Preliminary Testing of Hybrid Catalytic-Plasma Reactor for Biodiesel Production Using Modified-Carbon Catalyst

Luqman Buchori  -  Department of Chemical Engineering, Faculty of Engineering, Diponegoro University, Jl. Prof. Soedarto, SH, Kampus Undip Tembalang, Semarang 50275, Indonesia
*Istadi Istadi  -  Department of Chemical Engineering, Faculty of Engineering, Diponegoro University, Jl. Prof. Soedarto, SH, Kampus Undip Tembalang, Semarang 50275, Indonesia
Purwanto Purwanto  -  Department of Chemical Engineering, Faculty of Engineering, Diponegoro University, Jl. Prof. Soedarto, SH, Kampus Undip Tembalang, Semarang 50275, Indonesia
Anggun Kurniawan  -  Department of Chemical Engineering, Faculty of Engineering, Diponegoro University, Jl. Prof. Soedarto, SH, Kampus Undip Tembalang, Semarang 50275
Teuku Irfan Maulana  -  Department of Chemical Engineering, Faculty of Engineering, Diponegoro University, Jl. Prof. Soedarto, SH, Kampus Undip Tembalang, Semarang 50275, Indonesia
Received: 10 Nov 2015; Revised: 16 Jan 2016; Accepted: 16 Jan 2016; Published: 1 Apr 2016; Available online: 10 Mar 2016.
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Section: The 2nd International Conference on Chemical and Material Engineering 2015
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Preliminary testing of hybrid catalytic-plasma reactor for biodiesel production through transesterification of soybean oil with methanol over modified-carbon catalyst was investigated. This research focused on synergetic roles of non-thermal plasma and catalysis in the transesterification process. The amount of modified-carbon catalyst with grain size of 1.75 mm was placed into fixed tubular reactor within discharge zone. The discharge zone of the hybrid catalytic-plasma reactor was defined in the volume area between high voltage and ground electrodes. Weight Hourly Space Velocity (WHSV) of 1.85 h-1 of reactant feed was studied at reaction temperature of 65 oC and at ambient pressure. The modified-carbon catalyst was prepared by impregnation of active carbon within H2SO4 solution followed by drying at 100 oC for overnight and calcining at 300 oC for 3 h. It was found that biodiesel yield obtained using the hybrid catalytic-plasma reactor was 92.39% and 73.91% when using active carbon and modified-carbon catalysts, respectively better than without plasma. Therefore, there were synergetic effects of non-thermal plasma and catalysis roles for driving the transesterification process. Copyright © 2016 BCREC GROUP. All rights reserved

Received: 10th November 2015; Revised: 16th January 2016; Accepted: 16th January 2016

How to Cite: Buchori, L., Istadi, I., Purwanto, P., Kurniawan, A., Maulana, T.I. (2016). Preliminary Testing of Hybrid Catalytic-Plasma Reactor for Biodiesel Production Using Modified-Carbon Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1): 59-65. (doi:10.9767/bcrec.11.1.416.59-65) 


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Keywords: biodiesel; modified-carbon catalyst; hybrid catalytic-plasma reactor; transesterification

