Selective Hydrogenation of Biomass-derived Furfural over Supported Ni3Sn2 Alloy: Role of Supports

*Rodiansono Rodiansono  -  Department of Chemistry, Lambung Mangkurat University, Banjarbaru, South Kalimantan, 70713, Indonesia
Maria Dewi Astuti  -  Department of Chemistry, Lambung Mangkurat University, Banjarbaru, South Kalimantan, 70713, Indonesia
Syahrul Khairi  -  Department of Chemical Engineering, Tanjung Pura University, Pontianak, West Kalimantan,, Indonesia
Shogo Shimazu  -  Graduate School of Engineering, Chiba University, 1-33 Yayoi, Inage, Chiba 263-8522,, Japan
Received: 10 Nov 2015; Revised: 31 Dec 2015; Accepted: 5 Jan 2016; Published: 1 Apr 2016; Available online: 10 Mar 2016.
Open Access Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis
Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Citation Format:
Cover Image
Article Info
Section: The 2nd International Conference on Chemical and Material Engineering 2015
Full Text:
In 2016: BCREC Volume 11 Issue 1 Year 2016 (SCOPUS and Web of Science Indexed, April 2016)
Statistics: 1456 485

Abstract

A highly active and selective hydrogenation of biomass-derived furfural into furfuryl alcohol was achieved using supported single phase Ni3Sn2 alloy catalysts. Various supports such as active carbon (AC), g-Al2O3, Al(OH)3, ZnO, TiO2, ZrO2, MgO, Li-TN, and SiO2 have been employed in order to understand the role of the support on the formation of Ni3Sn2 alloy phase and its catalytic performance. Supported Ni3Sn2 alloy catalysts were synthesised via a simple hydrothermal treatment of the mixture of aqueous solution of nickel chloride hexahydrate and ethanol solution of tin(II) chloride dihydrate in presence of ethylene glycol at 423 K for 24 h followed by H2 treatment at 673 K for 1.5 h, then characterised by using ICP-AES, XRD, H2- and N2-adsorption. XRD profiles of samples showed that the Ni3Sn2 alloy phases are readily formed during hydrothermal processes and become clearly observed at 2θ = 43-44o after H2 treatment. The presence of Ni3Sn2 alloy species that dispersed on the supports is believed to play a key role in highly active and selective hydrogenation of biomass-derived furfural towards furfuryl alcohol. Ni3Sn2 on TiO2 and ZnO supports exhibited much lower reaction temperature to achieved >99% yield of furfuryl alcohol product compared with other supports. The effects of loading amount of Ni-Sn, reaction conditions (temperature and time profile) on the activity and selectivity towards the desired product are systematically discussed. Copyright © 2016 BCREC GROUP. All rights reserved

Received: 10th November 2015; Revised: 31st December 2015; Accepted: 5th January 2016

How to Cite: Rodiansono, R., Astuti, M.D., Khairi, S., Shimazu, S. (2016). Selective Hydrogenation of Biomass-derived Furfural over Supported Ni3Sn2 Alloy: Role of Supports. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1): 1-9. (doi:10.9767/bcrec.11.1.393.1-9)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.1.393.1-9

Article Metrics: (click on the button below to see citations in Scopus)

cited by count 

Keywords
selective hydrogenation; furfural; furfuryl alcohol; supported Ni3Sn2 alloy catalysts

Article Metrics:

