Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts

License URL: http://creativecommons.org/licenses/by-sa/4.0

Even though platinum is known as an active electro-catalyst for ethanol oxidation at low temperatures (< 100 oC), choosing the electrode material for ethanol electro-oxidation is a crucial issue. It is due to its property which easily poisoned by a strong adsorbed species such as CO. PtSn-based electro-catalysts have been identified as better catalysts for ethanol electro-oxidation. The third material is supposed to improved binary catalysts performance. This work presents a study of the ethanol electro-oxidation on carbon supported Pt-Sn and Pt-Sn-Ni catalysts. These catalysts were prepared by alcohol reduction. Nano-particles with diameters between 2.5-5.0 nm were obtained. The peak of (220) crystalline face centred cubic (fcc) Pt phase for PtSn and PtSnNi alloys was repositioned due to the presence of Sn and/or Ni in the alloy. Furthermore, the modification of Pt with Sn and SnNi improved ethanol and CO electro-oxidation. Copyright © 2016 BCREC GROUP. All rights reserved
Received: 10th November 2015; Revised: 1st February 2016; Accepted: 1st February 2016
How to Cite: Hidayati, N., Scott, K. (2016). Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1): 10-20. (doi:10.9767/bcrec.11.1.399.10-20)
Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.1.399.10-20
Article Metrics: (click on the button below to see citations in Scopus)
Article Metrics:
- Lamy, C., Belgsir, E.M., Léger, J.M. (2001). Electrocatalytic oxidation of aliphatic alcohols: Application to the direct alcohol fuel cell (DAFC). J. Appl. Electrochem., 31: 799-809
- Zhou, W., Zhou, Z., Song S, Li. W., Sun, G., Tsiakaras, P., Xin, Q. (2003). Pt based anode catalysts for direct ethanol fuel cells. Appl. Catal. B. Environ., 46: 273-285
- Delime, F., Leger, J.M., Lamy, C. (1999). Enhancement of the electrooxidation of ethanol on a Pt-PEM electrode modified by tin. Part I: Half cell study. J Appl Electrochem, 29: 1249-1254
- Camara, G., de Lima, R., Iwasita, T. (2004). Catalysis of ethanol electrooxidation by PtRu: the influence of catalyst composition. Electrochem. Commun., 6: 812-815
- Liu, Z., Ling, X.Y., Su, X., Lee, J.Y., Gan, L.M. (2005). Preparation and characterization of Pt/C and PtRu/C electrocatalysts for direct ethanol fuel cells. J. Power Sources, 149: 1-7
- Mann, J., Yao, N., Bocarsly, A.B. (2006). Characterization and analysis of new catalysts for a direct ethanol fuel cell. Langmuir, 22: 10432-10436
- Sen Gupta, S., Datta, J.A. (2006). Comparative study on ethanol oxidation behavior at Pt and PtRh electrodeposits. J. Electroanal. Chem, 594: 65-72
- Zhou, W.J., Li, W.Z., Song, S.Q., Zhou, Z.H., Jiang, L.H., Sun, G.Q., et al. (2004). Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells. J .Power Sources, 131: 217-223
- Song, S.Q., Zhou, W.J., Zhou, Z.H., Jiang, LH., Sun, G.Q., Xin, Q., et al. (2005). Direct ethanol PEM fuel cells: The case of platinum based anodes. Int. J. Hydrogen Energy, 30: 995-1001
- Wang, H., Jusys, Z., Behm, R.J. (2006). Ethanol electro-oxidation on carbon-supported Pt, PtRu and Pt3Sn catalysts: A quantitative DEMS study. J. Power Sources, 154: 351-359
- Jiang, L., Colmenares, L., Jusys, Z., Sun, G.Q., Behm, R.J. (2007). Ethanol electrooxidation on novel carbon supported Pt/SnOx/C catalysts with varied Pt:Sn ratio. Electrochim. Acta, 53: 377-389
- Guo, Y., Zheng, Y., Huang, M., (2008). Enhanced activity of PtSn/C anodic electrocatalyst prepared by formic acid reduction for direct ethanol fuel cells. Electrochim. Acta, 53: 3102-3108
- Lamy, C., Rousseau, S., Belgsir, E.M., Coutanceau, C., Léger, J.M. (2004). Recent progress in the direct ethanol fuel cell: Development of new platinum-tin electrocatalysts. Electrochim. Acta, 49: 3901-3908
- Kim, J.H., Choi, S.M., Nam, S.H., Seo, M,H., Choi, S.H., Kim, W.B. (2008). Influence of Sn content on PtSn/C catalysts for electrooxidation of C1-C3 alcohols: Synthesis, characterization, and electrocatalytic activity. Appl. Catal. B Environ., 82: 89-102
- Colmati, F., Antolini, E., Gonzalez, E.R. (2007). Ethanol Oxidation on Carbon Supported Pt-Sn Electrocatalysts Prepared by Reduction with Formic Acid. J. Electrochem. Soc., 154: B39
- Zhou, W.J., Song, S.Q., Li, W.Z., Zhou, Z.H., Sun, G.Q., Xin, Q., et al. (2005). Direct ethanol fuel cells based on PtSn anodes: the effect of Sn content on the fuel cell performance. J. Power Sources. 140: 50-58
- Vigier, F., Coutanceau, C., Hahn, F., Belgsir, E.M., Lamy, C. (2004). On the mechanism of ethanol electro-oxidation on Pt and PtSn catalysts: Electrochemical and in situ IR reflectance spectroscopy studies. J. Electroanal. Chem. 63: 81-89.
