DOI: https://doi.org/10.9767/bcrec.11.2.443.250-261

Kinetic and Thermodynamics of Methylene Blue Adsorption onto Zero Valent Iron Supported on Mesoporous Silica

1Faculty of Industrial Sciences and Technology, Universiti Malaysia Pahang, Lebuhraya Tun Razak 26300 Kuantan, Pahang, Malaysia

2Universiti Kuala Lumpur, Malaysian Institute of Chemical and Bioengineering Technology, Vendor City 1988, 78000 Alor Gajah, Melaka, Malaysia

3Key Laboratory for Catalysis and Materials Science of the State Ethnic Affairs Commissions & Ministry of Education, South Central University for Nationalties, Wuhan 430074, China

4 Faculty of Technology Management And Technopreneurship, Universiti Teknikal Malaysia Melaka, Hang Tuah Jaya, 76100 Durian Tunggal, Melaka, Malaysia

View all affiliations
Received: 5 Mar 2016; Revised: 18 Mar 2016; Accepted: 18 Mar 2016; Published: 20 Aug 2016; Available online: 30 Jun 2016.
Open Access Copyright (c) 2016 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

Zero valent iron supported on mesoporous silicanano particles (NZVI/MSNs) was prepared by the aqueous phase borohydride reduction methods. Prior to the reduction, mesoporous silica nanoparticles (MSNs) were prepared through the activation of fumed silica with concentrated HCl by refluxing at 90 °C. FTIR, XRD, FESEM, EDX and BET were used to characterize theadsorbents prepared. BET surface areas of MSNs, NZVI, and NZVI/MSNs were 126, 41, and 72 m2/g for, respectively. The performance of NZVI/MSNs as adsorbent was examined by adsorption of methylene blue (MB), performed in series of batch experiments. In the kinetic studies, pseudo first order and pseudo second order kinetic models were examined. The pseudo second order equation provided the best fit with the experimental data. Thermodynamic studies indicated that the adsorption process is endothermic with ΔH° was 90.53 kJ/mol. Positive ΔS° (300 J/mol) and negative ΔG° (-6.42 kJ/mol) was recorded, indicating the spontaneous of the adsorption process and naturally favorable. 

Fulltext View|Download
Keywords: Zero valent iron; Adsorption kinetics, Adsorption Thermodynamics; Methylene blue; Mesoporous silica

Article Metrics:

