Impact of Testing Temperature on the Structure and Catalytic Properties of Au Nanotubes Composites

*Anastassiya A. Mashentseva orcid scopus  -  The Institute of Nuclear Physics of the Republic of Kazakhstan, Kazakhstan
Maxim V. Zdorovets  -  The Institute of Nuclear Physics of the Republic of Kazakhstan, Russian Federation
Daryn B. Borgekov  -  The Institute of Nuclear Physics of the Republic of Kazakhstan, Kazakhstan
Received: 23 Jan 2018; Published: 4 Dec 2018.
Open Access Copyright (c) 2018 Bulletin of Chemical Reaction Engineering & Catalysis
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Abstract

In the paper, the catalytic activity of composites based on gold nanotubes and ion track membranes was studied using bench reaction of the p-nitrophenol (4-NP) reduction in the temperature range of 25-40 °C. The efficiency of the prepared catalysts was estimated on the rate constant of the reaction and by conversion degree of 4-NP to p-aminophenol (4-AP). The comprehensive evaluation of the structure was performed by X-ray diffraction and scanning electron microscopy. A decreasing of the composites activity was observed when the reaction were carried out at the temperature over 35 °C, due to an increased average crystallite size from 7.31±1.07 to 10.35±3.7 nm (after 1st run). In temperature range of 25-35 °C the efficiency of the composite catalyst was unchanged in 3 runs and decreases by 24-32 % after the 5th run. At the high temperature of 40 °C after the 5th run the composite become completely  catalytically inert. Copyright © 2018 BCREC Group. All rights reserved

Received: 23rd January 2018; Revised: 19th March 2018; Accepted: 19th March 2018

How to Cite: Mashentseva, A.A., Zdorovets, M.V., Borgekov, D.B. (2018). Impact of Testing Temperature on the Structure and Catalytic Properties of Au Nanotubes Composites. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (3): 405-411 (doi:10.9767/bcrec.13.3.2127.405-411)

Permalink/DOI: https://doi.org/10.9767/bcrec.13.3.2127.405-411

 

Keywords
Gold Nanotubes; Composite Membrane; Catalysis; Ion Track Membranes

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