  1. Falbe, J., Bahrmann, H., Lipps, W., Meyer, D. in Ullmanns encyclopedia of industrial chemistry, Wiley-VCH Verlag GmbH & Co. 2005. Vol. 11, pp. 21.
  2. Frainier, L.J., Fineberg, H. (1981). Preparation of furfuryl alcohol from furfural. US Patent 4,302,397.
  3. Rao, R., Dandekar, A., Baker, R.T.K., Vannice, M.A. (1997). Properties of copper chromite catalysts in hydrogenation reactions. J. Catal. 171: 406-419.
  4. Luo, H., Li, H., Zhuang, L. (2001). Furfural hydrogenation to furfuryl alcohol over a novel Ni-Co-B amorphous alloy catalyst. Chem. Let. 30(5): 404-405.
  5. Li, H., Zhang, S., Luo, H. (2004). A Ce-promoted Ni-B amorphous alloy catalyst (Ni-Ce-B) for liquid-phase furfural hydrogenation to furfural alcohol. Materials Letters. 58: 2741-2746.
  6. Li, H., Luo, H., Zhuang, L., Dai, W., Qiao, M. (2003). Liquid phase hydrogenation of furfural to furfuryl alcohol over the Fe-promoted Ni-B amorphous alloy catalysts. J. Mol. Catal. A: Chemical. 203: 267-275.
  7. Baijun, L., Lianhai, L., Bingchun, W., Tianxi, C., Iwatani, K. (1998). Liquid phase selective hydrogenation of furfural on Raney nickel modified by impregnation of salts of heteropolyacids. App. Catal. A: General. 171: 117-122.
  8. Vetere, V., Merlo, A. B., Ruggera, J. F., Casella, M. L. (2010). Transition metal-based bimetallic catalysts for the chemoselective hydrogenation of furfuraldehyde. J. Braz. Chem. Soc. 21: 914-920.
  9. Merlo, A.B., Vetere, V., Ruggera, J. F., Casella, M. L. (2009). Bimetallic PtSn catalyst for the selective hydrogenation of furfural to furfuryl alcohol in liquid-phase. Catal. Commun. 10: 1665-1669.
  10. Rodiansono, R., Hara, T., Ichikuni, N., Shimazu, S. (2012). Highly efficient and selective hydrogenation of unsaturated carbonyl compounds using Ni–Sn alloy catalysts. Catal. Sci. Technol. 2: 2139-2145.
  11. Rodiansono, R., Hara, T., Ichikuni, N., Shimazu, S. (2014). Development of nanoporous Ni-Sn alloy and application for chemoselective hydrogenation of furfural to furfuryl alcohol. Bull. Chem. React. Eng. & Catal. 9(1): 53-59. DOI: 10.9767/bcrec.9.1.5529.53-59
  12. Rodiansono, R., Hara, T., Ichikuni, N., Shimazu, S. (2012). A novel preparation method of Ni-Sn alloy catalysts supported on aluminium hydroxide: Application to chemoselective hydrogenation of unsaturated carbonyl compounds. Chem. Lett. 41(8): 769-771.
  13. Lowell, S., Shields, J. E., Thomas, M. A., Thommes, M. (2004). Characterization of porous solids and powders: surface area, pore size and density, Kluwer Academic Publishers, Netherlands, Chapter 8.
  14. Bartholomew, C.H., Pannel, R.B., Butler J.L. (1980). Support and crystallite size effects in CO hydrogenation on nickel. J. Catal. 65: 335-347 .
  15. Dandekar, A., Vannice, M. A. (1999). Crotonaldehyde hydrogenation on Pt/TiO2 and Ni/TiO2 SMSI catalysts. J. Catal. 183: 344-354.
  16. Kijenski, J., Winiarek, P., Paryjczak, T., Lewicki, A., Mikolajska, A. (2002). Platinum deposited on monolayer supports in selective hydrogenation of furfural to furfuryl alcohol. Appl. Catal. A. 233: 171-182.
  17. Corma, A., Serna, P., Concepcion, P., Calvino, J. J. (2008). Transforming nonselective into chemoselective metal catalysts for the hydrogenation of substituted nitroaromatics. J. Am. Chem. Soc.130: 8748-8753.
  18. Swift, H. E., Bozik, J. E.. (1968). Metallic phases and activities of nickel-tin-silica catalysts: dehydrogenation of cyclohexanone, cyclohexanol, and cyclohexane. J. Catal. 12: 5-14.
  19. Delbecq, F., Sautet, P. (1995). Competitive C=C and C=O adsorption of a-b-unsaturated aldehydes on Pt and Pd sur-faces in relation with the selectivity of hydrogenation reactions: A theoretical approach. J. Catal. 152: 217-236.
  20. Sitthisa, S., Pham, T., Prasomsri, T., Sooknoi, T., Mallinson, R. G., Resasco, D. E.. (2011). Conversion of furfural and 2-methylpentanal on Pd/SiO2 and Pd-Cu/SiO2 catalysts. J. Catal. 280: 17-27.
  21. Sordelli, L., Psaro, R., Vlaic, G., Cepparo, A., Recchia, S., Fusi, A., Zanoni, R.. (1999). EXAFS studies of supported Rh–Sn catalysts for citral hydrogenation. J. Catal. 182: 186-198.
  22. Margitfalvi, J. L., Tompos, A., Kolosova, I., Valyon, J. (1998). Reaction induced selectivity improvement in the hydrogenation of crotonaldehyde over Sn-Pt/SiO2 catalysts. J. Catal. 174: 246-249

Copyright (c) 2016 Bulletin of Chemical Reaction Engineering & Catalysis Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Author(s) Rights

As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including: use for classroom teaching by Author or Author's institutionand presentation at a meeting or conference and distributing copies to attendees; use for internal training by author's company; distribution to colleagues for their reseearch use; use in a subsequent compilation of the author's works; inclusion in a thesis or dissertation; reuse of portions or extracts from the article in other works (with full acknowledgement of final article); preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article); voluntary posting on open web sites operated by author or author’s institution for scholarly purposes (should follow CC by SA License).

Authors can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (cite to the article or content), provide a link to the license, and indicate if changes were made. If you remix, transform, or build upon the material, you must redistribute your contributions under the same license as the original.

Copyright Transfer Agreement (for Publishing)

The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright publishing of the article shall be assigned/transferred to Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) as Publisher of the journal. Upon acceptance of an article, authors will be asked to complete a 'Copyright Transfer Agreement' (see more information on this). An e-mail will be sent to the corresponding author confirming receipt of the manuscript together with a 'Copyright Transfer Agreement' form by online version of this agreement.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia-Indonesian Catalyst Society (MKICS), the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of copyright, our journal authors retain (or are granted back) significant scholarly rights as mention before.

The Copyright Transfer Agreement (CTA) Form can be downloaded here: [Copyright Transfer Agreement (CTA) Form BCREC 2020] 


The copyright form should be signed electronically and send to the Editorial Office in the form of original e-mail below:  

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering & Catalysis
Department of Chemical Engineering, Diponegoro University
Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Telp.: +62-24-7460058, Fax.: +62-24-76480675
E-mail: bcrec[at]live.undip.ac.id