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Valorization of the Phosphate Fertilizers Catalytic Activity in 1-(Benzothiazolylamino) Methyl-2-Naphthol Derivatives Synthesis

Laboratory of Organic, Organometallic and Theoretical Chemistry, Faculty of Sciences, Ibn Tofail University, B.P. 133, Kenitra, Morocco

Received: 19 Jul 2018; Revised: 27 Oct 2018; Accepted: 4 Nov 2018; Published: 1 Aug 2019; Available online: 30 Apr 2019.
Open Access Copyright (c) 2019 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

The present work focused on developing a new protocol of the 1-(benzothiazolylamino) methyl-2-naphthol derivatives synthesis by condensation of three compounds, i.e. aromatic 2-naphthol, 2-aminobenzothiazole and aldehyde. Furthermore, this reaction was carried out in the presence of three heterogeneous phosphate catalysts: monoammonium phosphates (MAP), diammonium phosphate (DAP), and trisuperphosphate (TSP). Moreover, this method offered many advantages, such as: very high yields, shorter reaction times, and the catalysts, can be easily recovered and reused without any loss of their catalytic activities.  

 

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Keywords: 1- (benzothiazolyamino) methyl-2-naphthol derivatives; Heterogeneous catalysts; Phosphate fertilizers; MAP; DAP; TSP
Funding: Center for Analysis, Expertise, Technology Transfer and Incubation (CUAE2TI) of Ibn Tofail University

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