Effect of Co and Mo Loading by Impregnation and Ion Exchange Methods on Morphological Properties of Zeolite Y Catalyst

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Coal tar can be used as an alternative raw material for the production of liquid fuels, such as: gasoline and diesel through hydrogenation and cracking process. Hydrogenation and cracking process requires a catalyst which has metal components for hydrogenation reaction and acid components for cracking reaction. In this study, the Co/Zeolite Y and Co-Mo/Zeolite Y catalysts were prepared by impregnation and ion exchange methods. Characterizations of the catalysts were carried out by X-Ray Diffraction (XRD) and gravimetric acidity. The catalysts were tested for coal tar conversion to liquid fuel under various temperatures, amount of catalyst and hydrogen flow rates in a fixed bed flow reaction system. Liquid fuels products were analyzed by gas chromatography (GC). The XRD Spectra indicated that the addition of Co and Mo metals did not affect catalysts structure, however it alters the percentage of crystallinity. The addition of Co metal using impregnation method caused reduction in crystallinity, while the addition of Mo caused improvement of crystallinity. The Co-Mo/Zeolite Y catalyst with highest crystallinity was obtained by loading using ion exchange method. The addition of Co and Mo metals caused increasing acidity. However, the increasing composition of Co and Mo loaded on Zeolite Y catalyst decreased the yield of liquid fuels from coal tar. It can be concluded that the yields of liquid fuels and the composition of gasoline fractions from hydrocracking of coal tar were highly dependent on acidity of the catalyst. Copyright © 2016 BCREC GROUP. All rights reserved
Received: 10th November 2015; Revised: 16th January 2016; Accepted: 16th January 2016
How to Cite: Anggoro, D.D., Hidayati, N., Buchori, L., Mundriyastutik, Y. (2016). Effect of Co and Mo Loading by Impregnation and Ion Exchange Methods on Morphological Properties of Zeolite Y Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1): 75-83. (doi:10.9767/bcrec.11.1.418.75-83)
Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.1.418.75-83
Article Metrics: (click on the button below to see citations in Scopus)
Article Metrics:
- Anonim. (2013, Januari). Energi Sumber Daya Mineral (ESDM). Retrieved Oktober 15, 2013, from http://www.esdm.go.id/statistik/ data-sektor-esdm/cat_view/58-publikasi/240-statistik/341-statistik-minyak-bumi.html
- Kan, T., Wang, H., He, H., Li, C., Zhang, S., (2011) Experimental Study on Two-stage catalytic hydroprocessing of middle-temperature Coal tar to clean liquid fuels, Fuel, 90: 3404-3409
- Rokhati, N. (1999). Pirolisis Tir Batu Bara Secara Sinambung, Master Thesis. Universitas Gajah Mada (in Indonesian)
- Krichko, A.A., Maloletnev, A.S., Mazneva, O., Gagarin, S.G (1996). Catalytic Properties of High-Silica Zeolite in Hydrotreatment of Coal Liquefaction Product, Fuel, 76: 683-685
- Fanani, Z. (2010). Hidrocrakcing Tir Batubara Menggunakan Katalis Ni-Mo-S/ZAA untuk Menghasilkan Fraksi Bensin dan Fraksi Kerosen, Jurnal Penelitian Sains, 1006, (08) 22-33
- Sayan, S, Paul, J. (2002) Hydrogenation of naphthalene and methylnaphthalene: Modeling and spectroscopy. J. Molec. Catal. A: Chem., 185: 211–222
