Synthesis of Titania Doped Copper Ferrite Photocatalyst and Its Photoactivity towards Methylene Blue Degradation under Visible Light Irradiation
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This paper reports the photocatalytic decomposition of methylene blue (MB) over titania doped copper ferrite, CuFe2O4/TiO2 with 50 wt% loading, synthesized via sol-gel method. The synthesized photocatalyst was characterized by X-ray diffraction, UV-vis diffuse reflectance, and photoluminescence, Mott-Schottky (MS) analysis and linear sweep voltammetry (LSV). The catalyst loadings were varied from 0.25 – 1.0 g/L and the optimum catalyst loading found to be 0.5 g/L. At the optimum loading, the conversion achieved was 83.7%. The other loadings produced slightly lower conversions at 82.7%, 80.6% and 80.0%, corresponding to 0.25, 1 and 0.75 g/L after 3 hours of irradiation. The study on the effect of initial concentration indicated that 20 ppm as the optimum concentration, tested with 0.5 g/L catalyst loading. The spent catalyst was used for the recyclability test and demonstrated a high longevity with a degradation efficiency less than 6 % for each time interval. The novelty of this study lies on the new application of photocatalytic material, CuFe2O4/TiO2 on thiazine dye that shows remarkable activity and reusability performance under visible light irradiation. Copyright © 2019 BCREC Group. All rights reserved
Received: 15th November 2018; Revised: 14th January 2019; Accepted: 17th January 2019; Available online: 25th January 2019; Published regularly: April 2019
How to Cite: Arifin, M.N., Karim, K.M.R., Abdullah, H., Khan, M.R. (2019). Synthesis of Titania Doped Copper Ferrite Photocatalyst and Its Photoactivity towards Methylene Blue Degradation under Visible Light Irradiation. Bulletin of Chemical Reaction Engineering & Catalysis, 14 (1): 219-227 (doi:10.9767/bcrec.14.1.3616.219-227)
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