Optimization of Monoglycerides Production Using KF/CaO-MgO Heterogeneous Catalysis

Luqman Buchori  -  Department of Chemical Engineering, Diponegoro University, Indonesia
*Didi Dwi Anggoro scopus  -  Department of Chemical Engineering, Diponegoro University, Indonesia
Indro Sumantri  -  Department of Chemical Engineering, Diponegoro University, Indonesia
Riko Rikardo Putra  -  Department of Chemical Engineering, Diponegoro University, Indonesia
Received: 25 Jan 2019; Revised: 28 May 2019; Accepted: 29 May 2019; Published: 1 Dec 2019; Available online: 30 Sep 2019.
Open Access Copyright (c) 2019 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

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Abstract

The production of monoglyceride or monoacylglycerol (MAG) from triglycerides and glycerol has been studied. The purpose of this research was to study the effect of using KF/CaO-MgO catalyst on MAG production with batch reactor. The effect of reaction temperature, reaction time, and catalyst loading was investigated using Response Surface Methods (RSM). The reaction temperature, reaction time, and catalyst loading were varied at 200-220 ºC,  2-4 hours, and 0.1-0.3 % w/w, respectively. The maximum yield of monoglyceride 41.58% was achieved the optimum conditions of  catalyst loading of 0.19 % (w/w), reaction temperature of 208.4 ºC, and reaction time of 3.20 hours. Copyright © 2019 BCREC Group. All rights reserved

 

Keywords: KF/Ca-MgO Catalyst; Monoglyceride; Optimization; Response Surface Method
Funding: Diponegoro University for the financial support received with Project No: 474–103/VN7.P43/PP/2018

Article Metrics:

  1. Buchori, L., Istadi, I., Purwanto, P. (2016). Advanced Chemical Reactor Technologies for Biodiesel Production from Vegetable Oils - A Review. Bulletin of Chemical Reaction Engineering & Catalysis, 11(3): 406-429
  2. Ferretti, C.A., Soldano, A., Apesteguía, C.R., Di Cosimo, J.I. (2010). Monoglyceride Synthesis by Glycerolysis of Methyl Oleate on Solid Acid–Base Catalysts. Chemical Engineering Journal, 161: 346–354
  3. Belelli, P.G., Ferretti, C.A., Apesteguía, C.R., Ferullo, R.M., Di Cosimo, J.I. (2015). Glycerolysis of Methyl Oleate on MgO: Experimental and Theoretical Study of the Reaction Selectivity. Journal of Catalysis, 323: 132–144
  4. Balsamo, N.F., Sapag, K., Oliva, M.I., Pecchi, G.A., Eimer, G.A., Crivello, M.E. (2017). Mixed Oxides Tuned with Alkaline Metals to Improve Glycerolysis for Sustainable Biodiesel Production, Catalysis Today, 279: 209–216
  5. Breeden, D.L., Meyer, R.L. (2005). Ester-Containing Downhole Drilling Lubricating Composition and Processes Therefor and Therewith. US Patent No. 6884762B2
  6. Chetpattananondh, P., Tongurai, C. (2008). Synthesis of High Purity
  7. Monoglycerides from Crude Glycerol and Palm Stearin. Songklanakarin Journal of Science and Technology, 30(4): 515-521
  8. Ferretti, C.A., Di Cosimo, J.I. (2018). Kinetic and Theoretical Study of the Conversion Reactions of Methyl Oleate with Glycerol on MgO, Molecular Catalysis, 458: 230–239
  9. Rosen, M., Hall, L.K. (1982). Glyceryl Monostearate Plastic Lubricants, US Patent No. 4,363,891
  10. Kore, P.P., Kachare, S.D., Kshirsagar, S.S., Oswal, R.J. (2012). Base Catalyzed Glycerolysis of Ethyl Acetate, Organic Chemistry: Current Research, 1(4): 108–111
  11. Satriana, Arpi, N., Lubis, Y.M., Adisalamun, Supardan, M.D., Mustapha, W.A.W. (2016). Diacylglycerol-enriched Oil Production Using Chemical Glycerolysis, European Journal of Lipid Science and Technology, 118: 1-11
  12. Ferretti, C.A., Apesteguía, C.R., Di Cosimo, J.I. (2011). MgO-based Catalysts for Monoglyceride Synthesis from Methyl Oleate and Glycerol: Effect of Li Promotion, Applied Catalysis A: General, 399: 146–153
  13. Ferretti, C.A., Fuente, S., Ferullo, R., Castellani, N., Apesteguía, C.R., Di Cosimo, J.I. (2012). Monoglyceride Synthesis by Glycerolysis of Methyl Oleate on MgO: Catalytic and DFT Study of the Active Site, Applied Catalysis A: General, 413-414: 322-331
  14. Schulz, G.A.S., da Silveira, K.C., Libardi, D.B., Peralba, M.C.R., and Samios, D. (2011). Synthesis and Characterization of Mono-Acylglycerols through the Glycerolysis of Methyl Esters Obtained from Linseed Oil, European Journal of Lipid Science and Technology, 113: 1533–1540
  15. Kesić, Ž., Lukić, I., Brkić, D., Rogan, J., Zdujić, M., Liu, H., Skala, D. (2012). Mechanochemical Preparation and Characterization of CaO-ZnO Used as Catalyst for Biodiesel Synthesis, Applied Catalysis A: General, 427-428, 58-65
  16. Taufiq-Yap, Y.H., Lee, H.V., Hussein, M.Z., Yunus, R. (2011). Calcium-based Mixed Oxide Catalysts for Methanolysis of Jatropha Curcas Oil to Biodiesel, Biomass and Bioenergy, 35(2): 827-834
  17. Anggoro, D.D., Buchori, L., Sasongko, S.B., Oktavianty, H. (2019). Optimization of Basicity of KF/Ca-MgO Catalyst by Impregnation Method, selected paper in Bulletin of Chemical Reaction Engineering & Catalysis, Department of Chemical Engineering, Diponegoro University
  18. Yang, F., Xiang, W., Sun, X., Wu, H., Li, T., Long, L. (2014). A Novel Lipid Extraction Method from Wet Microalga Picochlorum Sp. at Room Temperature, Marine Drugs, 12(3): 1258–1270
  19. Montgomery, D.C. (2001). Design and Analysis of Experiments, 5th edition, John Wiley & Sons, New York,
  20. Cornell, J.A. (1991). Experiments with Mixtures: Designs, Models, and the Analysis of Mixture Data, Journal of the American Statistical Association, 86(415): 56–57
  21. Solaesa, A.G., Sanz, M.T., Beltrán, S., Melgosa, R. (2016). Kinetic Study and Kinetic Parameters of Lipase‐Catalyzed Glycerolysis of Sardine Oil in a Homogeneous Medium, Chinese Journal of Catalysis, 37: 596–606
  22. Coker, A.K. (2001). Modeling of Chemical Kinetics and Reactor Design, 1st edition, Gulf Publishing Company, United States of America
  23. Thanh, L.T., Okitsu, K., Boi, L.V., Maeda, Y. (2012). Catalytic Technologies for Biodiesel Fuel Production and Utilization of Glycerol: A Review, Catalysts, 2: 191-222
  24. Prakoso, T., Sukanti, M.M. (2007). Production of Monoglycerides, Indonesian Journal of Chemical Engineering, 6(3): 689–697

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Last update: 2021-05-07 22:20:31

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