Kinetic and Thermodynamics of Methylene Blue Adsorption onto Zero Valent Iron Supported on Mesoporous Silica

*Atyaf Khalid Hameed  -  Faculty of Industrial Sciences and Technology, Universiti Malaysia Pahang, Lebuhraya Tun Razak 26300 Kuantan, Pahang, Malaysia
Nugroho Dewayanto  -  Universiti Kuala Lumpur, Malaysian Institute of Chemical and Bioengineering Technology, Vendor City 1988, 78000 Alor Gajah, Melaka, Malaysia
Du Dongyun  -  Key Laboratory for Catalysis and Materials Science of the State Ethnic Affairs Commissions & Ministry of Education, South Central University for Nationalties, Wuhan 430074, China
Mohd Ridzuan Nordin  -  Faculty of Technology Management And Technopreneurship, Universiti Teknikal Malaysia Melaka, Hang Tuah Jaya, 76100 Durian Tunggal, Melaka, Malaysia
Mohd Hasbi Ab Rahim  -  Faculty of Industrial Sciences and Technology, Universiti Malaysia Pahang, Lebuhraya Tun Razak 26300 Kuantan, Pahang, Malaysia
Received: 12 Mar 2016; Published: 20 Aug 2016.
Open Access Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

Citation Format:
Cover Image
Article Info
Section: The International Conference on Fluids and Chemical Engineering (FluidsChE 2015)
Language: EN
In 2016: BCREC Volume 11 Issue 2 Year 2016 (SCOPUS and Web of Science Indexed, August 2016)
Statistics: 1299 530
Abstract

Zero valent iron supported on mesoporous silicanano particles (NZVI/MSNs) was prepared by the aqueous phase borohydride reduction methods. Prior to the reduction, mesoporous silica nanoparticles (MSNs) were prepared through the activation of fumed silica with concentrated HCl by refluxing at 90 °C. FTIR, XRD, FESEM, EDX and BET were used to characterize theadsorbents prepared. BET surface areas of MSNs, NZVI, and NZVI/MSNs were 126, 41, and 72 m2/g for, respectively. The performance of NZVI/MSNs as adsorbent was examined by adsorption of methylene blue (MB), performed in series of batch experiments. In the kinetic studies, pseudo first order and pseudo second order kinetic models were examined. The pseudo second order equation provided the best fit with the experimental data. Thermodynamic studies indicated that the adsorption process is endothermic with ΔH° was 90.53 kJ/mol. Positive ΔS° (300 J/mol) and negative ΔG° (-6.42 kJ/mol) was recorded, indicating the spontaneous of the adsorption process and naturally favorable. Copyright © 2016 BCREC GROUP. All rights reserved

Received: 5th March 2016; Revised: 18th March 2016; Accepted: 18th March 2016

How to Cite: Hameed, A.K., Dewayanto, N., Dongyun, D., Nordin, M.R., Mohd Hasbi Ab. Rahim, M.H.A. (2016). Kinetic and Thermodynamics of Methylene Blue Adsorption onto Zero Valent Iron Supported on Mesoporous Silica. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2): 250-261 (doi:10.9767/bcrec.11.2.443.250-261)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.2.443.250-261

Article Metrics: (click on the button below to see citations in Scopus)

cited by count 

Keywords: Zero valent iron; Adsorption kinetics, Adsorption Thermodynamics; Methylene blue; Mesoporous silica

Article Metrics:

