DOI: https://doi.org/10.9767/bcrec.14.2.2880.260-267

Removal of Iron(II) Using Intercalated Ca/Al Layered Double Hydroxides with [α-SiW12O40]4-

1Environmental Science Study, Graduate Program, Universitas Sriwijaya, Indonesia

2Department of Chemistry, Faculty of Mathematic and Natural Sciences, Universitas Sriwijaya, Indonesia

Received: 1 Jul 2018; Revised: 5 Nov 2018; Accepted: 9 Nov 2018; Available online: 30 Apr 2019; Published: 1 Aug 2019.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2019 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

Ca/Al layered double hydroxide (LDH) was successfully synthesized by co-precipitation method at pH 11 under room temperature condition then followed by calcination at 800 oC. The synthesized Ca/Al LDH was further intercalated with Keggin ion [α-SiW12O40]4- in order to prepare the intercalated form of Ca/Al LDH. The synthesized materials were characterized by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) and used as an adsorbent for iron(II) removal from the aqueous medium. The adsorption performance was investigated by studying the kinetics and thermodynamic properties of the adsorption process. The results showed that pristine Ca/Al LDH exhibited diffraction peak at 2θ about 20o which corresponds to the layer structure of the LDH material. For the intercalated Ca/Al LDH, the diffraction observed at 2θ around 30-40o indicated that the [α-SiW12O40]4- was successfully intercalated into the interlayer space of Ca/Al LDH. Furthermore, the intercalated Ca/Al LDH showed higher adsorption capacity toward iron(II) than the pristine form of Ca/Al LDH. 

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Keywords: Layered Double Hydroxides; Iron(II); Keggin Ion; Adsorption
Funding: Universitas Sriwijaya through “Hibah Profesi” 2017/2018 contract no. 987/UN9.3.1/PP/2017

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Section: Original Research Articles
Language : EN
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  16. Anirudhan, T.S., Jalajamony, S., Sreekumari, S.S. (2012). Adsorption of heavy metal ions from aqueous solutions by amine and carboxylate functionalised bentonites. Applied Clay Science, 65-66: 67-71. doi: 10.1016/j.clay.2012.06.005
  17. Adebowale, K.O., Unuabonah, I.E., Olu-Owolabi, B.I. (2005). Adsorption of some heavy metal ions on sulfate- and phosphate-modified kaolin. Applied Clay Science, 29(2): 145-148. doi: 10.1016/j.clay.2004.10.003
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  30. Carriazo, D., Lima, S., Martín, C., Pillinger, M., Valente, A.A., Rives, V. (2007). Metatungstate and tungstoniobate-containing LDHs: Preparation, characterisation and activity in epoxidation of cyclooctene. Journal of Physics and Chemistry of Solids, 68(10): 1872-1880. doi: 10.1016/j.jpcs.2007.05.012
  31. Omwoma, S., Chen, W., Tsunashima, R., Song, Y.F. (2014). Recent advances on polyoxometalates intercalated layered double hydroxides: From synthetic approaches to functional material applications. Coordination Chemistry Reviews. doi: 10.1016/j.ccr.2013.08.039
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  33. Lesbani, A., Kawamoto, R., Uchida, S., Mizuno, N. (2008). Control of structures and sorption properties of ionic crystals of A2[Cr3O(OOCC2H5)6(H2O)3]2[alpha-SiW12O40] (A = Na, K, Rb, NH4, Cs. Inorganic chemistry, 47(8): 3349-3357. doi: 10.1021/ic702333w
  34. Lesbani, A., Hensen, H., Taher, T., Hidayati, N., Mohadi, R., Andreas, R. (2018). Intercalation of Zn/Al layered double hydroxides with Keggin ion as adsorbent of cadmium (II). In AIP Conference Proceedings (Vol. 2026, p. 20011)
  35. Mahjoubi, F.Z., Khalidi, A., Abdennouri, M., Barka, N. (2017). Zn–Al layered double hydroxides intercalated with carbonate, nitrate, chloride and sulphate ions: Synthesis, characterisation and dye removal properties. Journal of Taibah University for Science, 11(1): 90-100. doi: 10.1016/j.jtusci.2015.10.007
  36. Chang, C.H., Franses, E.I. (1992). Modified Langmuir-Hinselwood kinetics for dynamic adsorption of surfactants at the air/water interface. Colloids and Surfaces, 69(2): 189-201. doi: 10.1016/0166-6622(92)80230-Y

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