Cyclohexanone Oxidation over H3PMo12O40 Heteropolyacid via Two Activation Modes Microwave Irradiation and Conventional Method

Yasmina Idrissou -  Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB) , BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria
Sihem Mouanni -  Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB) , BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria
Dahbia Amitouche -  Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB) , BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria Département de Chimie, Faculté des Sciences, Université Mouloud Mammeri (UMMTO) , 15000 Tizi Ouzou, Algeria
*Tassadit Mazari -  Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB) , BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria Département de Chimie, Faculté des Sciences, Université Mouloud Mammeri (UMMTO) , 15000 Tizi Ouzou, Algeria
Catherine Marchal-Roch -  ILV-UMR 8180 CNRS, Université de Versailles-St Quent -en-Yvelines , Bâtiment Lavoisier, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France
Cherifa Rabia -  Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB) , BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria
Received: 7 Aug 2018; Revised: 10 Mar 2019; Accepted: 10 Mar 2019; Published: 1 Aug 2019; Available online: 30 Apr 2019.
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Abstract

The adipic acid (AA), important precursor for Nylon production, was synthesized from cyclohexanoneoxidation by two ways, microwaves irradiation and  conventional method (under reflux) using H3PMo12O40 heteropolyacid as catalyst in the presence of hydrogen peroxide. In the order to increase the AA yield, several parameters as cyclohexanone/catalyst ratio, H2O2 concentration, solvent nature (H2O, CH3CO2H, and CH3OH, CHCl3 and CH3CN) and cyclohexanol addition to cyclohexanone were examined.  For both activation modes, the highest AA yields are of 26-28%. Whereas, with microwaves irradiation, the time gain is much more attractive 30 min compared to 20 h. Copyright © 2019 BCREC Group. All rights reserved

 

Keywords
H3PMo12O40 heteropolyacid; Oxidation; Hydrogen peroxide; Cyclohexanone; Adipic acid; Microwave irradiation

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