Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts
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Even though platinum is known as an active electro-catalyst for ethanol oxidation at low temperatures (< 100 oC), choosing the electrode material for ethanol electro-oxidation is a crucial issue. It is due to its property which easily poisoned by a strong adsorbed species such as CO. PtSn-based electro-catalysts have been identified as better catalysts for ethanol electro-oxidation. The third material is supposed to improved binary catalysts performance. This work presents a study of the ethanol electro-oxidation on carbon supported Pt-Sn and Pt-Sn-Ni catalysts. These catalysts were prepared by alcohol reduction. Nano-particles with diameters between 2.5-5.0 nm were obtained. The peak of (220) crystalline face centred cubic (fcc) Pt phase for PtSn and PtSnNi alloys was repositioned due to the presence of Sn and/or Ni in the alloy. Furthermore, the modification of Pt with Sn and SnNi improved ethanol and CO electro-oxidation. Copyright © 2016 BCREC GROUP. All rights reserved
Received: 10th November 2015; Revised: 1st February 2016; Accepted: 1st February 2016
How to Cite: Hidayati, N., Scott, K. (2016). Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1): 10-20. (doi:10.9767/bcrec.11.1.399.10-20)
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- Lamy, C., Belgsir, E.M., Léger, J.M. (2001). Electrocatalytic oxidation of aliphatic alcohols: Application to the direct alcohol fuel cell (DAFC). J. Appl. Electrochem., 31: 799-809.
- Zhou, W., Zhou, Z., Song S, Li. W., Sun, G., Tsiakaras, P., Xin, Q. (2003). Pt based anode catalysts for direct ethanol fuel cells. Appl. Catal. B. Environ., 46: 273-285.
- Delime, F., Leger, J.M., Lamy, C. (1999). Enhancement of the electrooxidation of ethanol on a Pt-PEM electrode modified by tin. Part I: Half cell study. J Appl Electrochem, 29: 1249-1254.
- Camara, G., de Lima, R., Iwasita, T. (2004). Catalysis of ethanol electrooxidation by PtRu: the influence of catalyst composition. Electrochem. Commun., 6: 812-815.
- Liu, Z., Ling, X.Y., Su, X., Lee, J.Y., Gan, L.M. (2005). Preparation and characterization of Pt/C and PtRu/C electrocatalysts for direct ethanol fuel cells. J. Power Sources, 149: 1-7.
- Mann, J., Yao, N., Bocarsly, A.B. (2006). Characterization and analysis of new catalysts for a direct ethanol fuel cell. Langmuir, 22: 10432-10436.
- Sen Gupta, S., Datta, J.A. (2006). Comparative study on ethanol oxidation behavior at Pt and PtRh electrodeposits. J. Electroanal. Chem, 594: 65-72.
- Zhou, W.J., Li, W.Z., Song, S.Q., Zhou, Z.H., Jiang, L.H., Sun, G.Q., et al. (2004). Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells. J .Power Sources, 131: 217-223.
- Song, S.Q., Zhou, W.J., Zhou, Z.H., Jiang, LH., Sun, G.Q., Xin, Q., et al. (2005). Direct ethanol PEM fuel cells: The case of platinum based anodes. Int. J. Hydrogen Energy, 30: 995-1001.
- Wang, H., Jusys, Z., Behm, R.J. (2006). Ethanol electro-oxidation on carbon-supported Pt, PtRu and Pt3Sn catalysts: A quantitative DEMS study. J. Power Sources, 154: 351-359.
- Jiang, L., Colmenares, L., Jusys, Z., Sun, G.Q., Behm, R.J. (2007). Ethanol electrooxidation on novel carbon supported Pt/SnOx/C catalysts with varied Pt:Sn ratio. Electrochim. Acta, 53: 377-389.
- Guo, Y., Zheng, Y., Huang, M., (2008). Enhanced activity of PtSn/C anodic electrocatalyst prepared by formic acid reduction for direct ethanol fuel cells. Electrochim. Acta, 53: 3102-3108.
- Lamy, C., Rousseau, S., Belgsir, E.M., Coutanceau, C., Léger, J.M. (2004). Recent progress in the direct ethanol fuel cell: Development of new platinum-tin electrocatalysts. Electrochim. Acta, 49: 3901-3908.
- Kim, J.H., Choi, S.M., Nam, S.H., Seo, M,H., Choi, S.H., Kim, W.B. (2008). Influence of Sn content on PtSn/C catalysts for electrooxidation of C1-C3 alcohols: Synthesis, characterization, and electrocatalytic activity. Appl. Catal. B Environ., 82: 89-102.
- Colmati, F., Antolini, E., Gonzalez, E.R. (2007). Ethanol Oxidation on Carbon Supported Pt-Sn Electrocatalysts Prepared by Reduction with Formic Acid. J. Electrochem. Soc., 154: B39.
- Zhou, W.J., Song, S.Q., Li, W.Z., Zhou, Z.H., Sun, G.Q., Xin, Q., et al. (2005). Direct ethanol fuel cells based on PtSn anodes: the effect of Sn content on the fuel cell performance. J. Power Sources. 140: 50-58.
- Vigier, F., Coutanceau, C., Hahn, F., Belgsir, E.M., Lamy, C. (2004). On the mechanism of ethanol electro-oxidation on Pt and PtSn catalysts: Electrochemical and in situ IR reflectance spectroscopy studies. J. Electroanal. Chem. 63: 81-89..
