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Characterization and Application of Molten Slag as Catalyst in Pyrolysis of Waste Cooking Oil

1Chemical and Petrochemical Research Center, Corporation of Research and Industrial Development, Ministry of Industry and Minerals, Baghdad , Iraq

2Department of Chemical and Environmental Engineering, Faculty of Engineering, , Malaysia

3Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia

4 Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, Malaysia

5 State of Commission for Dams and Reservoirs, Ministry of Water Resources, Baghdad, Iraq

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Received: 21 Dec 2018; Revised: 24 Oct 2019; Accepted: 26 Oct 2019; Available online: 28 Feb 2020; Published: 1 Apr 2020.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2020 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

Chemical and physical analysis was performed to identify the molten slag composition and its ability to be used as alternative catalyst in pyrolysis of waste cooking oil. The implementation such type of catalytic material could be useful in reducing the process cost. To increase the efficiency (increase the active site) of molten slag, it was modified by acid washing that resulted in an increase in the acidity from 159 to 1224 µmol/g. The results showed that the yield of bio-fuel was increased and the product selective to n-C15 upon the modification of molten slag by acid treatment. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

 

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Keywords: Molten slag; Thermal activation; chemical activation; Pyrolysis; bio-fuel
Funding: Ministry of Higher Education Malaysia for Fundamental Research Grant Scheme under contract FRGS/11/TK/UPM/02

Article Metrics:

  1. Bennett, J., Wilson, K., Lee, A.F. (2016). Catalytic applications of waste derived materials. J. Mater. Chem. A, 4, 3617–3637
  2. Navarro, C., Mario, D., Villa-garc, I.A.A. (2010). Physico-Chemical Characterization of Steel Slag . Study of its Behavior under Simulated Environmental Conditions. Environ. Science Technology, 44, 5383–5388
  3. Kuwahara Y., Yamashita, H. (2013). A new catalytic opportunity for waste materials: Application of waste slag based catalyst in CO2 fixation reaction. J. CO2 Util., 1, 50–59
  4. Piatak, N.M., Parsons, M.B., Seal, R.R. (2014). Characteristics and Environmental Aspects of Slag: A Review. Appl. Geochemistry, 57, 236–266
  5. Shen, H., Forssberg, E. (2003). An overview of recovery of metals from slags. Waste Manag., 23, 933–949
  6. Kuwahara, Y., Tsuji, K., Ohmichi, T., Kamegawa, T., Mori, K., Yamashita, H. (2012). Transesterifications using a hydrocalumite synthesized from waste slag: an economical and ecological route for biofuel production. Catal. Sci. Technol., 2, 1842-1851
  7. Bermudez, J.M., Fidalgo, B., Arenillas, A., Menendez, J.A. (2012). Mixtures of steel-making slag and carbons as catalyst for microwave-assisted dry reforming of CH4. Cuihua Xuebao/Chinese J. Catal., 33, 1115–1118
  8. Wang, L., Li, H., Xin, S., Li, F. (2014). Generation of solid base catalyst from waste slag for the efficient synthesis of diethyl carbonate from ethyl carbamate and ethanol. Catal. Commun., 50, 49–53
  9. Kar, Y., Gurbuz, Z. (2016). Application of blast furnace slag as a catalyst for catalytic cracking of used frying sunflower oil. Energy Explor. Exploit., 34, 262–272
  10. Demirbas, A. (2008). Biofuels sources, biofuel policy, biofuel economy and global biofuel projections Energy Convers. Manag., 49, 2106–2116
  11. Kamil, F.H., Salmiaton, A., Hafriz, R.M., Omer, R. (2017). Characterization and Application of Aluminum Dross as Catalyst in Pyrolysis of Waste Cooking Oil. Bulletin of Chemical Reaction Engineering & Catalysis, 12, 81–88
  12. Klose, F., Scholz, P., Kreisel, G., Ondruschka, B., Kneise, R., Knopf, U. (2000). Catalysts from waste materials. Appl. Catal. B Environ., 28, 209–221
  13. Tan, S., Zhang, Z., Sun, J., Wang, Q. (2013). Recent progress of catalytic pyrolysis of biomass by HZSM-5. Chinese J. Catal., 34, 641–650
  14. Lu, Q., Zhang, Z.F., Dong, C.Q., Zhu, X.F. (2010). Catalytic upgrading of biomass fast pyrolysis vapors with nano metal oxides: An analytical Py-GC/MS study. Energies, 3, 1805–1820
  15. Romero, M.J.A., Pizzi, A., Toscano, G., Bosio, B., Arato, E. (2014). Study of an innovative process for the production of biofuels using non-edible vegetable oils. Chem. Eng. Trans., 37, 883–888
  16. Hocheng, H., Su, C., Jadhav, U.U. (2014). Bioleaching of metals from steel slag by Acidithiobacillus thiooxidans culture supernatant. Chemosphere, 117, 652–657
  17. Yildirim, I.Z., Prezzi, M. (2011). Chemical, mineralogical, and morphological properties of steel slag. Adv. Civil Eng., 2011, 1–13
  18. Rouquerol, F., Rouquerol, J., Sing, K.S., Llewellyn, P., Maurin, G. (2014). Adsorption by Powders and Porous Solid Principles, Methodology and Application., 2nd edition. Elsevier
  19. Maher, K.D., Bressler, D.C. (2007). Pyrolysis of triglyceride materials for the production of renewable fuels and chemicals. Bioresour. Technol., 98, 2351–2368
  20. Asikin-Mijan, N., Taufiq-Yap, Y.H., Lee, H. V. (2015). Synthesis of clamshell derived Ca(OH)2 nano-particles via simple surfactant-hydration treatment. Chem. Eng. J., 262, 1043–1051
  21. Putun, A.E., Ozean, A., Putun, E. (1999). Pyrolysis of hazelnut shells in a fixed-bed tubular reactor: Yields and structural analysis of bio-oil. J. Anal. Appl. Pyrolysis, 52, 33–49
  22. Tanneru, S.K., Steele, P.H. (2015). Production of liquid hydrocarbons from pretreated bio-oil via catalytic deoxygenation with syngas. Renew. Energy, 80, 251–258
  23. Hafriz, R.M., Salmiaton, A., Yunus, R., Taufiq-Yap, Y.H. (2018). Modified local carbonate mineral as deoxygenated catalyst for biofuel production via catalytic pyrolysis of waste cooking oil. In AIP Conference Proceedings. 020006. AIP publishing
  24. Junming, X., Jianchun, J., Yunjuan, S., Jie, C. (2010). Production of hydrocarbon fuels from pyrolysis of soybean oils using a basic catalyst. Bioresour. Technol., 101, 9803–9806
  25. Hafriz, R.M., Salmiaton, A., Yunus, R., Taufiq-Yap, Y.H. (2018). Green Biofuel Production via Catalytic Pyrolysis of Waste Cooking Oil using Malaysian Dolomite Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 13, 489-501
  26. Taufiqurrahmi, N., Mohamed, A.R, Bhatia, S. (2011). Production of biofuel from waste cooking palm oil using nanocrystalline zeolite as catalyst : Process optimization studies. Bioresour. Technol., 102, 10686–10694
  27. Hermida, L., Zuhairi, A., Rahman, A. (2015). Deoxygenation of fatty acid to produce diesel-like hydrocarbons : A review of process conditions , reaction kinetics and mechanism. Renew. Sustain. Energy Rev., 42, 1223–1233

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