Preparation and Characterization of Anadara Granosa Shells and CaCO3 as Heterogeneous Catalyst for Biodiesel Production

Hadiyanto Hadiyanto; Sri Puji Lestari; Widayat Widayat

doi:10.9767/bcrec.11.1.402.21-26

DOI: https://doi.org/10.9767/bcrec.11.1.402.21-26

Preparation and Characterization of Anadara Granosa Shells and CaCO3 as Heterogeneous Catalyst for Biodiesel Production

Hadiyanto Hadiyanto , Sri Puji Lestari, Widayat Widayat

Chemical Engineering Department, Faculty of Engineering, Diponegoro University, Jl. Prof. Soedarto, SH, Tembalang, Semarang 50275, Indonesia

Received: 10 Nov 2015; Revised: 6 Jan 2016; Accepted: 6 Jan 2016; Available online: 10 Mar 2016; Published: 1 Apr 2016.

Editor(s): BCREC JM

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Abstract

Nowadays, the use of homogenous catalyst has been gradually reduced for its operational reason. The homogenous catalyst leads in difficulty of separation after the process completed and the life cycle is shorter. Therefore, most of researches are introducing heterogenous catalyst for its substitution. This research was aimed to evaluate the use of shell of Anadara granosa and CaCO3 as source of CaO based catalyst through impregnation method. The preparation of the catalyst was started by decomposition of shells and CaCO3 at temperature of 800 oC for 3 hours, followed by impregnation at 70 oC for 4 hours and then calcined at 800 oC for 2 hours. The CaCO3 based catalyst gained high yield of biodiesel (94%) as compared to Anadara granoasa based catalyst (92%). The reusability study showed that these catalysts could be used until three times recycle with 40-60% yield of biodiesel. The CaO contents of catalyst decreased up to 90% after three times recycles.

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Keywords: Anadara granosa; heterogeneous catalyst; biodiesel; CaO

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Section: The 2nd International Conference on Chemical and Material Engineering 2015

In 2016: BCREC Volume 11 Issue 1 Year 2016 (April 2016)

Lee, S.L., Wong, Y.C., Tan, Y.P., Yew, S.Y. (2015). Transesterification of palm oil to biodiesel by using waste obtuse horn shell-derived CaO catalyst. Energy Conversion and Management, 93: 282-288
Nur, Z.A.S., Taufiq-Yap, Y.H., Nizah, M.F.R., Teo, S.H., Syazwani, O.N., Islam, A. (2014). Production of biodiesel from palm oil using modified Malaysian natural dolomites. Energy Conversion and Management, 78: 738-744
Pasupulety, N., Gunda, K., Liu, Y., Garry, L., Rempel, Ng Flora, T.T. (2013). Production of biodiesel from soybean oil on CaO/Al2O3 solid base catalysts. Applied Catalysis A: General, 452: 189-202
Boro, J., Deka, D., Thakur, A.J. (2012). A review on solid derived from waste shells as catalyst for biodiesel production. Renewable and Sustainable Energy Reviews, 16: 904-910
Viriya-empikul, N., Krasae, P., Puttasawat, B., Yoosuk, B., Chollacoop, N., Faungnawakij, K. (2010) Waste shell of mollusk and egg as biodiesel production catalysts. Bioresource Technology, 101: 3765-3766
Jain, D., Khatri, C., Rani, A. (2011) Synthesis and characterization of novel solid base catalyst from fly ash. Fuel, 90, 2083-2088
Ho, W.W.S, Ng, H.K., Gan, S., Tan, S.H. (2014). Evaluation of palm oil mill fly ash supported calcium oxide as a heterogeneous base catalyst in biodiesel synthesis from crude palm oil. Energy Conversion and Management, 88: 1167–1178
Chakraborty, R., Bepari, S., Banejee, A. (2010) Transesterification of soybean oil catalyzed by fly ash and egg shell derived solid catalysts. Chemical Engineering Journal, 165: 798-805
Liu, X., Piao, X., Wang, Y., Zhu, S. (2008) Calcium ethoxide as a solid base catalyst for the transesterification of soybean oil to biodiesel. Energy & Fuels, 22:1313-1317
Kouzu, M., Kasuno, T., Tajika, M., Yamanaka, S., Hidaka, J. (2008) Active phase of calcium oxide used as solid base catalyst for transesterification of soybean oil with refluxing methanol. Appl. Catal. A, 334: 357-365

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