Effects of Calcination Temperatures on The Catalytic Activities of Alumina Supported Cobalt and Chromium Catalysts

Mardwita Mardwita; Eka Sri Yusmartini; Nidya Wisudawati

doi:10.9767/bcrec.14.3.4673.654-659

DOI: https://doi.org/10.9767/bcrec.14.3.4673.654-659

Effects of Calcination Temperatures on The Catalytic Activities of Alumina Supported Cobalt and Chromium Catalysts

Mardwita Mardwita¹

, Eka Sri Yusmartini¹, Nidya Wisudawati²

¹Chemical Engineering Department, Faculty of Engineering, Universitas Muhammadiyah Palembang, Indonesia

²Industrial Engineering Department, Faculty of Engineering, Universitas Muhammadiyah Palembang, Indonesia

Received: 11 Apr 2019; Revised: 9 Aug 2019; Accepted: 18 Aug 2019; Available online: 30 Sep 2019; Published: 1 Dec 2019.

Editor(s): Istadi Istadi

BibTex Citation Data :

@article{BCREC4673,
    author = {Mardwita Mardwita and Eka Sri Yusmartini and Nidya Wisudawati},
    title = {Effects of Calcination Temperatures on The Catalytic Activities of Alumina Supported Cobalt and Chromium Catalysts},
    journal = {Bulletin of Chemical Reaction Engineering & Catalysis},
  volume = {14},
    number = {3},
    year = {2019},
    keywords = {Impregnation; Cobalt Catalyst; Chromium Catalyst; Methane Oxidation},
    abstract = { Catalysts properties are important for catalytic reactions. The interaction between support and metal in a catalyst is resulted from catalyst preparation. In this study, gamma-alumina (Al 2 O 3 ) supported cobalt (Co) and chromium (Cr) catalysts were prepared by impregnation method and calcined at two different temperatures, they are 400 °C for 4 hours and 800 °C for 4 hours. The resulted catalysts contained 10 wt.% of metal and denoted as Co/Al 2 O 3 (400), Co/Al 2 O 3 3(800), Cr/Al 2 O 3 (400), and Cr/Al 2 O 3 (800) catalysts. The surface and state of the catalysts were examined by using x-ray diffraction (XRD), x-ray photoelectron spectrometer (XPS) and transmission electron microscopy (TEM). The XRD result reveals that strong interaction between Co and Al 2 O 3  due to a formation of higher cobalt oxide. The XRD result further indicates aggregation and strong support metal interaction between Co and Al 2 O 3  during calcination. On the other hand, TEM result showed that large Co particle was observed on Al 2 O 3 . The Cr/Al 2 O 3  catalysts were characterized by using XPS. The XPS results showed that Cr/Al 2 O 3 (800) catalyst was dominated by Cr 6+  species at binding energy 579.04 eV, indicating high dispersion of Cr on Al 2 O 3 . Moreover, Cr metal particle was not observed on XRD and TEM image. All the characterization results provide information that the impregnated metal on Al 2 O 3  showed different properties. Co metal particle tends to be more oxidized and formed large particle, however it was not observed on Cr metal particle.  },
   issn = {1978-2993},   pages = {654--659}  doi = {10.9767/bcrec.14.3.4673.654-659},
    url = {https://ejournal2.undip.ac.id/index.php/bcrec/article/view/4673}
}

Citation Format:

Abstract

Catalysts properties are important for catalytic reactions. The interaction between support and metal in a catalyst is resulted from catalyst preparation. In this study, gamma-alumina (Al₂O₃) supported cobalt (Co) and chromium (Cr) catalysts were prepared by impregnation method and calcined at two different temperatures, they are 400 °C for 4 hours and 800 °C for 4 hours. The resulted catalysts contained 10 wt.% of metal and denoted as Co/Al₂O₃(400), Co/Al₂O₃3(800), Cr/Al₂O₃(400), and Cr/Al₂O₃(800) catalysts. The surface and state of the catalysts were examined by using x-ray diffraction (XRD), x-ray photoelectron spectrometer (XPS) and transmission electron microscopy (TEM). The XRD result reveals that strong interaction between Co and Al₂O₃ due to a formation of higher cobalt oxide. The XRD result further indicates aggregation and strong support metal interaction between Co and Al₂O₃ during calcination. On the other hand, TEM result showed that large Co particle was observed on Al₂O₃. The Cr/Al₂O₃ catalysts were characterized by using XPS. The XPS results showed that Cr/Al₂O₃(800) catalyst was dominated by Cr⁶⁺ species at binding energy 579.04 eV, indicating high dispersion of Cr on Al₂O₃. Moreover, Cr metal particle was not observed on XRD and TEM image. All the characterization results provide information that the impregnated metal on Al₂O₃ showed different properties. Co metal particle tends to be more oxidized and formed large particle, however it was not observed on Cr metal particle.

