Kinetic of Adsorption Process of Sulfonated Carbon-derived from Eichhornia crassipes in the Adsorption of Methylene Blue Dye from Aqueous Solution

Mukhamad Nurhadi; Iis Intan Widiyowati; Wirhanuddin Wirhanuddin; Sheela Chandren

doi:10.9767/bcrec.14.1.2548.17-27

DOI: https://doi.org/10.9767/bcrec.14.1.2548.17-27

Kinetic of Adsorption Process of Sulfonated Carbon-derived from Eichhornia crassipes in the Adsorption of Methylene Blue Dye from Aqueous Solution

Mukhamad Nurhadi¹

, Iis Intan Widiyowati¹, Wirhanuddin Wirhanuddin¹, Sheela Chandren^{2, 3}

¹Department of Chemical Education, Universitas Mulawarman, Kampus Gunung Kelua, Samarinda, 75123, East Kalimantan, Indonesia

²Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, Malaysia

³Centre for Sustainable Nanomaterials, Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, Malaysia

Received: 20 Apr 2018; Revised: 28 Aug 2018; Accepted: 4 Sep 2018; Available online: 25 Jan 2019; Published: 15 Apr 2019.

Editor(s): Istadi Istadi

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Abstract

The evaluation of kinetic adsorption process of sulfonated carbon-derived from Eichhornia crassipes in the adsorption of methylene blue dye from aqueous solution has been carried out. The sulfonated carbon-derived from E. crassipes (EGS-600) was prepared by carbonation of E. crassipes powder at 600 °C for 1 h, followed by sulfonation with concentrated sulfuric acid for 3 h. The physical properties of the adsorbents were characterized by using Fourier transform infrared spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), and nitrogen adsorption-desorption studies. Adsorption study using methylene blue dye was carried out by varying the contact time and initial dye concentration for investigated kinetics adsorption models. The effect of varying temperature was used to determine the thermodynamic parameter value of ΔG, ΔH, and ΔS. The results showed that the equilibrium adsorption capacity was 98% when EGS-600 is used as an adsorbent. The methylene blue dye adsorption onto adsorbent takes place spontaneity and follows a pseudo-second-order adsorption kinetic model.

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Keywords: Eichhornia crassipes (water hyacinth); methylene blue; adsorption; sulfonation; carbon

Funding: Islamic Development Bank (IDB) project and Faculty of Teacher Training and Education, Universitas Mulawarman, East Kalimantan Province, Indonesia

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Section: Original Research Articles

Language : EN

In 2019: BCREC Volume 14 Issue 1 Year 2019 (April 2019)

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