Article Info
Section: The International Conference on Fluids and Chemical Engineering (FluidsChE 2015)
Language : EN
Statistics:
Share:
Most viewed articles
Synthesis of Chitosan/Zinc Oxide Nanoparticles Stabilized by Chitosan via Microwave Heating Preparation, Characterization, and Catalytic Property of a Cu(II) Complex with 2-Carboxybenzaldehyde-p-Toluenesulfonyl Hydrazone Ligand Methyl Violet Degradation Using Photocatalytic and Photoelectrocatalytic Processes Over Graphite/PbTiO3 Composite Microwave Assisted Expeditious and Green Cu(II)-Clay Catalyzed Domino One-Pot Three Component Synthesis of 2H-indazoles The Impact of Hydrogen Peroxide as An Oxidant for Solvent-free Liquid Phase Oxidation of Benzyl Alcohol using Au-Pd Supported Carbon and Titanium Catalysts More articles
Most cited articles
Effects of Bentonite Activation Methods on Chitosan Loading Capacity The Effect of Mesoporous H-ZSM-5 Crystallinity as a CaO Support on the Transesterification of Used Cooking Oil Electrosynthesized Ni-Al Layered Double Hydroxide-Pt Nanoparticles as an Inorganic Nanocomposite and Potentate Anodic Material for Methanol Electrooxidation in Alkaline Media Egg-shell Treated Oil Palm Fronds (EG-OPF) as Low-Cost Adsorbent for Methylene Blue Removal Effects of Doping on the Performance of CuMnOx Catalyst for CO Oxidation More cited articles
  1. Sarioglu, M., Atay, U., A. (2006). Removal of methylene blue by using bio solid “, Global NEST Journal, 8 (2) : 113 -120
  2. Badruddoza, A., Goh, S., Hidajat, K. Uddin, M., (2010). Synthesis of carboxymethyl--cyclodextrin conjugated magnetic nano-adsorbent for removal of methylene blue. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 367(1-3): 85–95
  3. Fail, A .B ., Ozmetin, C. , Korkmaz , M. (2012) . Cationic dye (methylene blue) removal from aqueous solution by montrmorillonite , Bull. Korean Chem. Soc., 33, (10):.3184 3190
  4. Oyelude, E., O., Takyi, F. , A. , Felix, A. (2012). Removal of methylene blue from aqueous solution using alkali modified malted sorghum mash . Turkish Journal Engineering. Environment. Science,6 :161 – 169
  5. Kadirova, Z. C., Katsumata, K., Isobe, T. , Matsushita , N., Nakajima , A., Okada , K . (2013). Adsorption And Photodegradation of Methylene blue by iron oxide impregnated on granular activated carbons in an oxalate solution . Applied surface science 284: 72-79
  6. Rahman, M. A. ,Amin , S. M. R. and Alam , A. M. S. (2012). Removal of Methylene Blue from Waste Water Using Activated Carbon Prepared from rice husk . Dhaka Univ. Journal of Science. 60(2): 185-189
  7. Shih, Y. H. , Tso , C. P., Tung , L. Y., (2010) . Rapid degradation of methyl orange with nano scale zero valent iron particles.. Journal of Environ. Eng. Manage., 20 (3) : 137-143
  8. Ho,Y., Malarvizhi, ., R., Sulochana, N.(2009). Equilibrium Isotherm Studies of Methylene Blue Adsorption onto Activated Carbon Prepared from Delonix regia Pods.Journal of Environmental Protection Science, 3: 111–116
  9. Muslim, , M. A., Hammoud, Z. A. (2014) .Removal of Methylene Blue from Aqueous Solution by using iron filings waste material in batch and continuous experiments. Journal of Babylon University/Engineering Sciences 22 (1):.35-45
  10. Sun, X., Yan, Y.,,Li, J., Hana , W., Wang, L., (2014). Nanoscale Zero-Valent iron Particles for chromium(VI) removal from groundwater: Mechanism, effect of pH, humic acid and sustained reactivity “ Journal of Hazard materials 12, : 26-33
  11. Park, J., Han, Y., Kim, H. (2012). Formation of Mesoporous Materials from Silica dissolved in various NaOH concentrations: Effect of pH and ionic strength. Journal of Nanomaterials, (2012)
  12. Hameed, A. K , Dewayanto , N. , Dongyun , Du. , Nordin , M. R .(2014) . Synthesis and Characterization of Nano Scale Zero-Valent Iron Supported on Mesoporous Silica . 9th Joint Conference on Chemistry , Indonesia
  13. Petala, E., Dimos , K., Douvalis , A., Bakas , T., Tucek , J., Zboril , R. and Karakassides , M. , A. (2013) . Nano Scale Zero-Valent Iron Supported on Mesoporous Silica : Characterization and Reactivity for Cr(VI) Removal from Aqueous Solution . Journal of Hazardous Materials, 216 (2) : 295-306