  1. Sarioglu, M., Atay, U., A. (2006). Removal of methylene blue by using bio solid “, Global NEST Journal, 8 (2) : 113 -120.
  2. Badruddoza, A., Goh, S., Hidajat, K. Uddin, M., (2010). Synthesis of carboxymethyl--cyclodextrin conjugated magnetic nano-adsorbent for removal of methylene blue. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 367(1-3): 85–95.
  3. Fail, A .B ., Ozmetin, C. , Korkmaz , M. (2012) . Cationic dye (methylene blue) removal from aqueous solution by montrmorillonite , Bull. Korean Chem. Soc., 33, (10):.3184 3190
  4. Oyelude, E., O., Takyi, F. , A. , Felix, A. (2012). Removal of methylene blue from aqueous solution using alkali modified malted sorghum mash . Turkish Journal Engineering. Environment. Science,6 :161 – 169.
  5. Kadirova, Z. C., Katsumata, K., Isobe, T. , Matsushita , N., Nakajima , A., Okada , K . (2013). Adsorption And Photodegradation of Methylene blue by iron oxide impregnated on granular activated carbons in an oxalate solution . Applied surface science 284: 72-79.
  6. Rahman, M. A. ,Amin , S. M. R. and Alam , A. M. S. (2012). Removal of Methylene Blue from Waste Water Using Activated Carbon Prepared from rice husk . Dhaka Univ. Journal of Science. 60(2): 185-189.
  7. Shih, Y. H. , Tso , C. P., Tung , L. Y., (2010) . Rapid degradation of methyl orange with nano scale zero valent iron particles.. Journal of Environ. Eng. Manage., 20 (3) : 137-143.
  8. Ho,Y., Malarvizhi, ., R., Sulochana, N.(2009). Equilibrium Isotherm Studies of Methylene Blue Adsorption onto Activated Carbon Prepared from Delonix regia Pods.Journal of Environmental Protection Science, 3: 111–116.
  9. Muslim, , M. A., Hammoud, Z. A. (2014) .Removal of Methylene Blue from Aqueous Solution by using iron filings waste material in batch and continuous experiments. Journal of Babylon University/Engineering Sciences 22 (1):.35-45.
  10. Sun, X., Yan, Y.,,Li, J., Hana , W., Wang, L., (2014). Nanoscale Zero-Valent iron Particles for chromium(VI) removal from groundwater: Mechanism, effect of pH, humic acid and sustained reactivity “ Journal of Hazard materials 12, : 26-33.
  11. Park, J., Han, Y., Kim, H. (2012). Formation of Mesoporous Materials from Silica dissolved in various NaOH concentrations: Effect of pH and ionic strength. Journal of Nanomaterials, (2012).
  12. Hameed, A. K , Dewayanto , N. , Dongyun , Du. , Nordin , M. R .(2014) . Synthesis and Characterization of Nano Scale Zero-Valent Iron Supported on Mesoporous Silica . 9th Joint Conference on Chemistry , Indonesia.
  13. Petala, E., Dimos , K., Douvalis , A., Bakas , T., Tucek , J., Zboril , R. and Karakassides , M. , A. (2013) . Nano Scale Zero-Valent Iron Supported on Mesoporous Silica : Characterization and Reactivity for Cr(VI) Removal from Aqueous Solution . Journal of Hazardous Materials, 216 (2) : 295-306.
  14. Karim, A.K., Jalil, S., Triwahyono, N. H. N., Kamarudin, N. F. M. Salleh, (201`2). Adsorption of Methylene Blue From Aqueous Ssolution by Mesostructured Silica nanoparticles,” in Conference on Emerging Energy and Process Technology (CONCEPT).
  15. Ling, X ., Li, J. , Zhu, W. ,Zhu, Y. , Sun, X. , Shen, J. ,Han, W. , Wang, L. (2012) .Synthesis of Nano Scale Zero-Valent Iron /ordered Mesoporous Carbon For Adsorption and Synergistic Reduction of Nitrobenzene . Chemosphere, 87: 655-660.
  16. Noubactep, C., Care, S., Caren, R. (2012). Nano Scale Metallic Iron for Environmental Remediation: Prospects and limitations . Water Air Soil Pollutes, 223: .1363–1382.
  17. Kirk, C. T. (1988). Quantitative Analysis of The Effect of Disorder-Induced Mode Coupling on Infrared Absorption in Silica.Physical Review B, 38 (2):1255–1273.
  18. Kamitsos, E. I., Patsis, A. P., Kordas, G. (1993). Infrared-Reflectance Spectra of Heat-Treated Sol-gel-Derived Silica. Physical Review B, 48(17): 12499–12505.
  19. K. Dimos,K., Antoniou, M. K., . Meichanetzoglou, A., Lymperopoulou,S., Ouzouni, M. D., Koutselas, I. B., Fokas, D., Karakassides, M.A., Agostino, R. G. , Gournis, D.(2012). Naphthalene-Based Periodic Nanoporous OrganoSilicas: I. Synthesis and Structural Characterization. Microporous and Mesoporous Materials, 158, : 324–331.
  20. Frost, R. L. Xi, Y., He, H. (2013). Synthesis, Characterization of Palygorskite Supported Zero-Valent Iron and Its Application for Mmethylene Blue Adsorption. Journal of Colloid and Interface Science, 341: 153-161.
  21. Wang, P. Cao, M., Wang, Ch., Ao, Y., Hou, J., Qian, J. (2014). Kinetics and Thermodynamics of Adsorption of Methylene Blue by a Magnetic Graphene-Carbon Nanotube Composite. Applied Surface Science, 290 :116-124.
  22. Wang, L., Li, J. (2013).Removal of Methylene Blue from Aqueous Solution by Adsorption onto Crofton Weed Stalk.Bio Recourse, 8(2) : 2521-2536.
  23. Gouamid, M., Ouahrani,M. R. Bensaci, M. B.(2013). Adsorption Equilibrium, Kinetics and Thermodynamics of Methylene Blue from Aqueous Solutions Using Date palm Leaves. Energy Procedia, 36: 898–907.
  24. Suteu, D., Malutan, T. (2013). Industrial Cellolignin Wastes as Adsorbent for Removal of Methylene Blue Dye from Aqueous Solutions. Bio Resources, 8(1):427-446.
  25. Derakhshan, Z., Baghapour, M. (2013). Adsorption of Methylene Blue Dye from Aqueous Solutions by Modified Pumice Stone: Kinetics and Equilibrium Studies. Health Scope, 2(3): 136–44.
  26. ALzaydien,A.S.(2009). Adsorption of Methylene Blue from Aqueous Solution onto a Low-Cost Natural Jordanian Tripoli. American Journal of Applied Sciences, 6(6): 1047–1058.
  27. Abdel Ghafar, H. H., Ali, G. A. M., Fouad, O. A., Makhlouf, S. A. (2013). Enhancement of Adsorption Efficiency of Methylene Blue on Co3O4/SiO2 Nanocomposite. Desalination and Water Treatment, 53(11): 2980–2989.
  28. Kareem, S. H. Ali, I. H., Jalhoom, M. G.(2014). Synthesis and Characterizationof Organic Functionalized Mesoporous Silica and Evaluate Their Adsorptive Behavior for Removal of Methylene Blue From Aqueous Solution. American Journal of Environmental Sciences, 10(1): 48–60.
  29. Tan, I. A.W., Ahmad, A.L., Hameed, B. H. (2008). Adsorption of Basic Dye on High-Surface-Area Activated Carbon Prepared from Coconut Husk: Equilibrium, Kinetic and Thermodynamic Studies. Journal of Hazardous Materials, 154(1-3): 337–346.