- Jiang, L., Sun, G., Zhou, Z., Zhou, W., Xin, Q. (2004). Preparation and characterization of PtSn/C anode electrocatalysts for direct ethanol fuel cell. Catal. Today, 93-95: 665-670
- Jiang, L., Sun, G., Sun, S., Liu, J., Tang, S., Li, H, et al. (2005). Structure and chemical composition of supported Pt–Sn electrocatalysts for ethanol oxidation. Electrochim. Acta , 50: 5384-5389
- Spinacé, E. V., Linardi, M., Neto, A.O.(2005). Co-catalytic effect of nickel in the electro-oxidation of ethanol on binary Pt–Sn electrocatalysts. Electrochem. Commun., 7: 365-369
- Eberhart, J. (1991). Structural and Chemical Analysis of Materials: X-ray, Electron and Neutron Diffraction, X-ray, Electron and Ion Spectrometry, Electron Microscopy. John Wiley and Sons Ltd
- Mukerjee, S., Srinivasan, S., Soriaga, M.P., McBreen, J. (1995). Role of structural and electronic properties of Pt and Pt alloys on electrocatalysis of oxygen reduction. An in situ XANES and EXAFS investigation. J Electrochem. Soc., 142: 1409-1422
- Colmati, F., Antolini, E., Gonzalez, E.R. (2007). Ethanol oxidation on a carbon-supported Pt75Sn25 electrocatalyst prepared by reduction with formic acid: Effect of thermal treatment. Appl. Catal. B Environ., 73: 106-115
- Spinacé, E., Neto, A., Linardi, M. (2004). Electro-oxidation of methanol and ethanol using PtRu/C electrocatalysts prepared by spontaneous deposition of platinum on carbon-supported ruthenium nanoparticles. J. Power Sources, 129: 121-126
- Lim, D-H., Choi, D-H., Lee, W-D., Park, D-R., Lee, H-I. (2007) The Effect of Sn Addition on a Pt∕C Electrocatalyst Synthesized by Borohydride Reduction and Hydrothermal Treatment for a Low-Temperature Fuel Cell. Electrochem, Solid-State Lett., 10: B87‒B90
- Arenz, M., Stamenkovic, V., Blizanac, B., Mayrhofer, K, Markovic, N., Ross, P. (2005) Carbon-supported Pt–Sn electrocatalysts for the anodic oxidation of H2, CO, and H2/CO mixtures.Part II: The structure–activity relationship. J. Catal., 232: 402-410
- Lim, D-H., Choi, D-H., Lee, W-D., Lee, H-I. (2009) A new synthesis of a highly dispersed and CO tolerant PtSn/C electrocatalyst for low-temperature fuel cell; its electrocatalytic activity and long-term durability. Appl. Catal. B Environ., 89: 484-493
- Colmenares, L., Wang, H., Jusys, Z., Jiang, L., Yan, S., Sun, G.Q., et al. (2006). Ethanol oxidation on novel, carbon supported Pt alloy catalysts - Model studies under defined diffusion conditions. Electrochim. Acta, 52: 221-233
- Hayden, B.E., Rendall, M.E., South, O. (2005). The stability and electro-oxidation of carbon monoxide on model electrocatalysts: Pt(111)–Sn(2×2) and Pt(111)–Sn(√3×√3)R30°. J. Mol. Catal. A Chem., 228: 55-65
- Gasteiger, H.A., Marković, N.M., Ross, P.N. (1996). Structural effects in electrocatalysis: electrooxidation of carbon monoxide on Pt3Sn single-crystal alloy surfaces. Catal. Letters, 36: 1-8
- Tripković, A.V., Popović, K.D., Lović, J.D., Jovanović, V.M., Stevanović, S.I., Tripković, D.V., et al. (2009). Promotional effect of Snad on the ethanol oxidation at Pt3Sn/C catalyst. Electrochem. Commun., 11: 1030-1033
- Martínez-Huerta, M.V., Rojas, S, Gómez, D. L., Fuente, J.L, Terreros, P, Peña, M.A., Fierro, J.L.G. (2006). Effect of Ni addition over PtRu/C based electrocatalysts for fuel cell applications. Appl. Catal. B Environ., 69: 75-84
- Wang, Z-B,, Yin, G-P., Zhang, J., Sun, Y-C., Shi, P-F. (2006). Investigation of ethanol electrooxidation on a Pt-Ru-Ni/C catalyst for a direct ethanol fuel cell. J. Power Sources, 160: 37-43
- Simões, F.C., dos Anjos, D.M., Vigier, F., Léger, J-M., Hahn, F., Coutanceau, C., et al. (2007). Electroactivity of tin modified platinum electrodes for ethanol electrooxidation. J. Power Sources, 167: 1-10
- Rousseau, S., Coutanceau, C., Lamy, C., Léger, J-M. (2006). Direct ethanol fuel cell (DEFC): Electrical performances and reaction products distribution under operating conditions with different platinum-based anodes. J. Power Sources, 158: 18-24
- Zhu, M., Sun, G., Xin, Q. (2009). Effect of alloying degree in PtSn catalyst on the catalytic behavior for ethanol electro-oxidation. Electrochim. Acta, 54: 1511-1518
Last update: 2021-04-19 04:16:15
Last update: 2021-04-19 04:16:16
-
Preface, BCREC Vol. 11 No. 1 year 2016
Istadi I.. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1), 2016. doi: 10.9767/bcrec.11.1.441.v-vii -
Methanol Oxidation in Alkaline Media with Pt-Au/fMWCNTs and Pt-Pd/fMWCNTs Electrocatalysts on an Exfoliated Graphite Electrode
