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Egg-shell Treated Oil Palm Fronds (EG-OPF) as Low-Cost Adsorbent for Methylene Blue Removal

1Faculty of Chemical and Natural Resources Engineering, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, Pahang, Malaysia

2Centre of Excellence for Advanced Research in Fluid Flow, Universiti Malaysia Pahang, 26300 Gambang, Kuantan, Pahang, Malaysia

Received: 1 Oct 2018; Revised: 28 Oct 2018; Accepted: 14 Nov 2018; Published: 15 Apr 2019; Available online: 25 Jan 2019.
Open Access Copyright (c) 2019 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

A new adsorbent (egg-shell treated oil palm fronds (EG-OPF)) prepared from wastes was evaluated for methylene blue (MB) removal. Optimization among three significant variables (initial concentration (X1), initial pH (X2), and adsorbent dosage (X3)) were executed using response surface methodology (RSM). The most excellent performance was marked at X1 = 291.7 mg/L, X2 = pH 5, and X3 = 1.82 g/L, with MB removal of 80.26 %. The kinetic study was fitted perfectly with the pseudo-second-order model (R2 > 0.990), indicating the chemisorption process. The isotherm study was found to follow the Langmuir isotherm model (R2 = 0.999), with maximal adsorption magnitude of 714.3 mg/g, implying the monolayer adsorption on a homogenous adsorbent surface. The reusability study affirmed the feasibility of EG-OPF in MB removal, credited to its excellent performance during reusability studies. The present study successfully discovered a new low-cost adsorbent (EG-OPF) for MB removal. 

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Keywords: Adsorption; Low-Cost Adsorbent; Optimization; Methylene Blue
Funding: Universiti Malaysia Pahang (UMP) through Research University Grant (RDU170331)

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Section: The 4th International Conference of Chemical Engineering & Industrial Biotechnology (ICCEIB 2018)
Language : EN
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