- Jiang, L., Sun, G., Zhou, Z., Zhou, W., Xin, Q. (2004). Preparation and characterization of PtSn/C anode electrocatalysts for direct ethanol fuel cell. Catal. Today, 93-95: 665-670.
- Jiang, L., Sun, G., Sun, S., Liu, J., Tang, S., Li, H, et al. (2005). Structure and chemical composition of supported Pt–Sn electrocatalysts for ethanol oxidation. Electrochim. Acta , 50: 5384-5389.
- Spinacé, E. V., Linardi, M., Neto, A.O.(2005). Co-catalytic effect of nickel in the electro-oxidation of ethanol on binary Pt–Sn electrocatalysts. Electrochem. Commun., 7: 365-369.
- Eberhart, J. (1991). Structural and Chemical Analysis of Materials: X-ray, Electron and Neutron Diffraction, X-ray, Electron and Ion Spectrometry, Electron Microscopy. John Wiley and Sons Ltd.
- Mukerjee, S., Srinivasan, S., Soriaga, M.P., McBreen, J. (1995). Role of structural and electronic properties of Pt and Pt alloys on electrocatalysis of oxygen reduction. An in situ XANES and EXAFS investigation. J Electrochem. Soc., 142: 1409-1422.
- Colmati, F., Antolini, E., Gonzalez, E.R. (2007). Ethanol oxidation on a carbon-supported Pt75Sn25 electrocatalyst prepared by reduction with formic acid: Effect of thermal treatment. Appl. Catal. B Environ., 73: 106-115.
- Spinacé, E., Neto, A., Linardi, M. (2004). Electro-oxidation of methanol and ethanol using PtRu/C electrocatalysts prepared by spontaneous deposition of platinum on carbon-supported ruthenium nanoparticles. J. Power Sources, 129: 121-126.
- Lim, D-H., Choi, D-H., Lee, W-D., Park, D-R., Lee, H-I. (2007) The Effect of Sn Addition on a Pt∕C Electrocatalyst Synthesized by Borohydride Reduction and Hydrothermal Treatment for a Low-Temperature Fuel Cell. Electrochem, Solid-State Lett., 10: B87‒B90.
- Arenz, M., Stamenkovic, V., Blizanac, B., Mayrhofer, K, Markovic, N., Ross, P. (2005) Carbon-supported Pt–Sn electrocatalysts for the anodic oxidation of H2, CO, and H2/CO mixtures.Part II: The structure–activity relationship. J. Catal., 232: 402-410.
- Lim, D-H., Choi, D-H., Lee, W-D., Lee, H-I. (2009) A new synthesis of a highly dispersed and CO tolerant PtSn/C electrocatalyst for low-temperature fuel cell; its electrocatalytic activity and long-term durability. Appl. Catal. B Environ., 89: 484-493.
- Colmenares, L., Wang, H., Jusys, Z., Jiang, L., Yan, S., Sun, G.Q., et al. (2006). Ethanol oxidation on novel, carbon supported Pt alloy catalysts - Model studies under defined diffusion conditions. Electrochim. Acta, 52: 221-233.
- Hayden, B.E., Rendall, M.E., South, O. (2005). The stability and electro-oxidation of carbon monoxide on model electrocatalysts: Pt(111)–Sn(2×2) and Pt(111)–Sn(√3×√3)R30°. J. Mol. Catal. A Chem., 228: 55-65.
- Gasteiger, H.A., Marković, N.M., Ross, P.N. (1996). Structural effects in electrocatalysis: electrooxidation of carbon monoxide on Pt3Sn single-crystal alloy surfaces. Catal. Letters, 36: 1-8.
- Tripković, A.V., Popović, K.D., Lović, J.D., Jovanović, V.M., Stevanović, S.I., Tripković, D.V., et al. (2009). Promotional effect of Snad on the ethanol oxidation at Pt3Sn/C catalyst. Electrochem. Commun., 11: 1030-1033.
- Martínez-Huerta, M.V., Rojas, S, Gómez, D. L., Fuente, J.L, Terreros, P, Peña, M.A., Fierro, J.L.G. (2006). Effect of Ni addition over PtRu/C based electrocatalysts for fuel cell applications. Appl. Catal. B Environ., 69: 75-84.
- Wang, Z-B,, Yin, G-P., Zhang, J., Sun, Y-C., Shi, P-F. (2006). Investigation of ethanol electrooxidation on a Pt-Ru-Ni/C catalyst for a direct ethanol fuel cell. J. Power Sources, 160: 37-43.
- Simões, F.C., dos Anjos, D.M., Vigier, F., Léger, J-M., Hahn, F., Coutanceau, C., et al. (2007). Electroactivity of tin modified platinum electrodes for ethanol electrooxidation. J. Power Sources, 167: 1-10.
- Rousseau, S., Coutanceau, C., Lamy, C., Léger, J-M. (2006). Direct ethanol fuel cell (DEFC): Electrical performances and reaction products distribution under operating conditions with different platinum-based anodes. J. Power Sources, 158: 18-24.
- Zhu, M., Sun, G., Xin, Q. (2009). Effect of alloying degree in PtSn catalyst on the catalytic behavior for ethanol electro-oxidation. Electrochim. Acta, 54: 1511-1518.
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