No citation recorded.

Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis License URL: http://creativecommons.org/licenses/by-sa/4.0

Author(s) Rights

As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including: use for classroom teaching by Author or Author's institutionand presentation at a meeting or conference and distributing copies to attendees; use for internal training by author's company; distribution to colleagues for their reseearch use; use in a subsequent compilation of the author's works; inclusion in a thesis or dissertation; reuse of portions or extracts from the article in other works (with full acknowledgement of final article); preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article); voluntary posting on open web sites operated by author or author’s institution for scholarly purposes (should follow CC by SA License).

Authors can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (cite to the article or content), provide a link to the license, and indicate if changes were made. If you remix, transform, or build upon the material, you must redistribute your contributions under the same license as the original.

Copyright Transfer Agreement (for Publishing)

The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright publishing of the article shall be assigned/transferred to Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) as Publisher of the journal. Upon acceptance of an article, authors will be asked to complete a 'Copyright Transfer Agreement' (see more information on this). An e-mail will be sent to the corresponding author confirming receipt of the manuscript together with a 'Copyright Transfer Agreement' form by online version of this agreement.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia-Indonesian Catalyst Society (MKICS), the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of copyright, our journal authors retain (or are granted back) significant scholarly rights as mention before.

The Copyright Transfer Agreement (CTA) Form can be downloaded here: [Copyright Transfer Agreement (CTA) Form BCREC 2020] 


The copyright form should be signed electronically and send to the Editorial Office in the form of original e-mail below:  

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering & Catalysis
Department of Chemical Engineering, Diponegoro University
Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Telp.: +62-24-7460058, Fax.: +62-24-76480675
E-mail: bcrec[at]live.undip.ac.id