Visible Light Photocatalytic Properties of Modified Titanium Dioxide Nanoparticles via Aluminium Treatment

*Dessy Ariyanti -  1Department of Chemical & Materials Engineering, the University of Auckland, Auckland 1142, New Zealand 2Department of Chemical Engineering, Universitas Diponegoro, Semarang 50275, Indonesia, Indonesia
Junzhe Dong -  Department of Chemical & Materials Engineering, the University of Auckland, Auckland 1142, New Zealand
Junye Dong -  Department of Chemical & Materials Engineering, the University of Auckland, Auckland 1142, New Zealand
Wei Gao -  Department of Chemical & Materials Engineering, the University of Auckland, Auckland 1142, Indonesia
Received: 10 Nov 2015; Revised: 7 Jan 2016; Accepted: 7 Jan 2016; Published: 1 Apr 2016; Available online: 10 Mar 2016.
Open Access Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis
Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Citation Format:
Cover Image
Article Info
Section: The 2nd International Conference on Chemical and Material Engineering 2015
Full Text:
In 2016: BCREC Volume 11 Issue 1 Year 2016 (SCOPUS and Web of Science Indexed, April 2016)
Statistics: 899 319
Abstract

Titanium dioxide (TiO2) has gained much attentions for the last few decades due to its remarkable performance in photocatalysis and some other related properties. However, its wide bandgap (~3.2 eV) can only absorb UV energy which is only ~5% of solar light spectrum. The objective of this research was to improve the photocatalytic activity of TiO2 by improving the optical absorption to the visible light range. Here, colored TiO2 nanoparticles range from light to dark grey were prepared via aluminium treatment at the temperatures ranging from 400 to 600 oC. The modified TiO2 is able to absorb up to 50% of visible light (400-700 nm) and shows a relatively good photocatalytic activity in organic dye (Rhodamine B) degradation under visible light irradiation compared with the commercial TiO2. Copyright © 2016 BCREC GROUP. All rights reserved

Received: 10th November 2015; Revised: 7th January 2016; Accepted: 7th January 20

How to Cite: Ariyanti, D., Dong, J.Z., Dong, J.Y., Gao, W. (2016). Visible Light Photocatalytic Properties of Modified Titanium Dioxide Nanoparticles via Aluminium Treatment. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1): 40-47. (doi:10.9767/bcrec.11.1.414.40-47)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.1.414.40-47

Article Metrics: (click on the button below to see citations in Scopus)

cited by count 

Keywords
Colored Titania; Photocatalysis; Photodegradation; TiO2; Visible Light Absorption

Article Metrics:

