DOI: https://doi.org/10.9767/bcrec.13.3.1961.429-435

Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone

1College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, China

2College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China

Received: 13 Dec 2017; Revised: 23 May 2018; Accepted: 23 May 2018; Available online: 14 Nov 2018; Published: 4 Dec 2018.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2018 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

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Abstract

A new calcium(II) complex was synthesized by one-pot synthesis method from disodium 4-formylbenzene-1,3-disulfonate, isonicotinic acid hydrazide and Ca(ClO4)2•2H2O. The structure of calcium(II) complex was determined by elemental analysis, IR and single crystal X-ray diffraction. The results show that the Ca(II) complex molecules form 3D network structure by the interactions of π-π stacking and hydrogen bonds. The Ca(II) complex catalyst could efficiently catalyse oxidation of benzylic alcohol with good conversion of benzyl alcohol (78 %) and excellent selectivity of benzaldehyde (98 %).

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Keywords: Ca(II) Complex Catalyst; Synthesis; Structural Characterization; Catalytic Activity
Funding: National Natural Science Foundation of China (No. 21171132), the National Natural Science Foundation of Shandong (ZR2014BL003), the Project of Shandong Province Higher Educational Science and Technology Program (J14LC01), and Science Foundation of Weifang

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Section: Original Research Articles
Language : EN
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