- Ramirez, J., Rayo, P., GutiRrez-Alejandre, A., Ancheyta, J., Rana, M.S. (2005) Analysis of the hydrotreatment of Maya heavy crude with NiMo catalysts supported on TiO2-Al2O3 binary oxides: Effect of the incorporation method of Ti. Catal. Today, 109: 54-60
- Wang, L., Shen, B., Fang, F., Wang, F., Tian, R., Zhang, Z., Cui, L. (2010) Upgrading of light cycle oil via coupled hydrogenation and ring-opening over NiW/Al2O3-USY catalysts. Catal. Today 158: 343-347
- Arribas, M.A., Martı́nez, A. (2002) The influence of zeolite acidity for the coupled hydrogenation and ring opening of 1-methylnaphthalene on Pt/USY catalysts. Appl. Catal. A: Gen., 230: 203-217
- Leite, L., Benazzi, E., Marchal-George, N. (2001) Hydrocracking of phenanthrene over bifunctional Pt catalysts. Catal. Today, 65: 241-247
- Hassan, A., Ahmed, S., Ali, M.A., Hamid, H., Inui, T. (2001) A comparison between [beta]- and USY-zeolite-based hydrocracking catalysts. Appl. Catal. A: Gen., 220: 59-68
- Gallezot, P. (1979) The state and catalytic properties of platinum and palladium in faujasite-type zeolites. Catal. Rev. Sci. Eng. 20: 121–154
- Zheng, J., Guo, M., Song, C. (2008) Characterization of Pd catalysts supported on USY zeolites with different SiO2/Al2O3 ratios for the hydrogenation of naphthalene in the presence of benzothiophene. Fuel Process. Technol., 89: 467-474
- Yasuda, H., Sato, T., Yoshimura, Y. (1999) Influence of the acidity of USY zeolite on the sulfur tolerance of Pd-Pt catalysts for aromatic hydrogenation. Catal. Today, 50: 63-71
- Chorkendorff, Niemantsverdriet, (2003) Concepts of Modern Catalyst and Kinetics, WILEY-VSH Verlag GmbH & Co. KGaA, Weinheim
- Emelik, B., (1980) Catalysis by Zeolite, Proceeding of an International Symposium, Elsevier Scientific, Publishing Co, New York
- Tsitsishvili, G.V. (1992) Natural Zeolites, Ellis Horwood. New York,16-19
- Zeno, R.R., Tria, F. (2015), Effect of Co and Mo Metal Addition in Co-Mo/Zeolite Y Catalyst for Coal Tar Conversion To Liquid Fuel, Undergraduate Thesis, Chemical Engineering, Diponegoro University
- Li, L., Quan, K., Xu, J., Liu, F., Liu, S., Yu, S., Xie, C., Zhang, B., Ge, X. (2014) Liquid hydrocarbon fuels from catalytic cracking of rubber seed oil using USY as catalyst, Fuel, 123: 189-193
- Nicolaides, C.P. (1999). A novel family of solid acid catalysts: substantially amorphous orpartially crystalline zeolitic materials, Applied Catalysis A: General 185: 211-217
- Trisunaryanti, W. (2002) Optimation of Time and Catalyst/Feed Ratio in Catalytic Cracking of Waste Plastics Fraction to Gasoline Fraction Using Cr/Natural Zeolite Catalyst, Indonesian Journal of Chemistry, 2: 30-40
- Anggoro, D.D, Amin, N.A.S. (2006) Methane to Liquid Hydrocarbons over Tungsten-ZSM-5 and Tungsten Loaded Cu/ZSM-5 Catalysts, Journal of Natural Gas Chemistry 15: 340-347
- Trisunaryanti, W., Purwono, S., Putra, A. (2008) Catalytic Hydrocracking of Waste Lubricant Oil Into Liquid Fuel Fraction Using ZnO, Nb2O5, Activated Natural Zeolite Their Modification, Indo. J. Chem., 342-347
- Lin, L., Qiu, C., Zhuo, Z., Zhang, D., Zhao, S., Wu, H., Liu, Y., He, M. (2014) Acid Strength Controlled Reaction Pathways for the Catalytic Cracking of 1-Butene to Propene over ZSM-5, Journal of Catalysis, 309: 136-145
Last update: 2021-04-18 09:31:02
Last update: 2021-04-18 09:31:03
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