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An Efficient Synthesis of 1,8-Dioxo-Octahydroxanthenes Derivatives Using Heterogeneous Ce-ZSM-11 Zeolite Catalyst

Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad (M.S.), 431004, India

Received: 5 Jan 2018; Revised: 25 May 2018; Accepted: 27 May 2018; Published: 4 Dec 2018; Available online: 14 Nov 2018.
Open Access Copyright (c) 2018 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

The Ce-ZSM-11 zeolite has been used as an efficient catalyst for the one pot synthesis of 1,8-dioxo-octahydroxanthene derivatives from aromatic aldehyde and 5,5-dimethyl-cyclohexane-1,3-dione under reflux condition. The catalyst was characterized by Powder X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Fourier Transform Infrared Spectroscopy (FTIR), Brunauer-Emmer-Teller (BET) surface area analysis, and Temperature Programmed Desorption (TPD) techniques. This method provides several advantageous such as use of inexpensive catalyst, simple work-up procedure, high yield of desired product and reusability of catalyst. 

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Keywords: Ce-ZSM-11 Zeolite; 1,8-Dioxo-octahydroxanthene; Aromatic Aldehyde; 5,5-Dimethyl-cyclohexane-1,3-dione
Funding: Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad–431004 (MS), India

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