Mpeta L.. Electrocatalysis, 10 (6), 2019. doi: 10.1007/s12678-019-00555-0 -
Critical challenges in the system development of direct alcohol fuel cells as portable power supplies: An overview
Fadzillah D.M.. International Journal of Hydrogen Energy, 44 (5), 2019. doi: 10.1016/j.ijhydene.2018.11.089 -
An In Situ Quick X-ray Absorption Spectroscopy Study on Pt
Su B.J.. ChemCatChem, 2020. doi: 10.1002/cctc.2020014003 Sn/Graphene Catalyst for Ethanol Oxidation Reaction -
PtSn electrocatalysts for ethanol oxidation reaction: The effect of metal ratio and thermal treatment
Colmati F.. Advanced Materials and Systems for Electrochemical Technologies, 2018.
License URL: http://creativecommons.org/licenses/by-sa/4.0
Journal Author(s) Rights
In order for BCREC Group to publish and disseminate research articles, we need publishing rights (transfered from author(s) to publisher). This is determined by a publishing agreement between the Author(s) and BCREC Group. This agreement deals with the transfer or license of the copyright of publishing to BCREC Group, while Authors still retain significant rights to use and share their own published articles. BCREC Group supports the need for authors to share, disseminate and maximize the impact of their research and these rights, in any databases.
As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including:
- use for classroom teaching by Author or Author's institution and presentation at a meeting or conference and distributing copies to attendees;
- use for internal training by author's company;
- distribution to colleagues for their reseearch use;
- use in a subsequent compilation of the author's works;
- inclusion in a thesis or dissertation;
- reuse of portions or extracts from the article in other works (with full acknowledgement of final article);
- preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article);
- voluntary posting on open web sites operated by author or author’s institution for scholarly purposes,
Authors/Readers/Third Parties can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (the name of the creator and attribution parties (authors detail information), a copyright notice, an open access license notice, a disclaimer notice, and a link to the material), provide a link to the license, and indicate if changes were made (Publisher indicates the modification of the material (if any) and retain an indication of previous modifications using a CrossMark Policy and information about Erratum-Corrigendum notification).
Authors/Readers/Third Parties can read, print and download, redistribute or republish the article (e.g. display in a repository), translate the article, download for text and data mining purposes, reuse portions or extracts from the article in other works, sell or re-use for commercial purposes, remix, transform, or build upon the material, they must distribute their contributions under the same license as the original Creative Commons Attribution-ShareAlike (CC BY-SA).
Copyright Transfer Agreement for Publishing (Publishing Right)
The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright for publishing (publishing right) of the article shall be assigned/transferred to Publisher of Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) (or BCREC Group).
Upon acceptance of an article, authors will be asked to complete a 'Copyright Transfer Agreement for Publishing (CTAP)'. An e-mail will be sent to the Corresponding Author confirming receipt of the manuscript together with a 'Copyright Transfer Agreement for Publishing' form by online version of this agreement.
Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia-Indonesian Catalyst Society (MKICS), the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.
Remember, even though we ask for a transfer of copyright for publishing (CTAP), our journal Author(s) retain (or are granted back) significant scholarly rights as mentioned before.
The Copyright Transfer Agreement for Publishing (CTAP) Form can be downloaded here: [Copyright Transfer Agreement for Publishing (CTAP) Form BCREC 2020]
The copyright form should be signed electronically and send to the Editorial Office in the form of original e-mail below:
Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering & Catalysis
Laboratory of Plasma-Catalysis (R3.5), UPT Laboratorium Terpadu, Universitas Diponegoro
Jl. Prof. Soedarto, Semarang, Central Java, Indonesia 50275
Telp/Whatsapp: +62-81-316426342
E-mail: bcrec[at]live.undip.ac.id
(This policy statements has been updated at 24th December 2020)