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  1. Juan, J.C., Kartika, D.A., Wu, T.Y., Hin, T.Y.Y. (2011). Biodiesel production from jatropha oil by catalytic and non-catalytic approaches: An overview, Bioresour. Technol., 102(2): 452-460.
  2. Zheng, S., Kates, M., Dubé, M.A., McLean, D.D. (2006). Acid-catalyzed production of biodiesel from waste frying oil, Biomass and Bioenergy, 30(3): 267-272.
  3. Bhatti, H., Hanif, M., Qasim, M. (2008). Biodiesel production from waste tallow, Fuel, 87(13-14): 2961-2966.
  4. Issariyakul, T., Dalai, A.K. (2010). Biodiesel production from greenseed canola oil, Energy and Fuels, 24(7): 4652-4658.
  5. Rashid, U., Anwar, F., Moser, B.R., Ashraf, S. (2008). Production of sunflower oil methyl esters by optimized alkali-catalyzed methanolysis, Biomass and Bioenergy, 32(12): 1202-1205.
  6. Melero, J.A., Bautista, L.F., Morales, G., Iglesias, J., Sánchez-Vázquez, R. (2010). Biodiesel production from crude palm oil using sulfonic acid-modified mesostructured catalysts, Chem. Eng. J., 161(3): 323-331.
  7. Yan, F., Yuan, Z., Lu, P., Luo, W., Yang, L. Deng, L. (2011). Fe-Zn double-metal cyanide complexes catalyzed biodiesel production from high-acid-value oil, Renew. Energy, 36(7): 2026-2031.
  8. Liu, X., Xiong, X., Liu, C., Liu, D., Wu, A., Hu, Q., Liu, C. (2010). Preparation of biodiesel by transesterification of rapeseed oil with methanol using solid base catalyst calcined K2CO3/Al2O3, J. Am. Oil Chem. Soc., 87(7): 817-823.
  9. Sun, H., Ding, Y., Duan, J., Zhang, Q., Wang, Z., Lou, H., Zheng, X. (2010). Transesterification of sunflower oil to biodiesel on ZrO2 supported La2O3 catalyst, Bioresour. Technol., 101(3): 953-958.
  10. Jegannathan, K.R., Abang, S., Poncelet, D., Chan, E.S., Ravindra, P. (2008). Production of biodiesel using immobilized lipase-a critical review, Crit. Rev. Biotechnol., 28(4): 253-264.
  11. Yan, J., Zheng, X., Li, S. (2014). A novel and robust recombinant Pichia pastoris yeast whole cell biocatalyst with intracellular overexpression of a Thermomyces lanuginosus lipase: Preparation, characterization and application in biodiesel production, Bioresour. Technol., 151: 43-48.
  12. Kumari, V., Shah, S., Gupta, M.N. (2007). Preparation of biodiesel by lipase-catalyzed transesterification of high free fatty acid containing oil from Madhuca indica, Energy and Fuels, 21(12): 368-372.
  13. Christopher, L.P., Kumar, H., Zambare, V.P. (2014). Enzymatic biodiesel: Challenges and opportunities, Appl. Energy, 119: 497-520.
  14. Bajaj, A., Lohan, P., Jha, P.N., Mehrotra, R. (2010). Biodiesel production through lipase catalyzed transesterification: An overview, J. Mol. Catal. B: Enzym., 62(1): 9-14.
  15. Hama, S., Kondo, A. (2013). Enzymatic biodiesel production: An overview of potential feedstocks and process development, Bioresour. Technol., 135: 386-395.
  16. Micic, R.D., Tomić, M.D., Kiss, F.E., Nikolić-Djorić, E.B., Simikić, M. (2014). Influence of reaction conditions and type of alcohol on biodiesel yields and process economics of supercritical transesterification, Energy Convers. Manag., 86: 717-726.
  17. Yin, J.Z., Xiao, M., Song, J.B. (2008). Biodiesel from soybean oil in supercritical methanol with co-solvent, Energy Convers. Manag., 49(5): 908-912.
  18. Chen, K.S., Lin, Y.C., Hsu, K.H., Wang, H.K. (2012). Improving biodiesel yields from waste cooking oil by using sodium methoxide and a microwave heating system, Energy, 38(1): 151-156.
  19. Encinar, J.M., González, J.F., Martínez, G., Sánchez, N., Pardal, A. (2012). Soybean oil transesterification by the use of a microwave flow system, Fuel, 95: 386-393.
  20. Babajide, O., Petrik, L., Amigun, B., Ameer, F. (2010). Low-cost feedstock conversion to biodiesel via ultrasound technology, Energies, 3(10): 1691-1703.
  21. Maddikeri, G.L., Pandit, A.B., Gogate, P.R. (2013). Ultrasound assisted interesterification of waste cooking oil and methyl acetate for biodiesel and triacetin production, Fuel Process. Technol., 116: 241-249.
