Removal of Iron(II) Using Intercalated Ca/Al Layered Double Hydroxides With [-SiW12O40]4-

Tarmizi Taher -  Environmental Science Study, Graduate Program, Universitas Sriwijaya, Indonesia
Mikha Meilinda Christina -  Department of Chemistry, Faculty of Mathematic and Natural Sciences, Universitas Sriwijaya, Indonesia
Muhammad Said -  Department of Chemistry, Faculty of Mathematic and Natural Sciences, Universitas Sriwijaya, Indonesia
Nurlisa Hidayati -  Department of Chemistry, Faculty of Mathematic and Natural Sciences, Universitas Sriwijaya, Indonesia
Ferlinahayati Ferlinahayati -  Department of Chemistry, Faculty of Mathematic and Natural Sciences, Universitas Sriwijaya, Indonesia
*Aldes Lesbani -  Department of Chemistry, Faculty of Mathematic and Natural Sciences, Universitas Sriwijaya Environmental Science Study, Graduate Program, Universitas Sriwijaya, Indonesia
Received: 1 Jul 2018; Published: 1 Aug 2019.
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Ca/Al layered double hydroxides (LDH) was synthesized by co-precipitation method at pH 11 at room temperature following calcination at 800 ºC. Synthesized Ca/Al LDH was intercalated with Keggin ion [a-SiW12O40]4- to form intercalated Ca/Al LDH. Characterization was performed using powder X-Ray and FT-IR analyses. Ca/Al LDH and intercalated Ca/Al LDH was used as an adsorbent of iron(II) in an aqueous medium. The adsorption process was studied by kinetic and thermodynamic studies. The results showed that Ca/Al LDH has layered structures which were indicated at diffraction 2θ at 20o. Diffraction 2θ at 30-40o from intercalated Ca/Al LDH shows [a-SiW12O40]4-  was successfully conducted. Adsorption of iron(II) on LDH showed that intercalated Ca/Al LDH has slightly higher adsorption capacity than LDH without intercalation. Copyright © 2019 BCREC Group. All rights reserved

Received: 1st July 2018; Revised: 5th November 2018; Accepted: 9th November 2018; Available online: 8th April 2019; Published regularly: 1st August 2019

How to Cite: Taher, T., Christina, M.M., Said, M., Hidayati, N, Ferlinahayati, F., Lesbani, A. (2019). Removal of Iron(II) Using Intercalated Ca/Al Layered Double Hydroxides with [α-SiW12O40]4-. Bulletin of Chemical Reaction Engineering & Catalysis, 14 (2): xxx-xxx (doi:10.9767/bcrec.14.2.2880.xxx-xxx)

Permalink/DOI: https://doi.org/10.9767/bcrec.14.2.2880.xxx-xxx

 

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Keywords
Layered Double Hydroxides; Iron(II); Keggin Ion; Adsorption
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