A System of Photocatalysis for NAD+ Regeneration of Product of (S)-1-Pheylethanol by Enzymic Catalysis

Shujin Pu; Xuan Zhang; Han Huang; Chengli Yang; Dali Li; Junfang Yang; Jie Ouyang; Xing Chen; Sidra Naseer; Ruofu Shi

doi:10.9767/bcrec.14.2.3930.421-426

DOI: https://doi.org/10.9767/bcrec.14.2.3930.421-426

A System of Photocatalysis for NAD+ Regeneration of Product of (S)-1-Pheylethanol by Enzymic Catalysis

Shujin Pu, Xuan Zhang, Han Huang, Chengli Yang, Dali Li , Junfang Yang, Jie Ouyang, Xing Chen, Sidra Naseer, Ruofu Shi

Department of Bioengineering, Nanjing University of Science & Technology, Nanjing, 210094, China

Received: 18 Dec 2018; Revised: 27 Feb 2019; Accepted: 5 Mar 2019; Available online: 30 Apr 2019; Published: 1 Aug 2019.

Editor(s): Istadi Istadi

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Abstract

In this study, a system of photocatalysis for NAD⁺ regeneration of enzymatic catalysis was constructed. The optimal conditions for the coupling reaction of photocatalysis and biocatalysis were explored. Blue light was chosen for the efficient reaction and the optimal concentration of VB₂ (vitamin B₂, riboflavin) was determined. NAD⁺-dependent (R)-1-phenylethanol dehydrogenase was used in the reaction for transforming (R)-1-phenylethanol to acetophenone. The byproducts of the reaction were just H₂O and O₂ by means of catalase. The coupling reaction of catalysis and photocatalysis can be used for obtaining (S)-1-phenylethanol through racemization of 1-phenylethanol.

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Keywords: NAD+; Photocatalysis; Biocatalysis; Riboflavin; (R)-1-phenylethanol dehydrogenase

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Section: Original Research Articles

Language : EN

In 2019: BCREC Volume 14 Issue 2 Year 2019 (August 2019)

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