  1. Fujishima, A., Honda, K. (1972). Electrochemical Photolysis of Water at a Semiconductor Electrode. Nature, 238: 37-38.
  2. Park, H., Park, Y., Kim, W., Choi, W. (2013). Surface modification of TiO2 photocatalyst for environmental applications. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 15: 1-20.
  3. Liu, L., Chen, X. (2014). Titanium Dioxide Nanomaterials: Self-Structural Modifications. Chemical Reviews, 114: 9890-9918.
  4. Chen, X., Liu, L., Huang, F. (2015). Black titanium dioxide (TiO2) nanomaterials. Chemical Society Reviews, 44: 1861-1885.
  5. Schneider, J., Matsuoka, M., Takeuchi, M., Zhang, J., Horiuchi, Y., Anpo, M., Bahnemann, D.W. (2014). Understanding TiO2 Photocatalysis: Mechanisms and Materials. Chemical Reviews, 114: 9919-9986.
  6. Xia, T., Zhang, Y., Murowchick, J., Chen, X. (2014). Vacuum-treated titanium dioxide nanocrystals: Optical properties, surface disorder, oxygen vacancy, and photocatalytic activities. Catalysis Today, 225: 2-9.
  7. Zhuang, J., Dai, W., Tian, Q., Li, Z., Xie, L., Wang, J., Liu, P., Shi, X., Wang, D. (2010). Photocatalytic Degradation of RhB over TiO2 Bilayer Films: Effect of Defects and Their Location. Langmuir, 26: 9686-9694.
  8. Wang, Z., Helmersson, U., Käll, P. (2002). Optical properties of anatase TiO2 thin films prepared by aqueous sol–gel process at low temperature. Thin Solid Films, 405: 50-54.
  9. Wang, H., Lin, T., Zhu, G., Yin, H., Lü, X., Li, Y., Huang, F. (2015). Colored titania nanocrystals and excellent photocatalysis for water cleaning. Catalysis Communications, 60: 55-59.
  10. Diebold, U. (2003). The surface science of titanium dioxide. Surface Science Reports, 48: 53-229.
  11. Pan, J., Maschhoff, B.L., Diebold, U., Madey, T.E. (1992). Interaction of water, oxygen, and hydrogen with TiO2 (110) surfaces having different defect densities. Journal of Vacuum Science & Technology A 10(4): 2470-2476.
  12. Henderson, M.A., Epling, W.S., Perkins, C.L., Peden, C.H.F., Diebold, U. (1999). Interaction of Molecular Oxygen with the Vacuum-Annealed TiO2 (110) Surface: Molecular and Dissociative Channels. The Journal of Physical Chemistry B, 103: 5328-5337.
  13. Wang, J., Tafen, D.N., Lewis, J.P., Hong, Z., Manivannan, A., Zhi, M., Li, M., Wu, N. (2009). Origin of Photocatalytic Activity of Nitrogen-Doped TiO2 Nanobelts. Journal of the American Chemical Society, 131: 12290-12297.
  14. Dong, J., Han, J., Liu, Y., Nakajima, A., Matsushita, S., Wei, S., Gao, W. (2014). Defective Black TiO2 Synthesized via Anodization for Visible-Light Photocatalysis. ACS Applied Materials & Interfaces, 6: 1385-1388.
  15. Lin, T., Yang, C., Wang, Z., Yin, H., Lu, X., Huang, F., Lin, J., Xie, X., Jiang, M. (2014). Effective nonmetal incorporation in black titania with enhanced solar energy utilization. Energy & Environmental Science, 7: 967-972.
  16. Zhu, G., Yin, H., Yang, C., Cui, H., Wang, Z., Xu, J., Lin, T., Huang, F. (2015). Black Titania for Superior Photocatalytic Hydrogen Production and Photoelectrochemical Water Splitting. ChemCatChem, 7: 2614-2619.
  17. Serpone, N. (2006). Is the Band Gap of Pristine TiO2 Narrowed by Anion- and Cation-Doping of Titanium Dioxide in Second-Generation Photocatalysts? The Journal of Physical Chemistry B, 110: 24287-24293.
  18. Hamdam Momen, M., Amadeh, A., Heydarzadeh Sohi, M., Moghanlou, Y. (2014). Photocatalytic properties of ZnO nanostructures grown via a novel atmospheric pressure solution evaporation method. Materials Science and Engineering: B, 190: 66-74.
  19. Naldoni, A., Allieta, M., Santangelo, S., Marelli, M., Fabbri, F., Cappelli, S., Bianchi, C. L., Psaro, R., Dal Santo, V. (2012). Effect of Nature and Location of Defects on Bandgap Narrowing in Black TiO2 Nanoparticles. Journal of the American Chemical Society, 134: 7600-7603.
  20. Yan, C., Yi, W., Yuan, H., Wu, X., Li, F. (2014). A highly photoactive S, Cu-codoped nano-TiO2 photocatalyst: Synthesis and characterization for enhanced photocatalytic degradation of neutral red. Environmental Progress & Sustainable Energy, 33: 419-429.
  21. Kurtz, R.L., Stock-Bauer, R., Msdey, T.E., Román, E., De Segovia, J. (1989). Synchrotron radiation studies of H2O adsorption on TiO2 (110). Surface Science, 218: 178-200.
  22. Henderson, M.A., Epling, W.S., Peden, C.H. F., Perkins, C.L. (2003). Insights into Photoexcited Electron Scavenging Processes on TiO2 Obtained from Studies of the Reaction of O2 with OH Groups Adsorbed at Electronic Defects on TiO2 (110). The Journal of Physical Chemistry B, 107: 534-545

Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. 

Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including: use for classroom teaching by Author or Author's institutionand presentation at a meeting or conference and distributing copies to attendees; use for internal training by author's company; distribution to colleagues for their reseearch use; use in a subsequent compilation of the author's works; inclusion in a thesis or dissertation; reuse of portions or extrcats from the article in other works (with full acknowledgement of final article); preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article); voluntary posting on open web sites operated by author or author’s institution for scholarly purposes (follow CC by SA License).

Authors and readers can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (cite to the article or content), provide a link to the license, and indicate if changes were made. If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.

Copyright Transfer Agreement

The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright publishing of the article shall be assigned to Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University as publisher of the journal.

Copyright encompasses exclusive rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations. The reproduction of any part of this journal, its storage in databases and its transmission by any form or media, such as electronic, electrostatic and mechanical copies, photocopies, recordings, magnetic media, etc., will be allowed only with a written permission from Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University, the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of copyright, our journal authors retain (or are granted back) significant scholarly rights.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form BCREC 2016] 


The copyright form should be signed originally and send to the Editorial Office in the form of original mail, scanned document or fax :  

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering and Catalysis
Department of Chemical Engineering, Diponegoro University
Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Telp.: +62-24-7460058, Fax.: +62-24-76480675
E-mail: bcrec[at]live.undip.ac.id