Preparation, Characterization, and Catalytic Activity of Tin (Antimony) Substituted and Lacunar Dawson Phosphotungstomolybdates for Synthesis of Adipic Acid
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Tin (antimony) substituted and lacunar Dawson phosphotungstomolybdates (a1-K10P2W12Mo5□O61, a1-K8P2W12Mo5SnO61 and a-Cs4SnP2W12Mo6O62,and a-Cs3SbP2W12Mo6O62) were synthesized and characterized by Fourier Transform Infra Red (FTIR), nuclear magnetic resonance (31P NMR), Visible Ultra Violet (UV-Vis) spectroscopy, and x-ray diffraction (XRD). Their catalytic properties were examined in the oxidation reaction of cyclohexanone at 90 °C and that of cyclohexene at 70 °C to adipic acid (AA), in presence of hydrogen peroxide and in free solvent. The effects of catalyst/substrate molar ratios, hydrogene peroxide flow rate, heteropolysalt composition, and cyclohexanol addition on AA yields were studied. The Cs4SnP2W12Mo6O62 (the most efficient) led to 61 % of AA yield from the cyclohexanone oxidation using a catalyst/substrate molar ratio of 13.3×10-4, H2O2 flow rate of 0.5 mL/h, and a reaction time of 20 h. Copyright © 2019 BCREC Group. All rights reserved
Received: 6th July 2018; Revised: 21st November 2018; Accepted: 4th December 2018; Available online: 8th April 2019; Published regularly: 1st August 2019
How to Cite: Guerroudj, M.R., Dermeche, L., Mouheb, L., Mazari, T., Benadji, S., Rabia, C. (2019). Preparation, Characterization, and Catalytic Activity of Tin (Antimony) Substituted and Lacunar Dawson Phosphotungstomolybdates for Synthesis of Adipic Acid. Bulletin of Chemical Reaction Engineering & Catalysis, 14 (2): xxx-xxx (doi:10.9767/bcrec.14.2.2905.xxx-xxx)
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