Fulltext View|Download

Keywords: Impregnation; Cobalt Catalyst; Chromium Catalyst; Methane Oxidation

Funding: Directorate of Research and Community Service Directorate General of Research and Development (DRPM) The Ministry of Research Technology and Higher Education (RISTEKDIKTI)

Article Metrics:

Article Info

Section: Original Research Articles

Language : EN

In 2019: BCREC Volume 14 Issue 3 Year 2019 (December 2019)

Recent articles

Carbon-containing Hydroxyapatite Obtained from Fish Bone as Low-cost Mesoporous Material for Methylene Blue Adsorption Palladium(0) Nanoparticles Immobilized onto Silica/Starch Composite: Sustainable Catalyst for Hydrogenations and Suzuki Coupling Direct Synthesis of Sodalite from Indonesian Kaolin for Adsorption of Pb2+ Solution, Kinetics, and Isotherm Approach Synergistic Corrosion Inhibition Effect of Rice Husk Extract and KI for Mild Steel in H2SO4 Solution Basicity Optimization of KF/Ca-MgO Catalyst using Impregnation Method Production of Triacetin by Microwave Assisted Esterification of Glycerol Using Activated Natural Zeolite Backmatter (Publication Ethics, Copyright Transfer Agreement Form) Frontmatter (Front Cover, Editorial Team, Indexing, and Table of Contents) More recent articles

Ali, S., Mohd Zabidi, N.A., Al-Marri, M.J., Khader, M.M. (2016). Effect of the Support on Physicochemical Properties and Catalytic Performance of Cobalt Based Nanocatalysts in Fischer-Tropsch Reaction. Materials Today Communications, 10: 67-71
Ozawa, M., Yoshitoyo, N. (2016). Thermal Stability and Microstructure of Catalytic Alumina Composite Support with Lanthanum Species. Applied Surface Science, 380: 288-293
Okumura, K., Niwa, M. (2002). Metal-Support Interaction which Controls the Oxidation State, Structure and Catalysis of Pd. Catalysis Surveys from Japan, 5: 121-126
Dey, S., Dhal, G.C., Mohan, D., Prasad, R. (2017). Effect of Preparation Conditions on the Catalytic Activity of CuMnOx Catalysts for CO Oxidation. Bulletin of Chemical Reaction Engineering & Catalysis, 12(3): 431-451
Singha, R.K., Shukla, A., Yadav, A., Konathala, L.N.S., Bal, R. (2017). Effect of Metal-Support Interaction on Activity and Stability of Ni-CeO2 Catalyst for Partial Oxidation of Methane. Applied Catalysis B: Environmental, 202: 473-488
Valdes-Martinez, O.U., Suarez-Toriello, V.A., De Los Reyes, J.A., Pawelec, B., Fierro, L.G. (2017). Support Effect and Metals Interactions for NiRu/Al2O3, TiO2 and ZrO2 Catalysts in the Hydrodeoxygenation of Phenol. Catalysis Today, 296: 219-227
Mardwita, M., Matsune, H., Takenaka, S., Kishida, M. (2012). Chromium Addition to Alumina-Supported Platinum Catalysts and Effect on Catalytic in Methane Combustion. Journal of Chemical Engineering of Japan, 45: 493- 497
Mardwita, M., Bustan, M.D. (2017). Ammonium Hydroxide Addition and Its Influence on the Catalytic Activities of Pt-Based Catalysts for Methane Oxidation. MATEC Web of Conferences, 101: 1-6
Tijani, M.M., Aqsha, A., Mahinpey, N. (2017). Synthesis and Study of Metal-Based Oxygen Carriers (Cu, Co, Fe, Ni) and Their Interaction with Supported Metal Oxides (Al2O3, CeO2, TiO2, ZrO2) in A Chemical Looping Combustion System. Energy, 138: 873-882
Murata, K., Mahara, Y., Ohyama, J., Yamamoto, Y., Arai, S., Satsuma, A. (2017). Metal-Support Interaction Concerning Particle Size Effect of Pd/Al2O3 on Methane Combustion. Angewandte Chemie International Edition, 50: 15993-15997
Khangale, P.R., Meijboom, R., Jalama, K. (2019). Fischer-Tropsch Synthesis over Unpro-moted Co/ɣ-Al2O3 Catalyst: Effect of Activation with CO Compared to H2 on Catalyst Performance. Bulletin of Chemical Reaction Engineering & Catalysis, 14(1): 35-41
Goodman, D.W. (2005). Catalytically Active Au on Titania: Yet Another Example of A Strong Metal Support Interaction (SMSI)?. Catalysis Letter, 99: 1-4
Rekkab-Hammoumraoui, I., Choukchou-Braham, A. (2018). Catalytic Properties of Alumina-Supported Ruthenium, Platinum, and Cobalt Nanoparticles towards the Oxidation of Cyclohexane to Cyclohexanol and Cyclohexanone. Bulletin of Chemical Reaction Engineering & Catalysis, 13(1): 24-36
Tavasoli, A., Abbaslou, R.M.M., Dalai, A.K. (2008). Deactivation Behavior of Ruthenium Promoted Co/gAl2O3 Catalysts in Fischer-Tropsch Synthesis. Applied Catalysis A: General, 346: 58-64
Jongsomjit, B., Panranot, J., Goodwin, Jr.J. (2001). Co-Supported Compound Formation in Alumina-Supported Cobalt Catalysts. Journal of Catalysis, 204: 98-109
Ji, L., Lin, J., Zeng, H.C. (2000). Metal-Support Interactions in Co/Al2O3 Catalysts: A Comparative Study on Reactivity of Support. The Journal of Physical Chemistry B, 104(8): 1783-1789
Rahman, A., Mohammed, M.H., Ahmed, M., Aitani, A.M. (1995). Characterization of Chromia.Alumina Catalysts by X-Ray Photoelectron Spectroscopy, Proton Induced X-Ray Emission and Thermogravimetric Analysis. Applied Catalysis A: General, 121: 203-216
Sainio, J., Aronniemi, M., Pakarinen, O., Kauraala, K., Airaksinen, S., Krause, O., Lahtinen, J. (2005). An Xps Study of CrOx on A Thin Alumina Film and in Alumina Supported Catalysts. Applied Surface Science, 252: 1076-1083
Park, W.P., Ledford, J.S. (1997). Characterization and CH4 Oxidation Activity of Cr/Al2O3 Catalysts. Langmuir, 13: 2726-2730
Kuznetsova, L.L., Paukshtis, E.A., Shkurina, G.P., Shkrabina, R.A., Koryabkina, N.A., Arendarskii, D.A., Barannik, G.B., Ismagilov, Z.R. (1997). Chromium Catalysts for Hydrocarbons Destruction. Catalysis Today, 17: 209-216