  14. Karim, A.K., Jalil, S., Triwahyono, N. H. N., Kamarudin, N. F. M. Salleh, (201`2). Adsorption of Methylene Blue From Aqueous Ssolution by Mesostructured Silica nanoparticles,” in Conference on Emerging Energy and Process Technology (CONCEPT)
  15. Ling, X ., Li, J. , Zhu, W. ,Zhu, Y. , Sun, X. , Shen, J. ,Han, W. , Wang, L. (2012) .Synthesis of Nano Scale Zero-Valent Iron /ordered Mesoporous Carbon For Adsorption and Synergistic Reduction of Nitrobenzene . Chemosphere, 87: 655-660
  16. Noubactep, C., Care, S., Caren, R. (2012). Nano Scale Metallic Iron for Environmental Remediation: Prospects and limitations . Water Air Soil Pollutes, 223: .1363–1382
  17. Kirk, C. T. (1988). Quantitative Analysis of The Effect of Disorder-Induced Mode Coupling on Infrared Absorption in Silica.Physical Review B, 38 (2):1255–1273
  18. Kamitsos, E. I., Patsis, A. P., Kordas, G. (1993). Infrared-Reflectance Spectra of Heat-Treated Sol-gel-Derived Silica. Physical Review B, 48(17): 12499–12505
  19. K. Dimos,K., Antoniou, M. K., . Meichanetzoglou, A., Lymperopoulou,S., Ouzouni, M. D., Koutselas, I. B., Fokas, D., Karakassides, M.A., Agostino, R. G. , Gournis, D.(2012). Naphthalene-Based Periodic Nanoporous OrganoSilicas: I. Synthesis and Structural Characterization. Microporous and Mesoporous Materials, 158, : 324–331
  20. Frost, R. L. Xi, Y., He, H. (2013). Synthesis, Characterization of Palygorskite Supported Zero-Valent Iron and Its Application for Mmethylene Blue Adsorption. Journal of Colloid and Interface Science, 341: 153-161
  21. Wang, P. Cao, M., Wang, Ch., Ao, Y., Hou, J., Qian, J. (2014). Kinetics and Thermodynamics of Adsorption of Methylene Blue by a Magnetic Graphene-Carbon Nanotube Composite. Applied Surface Science, 290 :116-124
  22. Wang, L., Li, J. (2013).Removal of Methylene Blue from Aqueous Solution by Adsorption onto Crofton Weed Stalk.Bio Recourse, 8(2) : 2521-2536
  23. Gouamid, M., Ouahrani,M. R. Bensaci, M. B.(2013). Adsorption Equilibrium, Kinetics and Thermodynamics of Methylene Blue from Aqueous Solutions Using Date palm Leaves. Energy Procedia, 36: 898–907
  24. Suteu, D., Malutan, T. (2013). Industrial Cellolignin Wastes as Adsorbent for Removal of Methylene Blue Dye from Aqueous Solutions. Bio Resources, 8(1):427-446
  25. Derakhshan, Z., Baghapour, M. (2013). Adsorption of Methylene Blue Dye from Aqueous Solutions by Modified Pumice Stone: Kinetics and Equilibrium Studies. Health Scope, 2(3): 136–44
  26. ALzaydien,A.S.(2009). Adsorption of Methylene Blue from Aqueous Solution onto a Low-Cost Natural Jordanian Tripoli. American Journal of Applied Sciences, 6(6): 1047–1058
  27. Abdel Ghafar, H. H., Ali, G. A. M., Fouad, O. A., Makhlouf, S. A. (2013). Enhancement of Adsorption Efficiency of Methylene Blue on Co3O4/SiO2 Nanocomposite. Desalination and Water Treatment, 53(11): 2980–2989
  28. Kareem, S. H. Ali, I. H., Jalhoom, M. G.(2014). Synthesis and Characterizationof Organic Functionalized Mesoporous Silica and Evaluate Their Adsorptive Behavior for Removal of Methylene Blue From Aqueous Solution. American Journal of Environmental Sciences, 10(1): 48–60
  29. Tan, I. A.W., Ahmad, A.L., Hameed, B. H. (2008). Adsorption of Basic Dye on High-Surface-Area Activated Carbon Prepared from Coconut Husk: Equilibrium, Kinetic and Thermodynamic Studies. Journal of Hazardous Materials, 154(1-3): 337–346

Last update:

No citation recorded.

Last update: 2021-09-20 01:50:35

  1. Zero valent iron loaded on SiC nanoparticles as a new adsorbent for removing Pb (lead) and azo dyes from aqueous solution

    Ghasemian Lemraski E.. Environmental Progress and Sustainable Energy, 37 (5), 2018. doi: 10.1002/ep.12849

  2. Zero valent cobalt impregnated silica nanoparticles for the sanitation of contaminated water

    Shukla N.. Environmental Progress and Sustainable Energy, 38 , 2019. doi: 10.1002/ep.12913

  3. Silica extraction from beach sand for dyes removal: Isotherms, kinetics and thermodynamics

    Firdaus M.L.. Rasayan Journal of Chemistry, 13 (1), 2020. doi: 10.31788/RJC.2020.1315496