Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil

Yustia Wulandari Mirzayanti; Firman Kurniawansyah; Danawati Hari Prayitno; Achmad Roesyadi

doi:10.9767/bcrec.13.1.1508.136-143

DOI: https://doi.org/10.9767/bcrec.13.1.1508.136-143

Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil

Yustia Wulandari Mirzayanti

, Firman Kurniawansyah, Danawati Hari Prayitno, Achmad Roesyadi

Chemical Reaction Engineering Laboratory, Department of Chemical Engineering, Sepuluh Nopember Institute of Technology, Sukolilo, Surabaya, 60111, Indonesia

Received: 8 Sep 2017; Revised: 9 Sep 2017; Accepted: 17 Sep 2017; Available online: 22 Jan 2018; Published: 2 Apr 2018.

Editor(s): Istadi Istadi

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

BibTex Citation Data :

@article{BCREC1508,
    author = {Yustia Mirzayanti and Firman Kurniawansyah and Danawati Prayitno and Achmad Roesyadi},
    title = {Zn-Mo/HZSM-5 Catalyst for Gasoil Range Hydrocarbon Production by Catalytic Hydrocracking of Ceiba pentandra oil},
    journal = {Bulletin of Chemical Reaction Engineering & Catalysis},
  volume = {13},
    number = {1},
    year = {2018},
    keywords = {catalytic hydrocracking; Ceiba pentandra oil; ZincMo/HZSM-5 catalyst; liquid hydrocarbon},
    abstract = { Biofuel from vegetable oil becomes one of the most suitable and logical alternatives to replace fossil fuel. The research focused on various metal ratio Zinc/Molybdenum/HZSM-5 (Zn-Mo/HZSM-5) catalyst to produce liquid hydrocarbon via catalytic hydrocracking of Ceiba penandra oil. The catalytic hydrocracking process has been applied in this study to crack Ceiba pentandra oil into a gasoil range hydrocarbon using Zn-Mo/HZSM-5 as a catalyst. The effect of various reaction temperature on the catalytic hydrocracking of Ceiba pentandra oil were studied. The Zn-Mo/HZSM-5 catalyst with metal ratio was prepared by incipient wetness impregnation method. This process used slurry pressure batch reactor with a mechanical stirrer. A series of experiments were carried out in the temperature range from 300-400  o C for 2 h at pressure between 10-15 bar. The conversion and selectivity were estimated. The liquid hydrocarbon product were identified to gasoline, kerosene, and gas oil. The results show that the use of Zn-Mo/HZSM-5 can produce gas oil as the most component in the product. Overall, the highest conversion and selectivity of gas oil range hydrocarbon was obtained when the ZnMo/HZSM-5 metal ratio was Zn(2.86 wt.%)-Mo(5.32 wt.%)/HZSM-5 and the name is Zn-Mo/HZSM-5_102. The highest conversion was obtained at 63.31 % and n-paraffin (gas oil range) selectivity was obtained at 90.75 % at a temperature of 400  o C. Ceiba pentandra oil can be recommended as the source of inedible vegetable oil to produce gasoil as an environmentally friendly transportation fuel.  },
   issn = {1978-2993},   pages = {136--143}  doi = {10.9767/bcrec.13.1.1508.136-143},
    url = {https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1508}
}

Citation Format:

Abstract

Biofuel from vegetable oil becomes one of the most suitable and logical alternatives to replace fossil fuel. The research focused on various metal ratio Zinc/Molybdenum/HZSM-5 (Zn-Mo/HZSM-5) catalyst to produce liquid hydrocarbon via catalytic hydrocracking of Ceiba penandra oil. The catalytic hydrocracking process has been applied in this study to crack Ceiba pentandra oil into a gasoil range hydrocarbon using Zn-Mo/HZSM-5 as a catalyst. The effect of various reaction temperature on the catalytic hydrocracking of Ceiba pentandra oil were studied. The Zn-Mo/HZSM-5 catalyst with metal ratio was prepared by incipient wetness impregnation method. This process used slurry pressure batch reactor with a mechanical stirrer. A series of experiments were carried out in the temperature range from 300-400 ^oC for 2 h at pressure between 10-15 bar. The conversion and selectivity were estimated. The liquid hydrocarbon product were identified to gasoline, kerosene, and gas oil. The results show that the use of Zn-Mo/HZSM-5 can produce gas oil as the most component in the product. Overall, the highest conversion and selectivity of gas oil range hydrocarbon was obtained when the ZnMo/HZSM-5 metal ratio was Zn(2.86 wt.%)-Mo(5.32 wt.%)/HZSM-5 and the name is Zn-Mo/HZSM-5_102. The highest conversion was obtained at 63.31 % and n-paraffin (gas oil range) selectivity was obtained at 90.75 % at a temperature of 400 ^oC. Ceiba pentandra oil can be recommended as the source of inedible vegetable oil to produce gasoil as an environmentally friendly transportation fuel.

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Keywords: catalytic hydrocracking; Ceiba pentandra oil; ZincMo/HZSM-5 catalyst; liquid hydrocarbon

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Section: Original Research Articles

Language : EN

In 2018: BCREC Volume 13 Issue 1 Year 2018 (April 2018)

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