Last update:

No citation recorded.

Last update:

No citation recorded.

Journal Author(s) Rights

In order for BCREC Group to publish and disseminate research articles, we need non-exclusive publishing rights (transfered from author(s) to publisher). This is determined by a publishing agreement between the Author(s) and BCREC Group. This agreement deals with the transfer or license of the copyright of publishing to BCREC Group, while Authors still retain significant rights to use and share their own published articles. BCREC Group supports the need for authors to share, disseminate and maximize the impact of their research and these rights, in any databases.

As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including:

use for classroom teaching by Author or Author's institution and presentation at a meeting or conference and distributing copies to attendees;
use for internal training by author's company;
distribution to colleagues for their reseearch use;
use in a subsequent compilation of the author's works;
inclusion in a thesis or dissertation;
reuse of portions or extracts from the article in other works (with full acknowledgement of final article);
preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article);
voluntary posting on open web sites operated by author or author’s institution for scholarly purposes,

(but it should follow the open access license of Creative Common CC-by-SA License).

Authors/Readers/Third Parties can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (the name of the creator and attribution parties (authors detail information), a copyright notice, an open access license notice, a disclaimer notice, and a link to the material), provide a link to the license, and indicate if changes were made (Publisher indicates the modification of the material (if any) and retain an indication of previous modifications using a CrossMark Policy and information about Erratum-Corrigendum notification).

Authors/Readers/Third Parties can read, print and download, redistribute or republish the article (e.g. display in a repository), translate the article, download for text and data mining purposes, reuse portions or extracts from the article in other works, sell or re-use for commercial purposes, remix, transform, or build upon the material, they must distribute their contributions under the same license as the original Creative Commons Attribution-ShareAlike (CC BY-SA).

Copyright Transfer Agreement for Publishing (Publishing Right)

The Authors submitting a manuscript do so on the understanding that if accepted for publication, non-exclusive right for publishing (publishing right) of the article shall be assigned/transferred to Publisher of Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) (or BCREC Group).

Upon acceptance of an article, authors will be asked to complete a 'Copyright Transfer Agreement for Publishing (CTAP)'. An e-mail will be sent to the Corresponding Author confirming receipt of the manuscript together with a 'Copyright Transfer Agreement for Publishing' form by online version of this agreement.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia-Indonesian Catalyst Society (MKICS), the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of copyright for publishing (CTAP), our journal Author(s) retain (or are granted back) significant scholarly rights as mentioned before.

The Copyright Transfer Agreement for Publishing (CTAP) Form can be downloaded here: [Copyright Transfer Agreement for Publishing (CTAP) Form BCREC 2020]

The copyright form should be signed electronically and send to the Editorial Office in the form of original e-mail below:

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering & Catalysis
Laboratory of Plasma-Catalysis (R3.5), UPT Laboratorium Terpadu, Universitas Diponegoro
Jl. Prof. Soedarto, Semarang, Central Java, Indonesia 50275
Telp/Whatsapp: +62-81-316426342
E-mail: bcrec[at]live.undip.ac.id

(This policy statements has been updated at 24th December 2020)