Bio-kerosene and Bio-gasoil from Coconut Oils Via Hydrocracking Process over Ni-Fe/HZSM-5 Catalyst

DOI: https://doi.org/10.9767/bcrec.0.0.2669.xxx-xxx
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Submitted: 16-05-2018
Published: 25-01-2019
Section: Original Research Articles
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In this study, hydrocracking of coconut oil over Ni-Fe/HZSM-5 catalyst were carried out in a batch reactor under different reaction temperature. Coconut oil is proposed as one of the potential feedstock for biofuel production. Ni-Fe/HZSM-5 catalyst was prepared by incipient wetness impregnation method. The characterization of Ni-Fe/HZSM-5 catalyst by X-Ray Diffraction (XRD), Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDAX), and Brunauer-Emmett-Teller (BET). The chemical composition of biofuel was analyzed by Gas-Chromatography-Mass Spectrometry (GC-MS). The results from the GC-MS analysis showed that the hydrocracking reaction over 10%(Ni-Fe)/HZSM-5 catalyst at 375 oC obtained the highest hydrocarbon content (contained 49.4% n-paraffin, 26.93% isoparaffin, 3.58% olefin) and the highest yield of bio-gasoil 38.6% in the biofuel liquid hydrocarbon. Pentadecane (n-C15) and heptadecane (n-C17) were the most abundant hydrocarbon compounds in biofuel liquid hydrocarbon. Decarboxylation and/or decarbonylation was the dominant reaction pathways in this process. Based on the result, the reaction temperature had a significantly effect on the distribution of biofuel composition and yield of biofuel from coconut oil.

Received: 16th May 2018; Revised: 18th December2018; Accepted: 22th December 2018

Keywords

Hydrocracking; coconut oil; Ni-Fe/HZSM-5 catalyst; n-paraffin

  1. Muhammad Al-Muttaqii 
    Chemical Reaction Engineering Laboratory, Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology Surabaya, 60111, Indonesia
    Chemical Engineering Department
  2. Firman Kurniawansyah 
    Chemical Reaction Engineering Laboratory, Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology Surabaya, 60111, Indonesia
  3. Danawati Hari Prajitno 
    Chemical Reaction Engineering Laboratory, Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology Surabaya, 60111, Indonesia
  4. Achmad Roesyadi 
    Chemical Reaction Engineering Laboratory, Department of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology Surabaya, 60111, Indonesia
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