  22. Istadi, I., Yudhistira, A.D., Anggoro, D.D., Buchori, L. (2014). Electro-Catalysis System for Biodiesel Synthesis from Palm Oil over Dielectric-Barrier Discharge Plasma Reactor, Bull. Chem. React. Eng. Catal., 9(2): 111-120. (doi: 10.9767/bcrec.9.2.6090.111-120)
  23. Lawson, J.A., Baosman, A.A. (2010). Method of Electro-Catalytic Reaction to Produce Mono Alkyl Esters for Renewable Biodiesel, US Patent 7,722,755 B2 (25 May 2010).
  24. Ketcong, A., Meechan, W., Naree, T., Seneevong, I., Winitsorn, A., Butnark, S., Ngamcharussrivichai, C. (2014). Production of fatty acid methyl esters over a limestone-derived heterogeneous catalyst in a fixed-bed reactor, J. Ind. Eng. Chem., 20(4): 1665-1671.
  25. Wali, W.A., Al-Shamma’, A.A.I., Hassan, K.H., Cullen, J.D. (2012). Online genetic-ANFIS temperature control for advanced microwave biodiesel reactor, J. Process Control, 22(7): 1256-1272.
  26. Ren, Y., He, B., Yan, F., Wang, H., Cheng, Y., Lin, L., Feng, Y., Li, J. (2012). Continuous biodiesel production in a fixed bed reactor packed with anion-exchange resin as heterogeneous catalyst, Bioresour. Technol., 113: 19-22.
  27. Olivares-Carrillo, P., Quesada-Medina, J. (2012). Thermal decomposition of fatty acid chains during the supercritical methanol transesterification of soybean oil to biodiesel, J. Supercrit. Fluids, 72: 52-58.
  28. Furuta, S., Matsuhashi, H., Arata, K. (2006). Biodiesel fuel production with solid amorphous-zirconia catalysis in fixed bed reactor, Biomass and Bioenergy, 30(10): 870-873.
  29. Liu, W., Yin, P., Liu, X., Chen, W., Chen, H., Liu, C., Qu, R., Xu, Q. (2013). Microwave assisted esterification of free fatty acid over a heterogeneous catalyst for biodiesel production, Energy Convers. Manag., 76: 1009-1014
  30. Fridman, A. (2008). Plasma Chemistry, New York, United States of America: Cambridge University Press.
  31. Istadi, I., Amin, N.A.S. (2006). Co-generation of synthesis gas and C2+ hydrocarbons from methane and carbon dioxide in a hybrid catalytic-plasma reactor: A review, Fuel, 85(5-6): 577-592.
  32. Kim, S.S., Lee, H., Na, B.K., Song, H.K. (2004). Plasma-assisted reduction of supported metal catalyst using atmospheric dielectric-barrier discharge, Catal. Today, 89(1-2): 193-200.
  33. Pietruszka, B., Heintze, M. (2004). Methane conversion at low temperature: the combined application of catalysis and non-equilibrium plasma, Catal. Today, 90(1-2): 151-158.
  34. Heintze, M., Pietruszka, B. (2004). Plasma catalytic conversion of methane into syngas: The combined effect of discharge activation and catalysis, Catal. Today, 89(1-2): 21-25.
  35. Liu, C., Mallinson, R., Lobban, L. (1999). Comparative investigations on plasma catalytic methane conversion to higher hydrocarbons over zeolites, Appl. Catal. A: Gen., 178(1): 17-27.
  36. Zhu, X., Gao, X., Qin, R., Zeng, Y., Qu, R., Zheng, C. (2015). Plasma-catalytic removal of formaldehyde over Cu-Ce catalysts in a dielectric barrier discharge reactor, Appl. Catal. B: Environ., 170-171: 293-300.
  37. Konwar, L.J., Boro, J., Deka, D. (20104). Review on latest developments in biodiesel production using carbon-based catalysts, Renew. Sustain. Energy Rev., 29: 546-564.
  38. Shu, Q., Zhang, Q., Xu, G., Nawaz, Z., Wang, D., Wang, J. (2009). Synthesis of biodiesel from cottonseed oil and methanol using a carbon-based solid acid catalyst, Fuel Process. Technol., 90(7-8): 1002-1008.
  39. Huu, T.P., Gil, S., Da Costa, P., Giroir-Fendler, A., Khacef, A. (2015). Plasma-catalytic hybrid reactor: Application to methane removal, Catal. Today, …: 3-9.
  40. Konwar, L.J., Das, R., Thakur, A.J., Salminen, E., Mäki-Arvela, P., Kumar, N., Mikkola, J.P., Deka, D. (2014). Biodiesel production from acid oils using sulfonated carbon catalyst catalystderived from oil-cake waste, J. Molec. Catal. A: Chem., 388-389: 167-176.
  41. Rahimpour, M.R., Jahanmiri, A., Mohamadzadeh Shirazi, M., Hooshmand, N., Taghvaei, H. (2013). Combination of non-thermal plasma and heterogeneous catalysis for methane and hexadecane co-cracking: Effect of voltage and catalyst configuration, Chem. Eng. J., 219: 245-253.

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