Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone

DOI: https://doi.org/10.9767/bcrec.13.3.1961.429-435
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Submitted: 13-12-2017
Published: 04-12-2018
Section: Original Research Articles
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A new calcium(II) complex was synthesized by one-pot synthesis method from disodium 4-formylbenzene-1,3-disulfonate, isonicotinic acid hydrazide and Ca(ClO4)2•2H2O. The structure of calcium(II) complex was determined by elemental analysis, IR and single crystal X-ray diffraction. The results show that the Ca(II) complex molecules form 3D network structure by the interactions of π-π stacking and hydrogen bonds. The Ca(II) complex catalyst could efficiently catalyse oxidation of benzylic alcohol with good conversion of benzyl alcohol (78 %) and excellent selectivity of benzaldehyde (98 %).Copyright © 2018 BCREC Group. All rights reserved.

Received: 13rd December 2017; Revised: 23rd May 2018; Accepted: 23rd May 2018

How to Cite: Tai, X.S., Li, P.F., Liu, L.L. (2018). Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (3): 429-435 (doi:10.9767/bcrec.13.3.1961.429-435)

Permalink/DOI: https://doi.org/10.9767/bcrec.13.3.1961.429-435

 

Keywords

Ca(II) Complex Catalyst; Synthesis; Structural Characterization; Catalytic Activity

  1. Xi-Shi Tai 
    College of Chemistry and Chemical Engineering, Weifang University , Weifang 261061, China
  2. Peng-Fei Li 
    College of Chemical Engineering, Qingdao University of Science and Technology , Qingdao 266061, China
  3. Li-Li Liu 
    College of Chemistry and Chemical Engineering, Weifang University , Weifang 261061, China
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