to attendees; use for internal training by author's company; distribution to colleagues for their reseearch use; use in a subsequent compilation of the author's works; inclusion in a thesis or dissertation; reuse of portions or extracts from the article in other works (with full acknowledgement of final article); preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article); voluntary posting on open web sites operated by author or author’s institution for scholarly purposes (should follow CC by SA License).

Authors can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (cite to the article or content), provide a link to the license, and indicate if changes were made. If you remix, transform, or build upon the material, you must redistribute your contributions under the same license as the original.

Copyright Transfer Agreement (for Publishing)

The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright publishing of the article shall be assigned/transferred to Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) as Publisher of the journal. Upon acceptance of an article, authors will be asked to complete a 'Copyright Transfer Agreement' (see more information on this). An e-mail will be sent to the corresponding author confirming receipt of the manuscript together with a 'Copyright Transfer Agreement' form by online version of this agreement.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia-Indonesian Catalyst Society (MKICS), the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of copyright, our journal authors retain (or are granted back) significant scholarly rights as mention before.

The Copyright Transfer Agreement (CTA) Form can be downloaded here: [Copyright Transfer Agreement (CTA) Form BCREC 2020] 


The copyright form should be signed electronically and send to the Editorial Office in the form of original e-mail below:  

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering & Catalysis
Department of Chemical Engineering, Diponegoro University
Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Telp.: +62-24-7460058, Fax.: +62-24-76480675
E-mail: bcrec[at]live.undip.ac.id