Preparation, characterization and catalytic activity of tin (antimony) substituted and lacunar Dawson phosphotungstomolybdates for the adipic acid Synthesis

DOI: https://doi.org/10.9767/bcrec.0.0.2905.xxx-xxx
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Submitted: 06-07-2018
Published: 25-01-2019
Section: Original Research Articles
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Tin (antimony) substituted and lacunar Dawson phosphotungstomolybdates (α1-K10P2W12Mo5□O62,α1-K8P2W12Mo5SnO62 and α-Cs4SnP2W12Mo6O62 and α-Cs3SbP2W12Mo6O62)were synthesized and characterized by IR, 31 P NMR and UV-Vis  spectroscopies. Their catalytic properties were examined in the oxidation reaction of cyclohexanone at 90 °C and that of cyclohexene at 70 °C to adipic acid (AA), in presence of the hydrogen peroxide and in free solvent. The effects of catalyst/substrate molar ratios, hydrogene peroxide flow rate, heteropolysalt composition and cyclohexanol addition on AA yields were studied. Cs4SnP2W12Mo6O62, the most efficient, led to 61 % yield AA from the cyclohexanone oxidation using a catalyst/substrate molar ratio of 13.3 10- 4, H2O2 flow rate of 0.5 mL/h and a reaction time of 20 h.

Received: 6th July 2018; Revised: 21st November 2018; Accepted: 4th December 2018

Keywords

Dawson; polyoxometalate; adipic acid; cyclohexanone; cyclohexene

  1. Mohamed Riad Guerroudj 
    Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB) BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria Centre de Recherche Scientifique et Technique en Analyse Physico-chimique CRAPC, BP 384, Zone Industrielle Bou-Ismail, RP 42004 Tipaza, Algeria
  2. Leila Dermeche 
    Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB), BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria, Algeria
    Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB)
  3. Lynda Mouheb 
    1 Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB) BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria 3 Laboratoire de Recherche de Chimie Appliquée et de Génie Chimique, Hasnaoua I, Université Mouloud Mammeri B.P.17 RP, 15000 Tizi-Ouzou., Algeria
  4. Tassadit Mazari 
    1 Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB) BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria 3 Laboratoire de Recherche de Chimie Appliquée et de Génie Chimique, Hasnaoua I, Université Mouloud Mammeri B.P.17 RP, 15000 Tizi-Ouzou., Algeria
  5. Siham Benadji 
    Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB) BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria
  6. Chérifa Rabia 
    Laboratoire de Chimie du Gaz Naturel, Faculté de Chimie, Université des Sciences et de la Technologie Houari Boumediene (USTHB) BP 32, El-Alia, 16111 Bab-Ezzouar, Alger, Algeria
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