DOI: https://doi.org/10.9767/bcrec.17.2.14074.476-485

Hydrocracking of Crude Palm Oil over Bimetallic Oxide NiO-CdO/biochar Catalyst

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Islam Indonesia, Yogyakarta, Indonesia

Received: 16 Apr 2022; Revised: 16 Jun 2022; Accepted: 17 Jun 2022; Available online: 18 Jun 2022; Published: 30 Jun 2022.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2022 by Authors, Published by BCREC Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

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Abstract

The bimetallic oxide NiO-CdO/biochar catalyst was prepared by coprecipitation and calcination methods. Characterizations of catalyst were carried out using Fourier Transform Infra Red (FTIR), Surface Area Analyzer (SAA), X-ray Diffraction (XRD), and Scanning Electron Microscope-Energy Dispersive X-ray (SEM-EDX) mapping methods. The catalyst showed a good average crystalized size of 12.30 nm related to the nanoparticles and high dispersion of Ni and Cd metals  on the biochar surface. Analysis of liquid fuel products was observed using Gas Chromatography - Mass Spectrometry (GC-MS) which was separated to the main product of gasoline fraction (C6–C10), and the second product of kerosene fraction (C11–C16), and diesel fraction (C17–C23). The presence of the catalyst in the hydrocracking resulted in more liquid product of 56.55 wt% than the thermal cracking with a liquid product of 20.55 wt%. The best performance activity of catalyst was found at a temperature of 150 °C with high selectivity to hydrocarbon fuel with 12 types of gasoline fractions (39.24 wt%) compared to gasoline fractions obtained at higher hydrocracking temperatures of 250 °C and 350 °C. The results of this study showed that the bimetallic oxide catalyst supported with biochar from palm kernel shell plays an important role in the hydrocracking process to increase the selectivity of the gasoline fraction. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

 

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Keywords: Crude palm oil, NiO-CdO/biochar, catalytic hydrocracking, gasoline fraction, coke.
Funding: The Ministry of Education, Culture, Research, and Technology (Kemdikbudristek) under contract 003/DirDPPM/70/DPPM/PDUPT-Kemendikbudristek/VII/2021

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Section: Original Research Articles
Language : EN
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  8. Wibowo, S., Efiyanti, L., Pari, G. (2020). Catalytic and Thermal Cracking of Bio-Oil from Oil-Palm Empty Fruit Bunches, in Batch Reactor, Indonesian Journal of Chemistry, 20(5), 1000-1009. DOI: 10.22146/ijc.44076
  9. Wijaya, K., Syoufian, A., Fitroturokhmah, A., Trisunaryanti, W., Saputra, D.A., Hasanudin, H. (2019). Chrom/Nanocomposite ZrO2-Pillared Bentonite Catalyst for Castor Oil (Ricinus communis) Hydrocracking. Nano Hybrids and Composites, 27, 31-37. DOI: 10.4028/www.scientific.net/NHC.27.31
  10. Krishnamurthy, K.R. (1998). Modifications in supported metal catalysts: effect of promoters. Studies in Surface Science and Catalysis, 113, 139-150. DOI: 10.1016/S0167-2991(98)80281-4
  11. Koji, S., Toshiyuki, K., Mami, Y., Sachio, A. (2011). NiMo/Al2O3 Promoted Hybrid Catalysts of Nanosized Alumina and Beta Zeolite for Hydrocracking with Isomerization. Journal of the Japan Petroleum Institute, 54(5), 320-330. DOI: 10.1627/jpi.54.320
  12. Hossein, E., Sajad, T. (2020). Ultrasonic-assisted synthesis of natural clay/Fe3O4/graphene oxide for enhance removal of Cr (VI) from aqueous media. Environmental Science and Pollution Research, 27, 31652–31664. DOI: 10.1007/s11356-020-09448-y
  13. Tambun, R., Ferani, D.G., Afrina, A., Tambun, J.A.A., Tarigan, I.A.A. (2019). Fatty Acid Direct Production from Palm Kernel Oil. IOP Conference Series: Materials Science and Engineering, 505, 012115. DOI: 10.1088/1757-899X/505/1/012115
  14. Maliwan, S., Pakpoom, S., Chalerm, R. (2017). Effect of bimetallic NiW modified crystalline ZSM-5 zeolite on catalytic conversion of crude palm oil and identification of biofuel products. Asia-Pacific Journal of Chemical Engineering, 12(1), 147-158. https://doi.org/10.1002/apj.2061
  15. Stella, B., Spyros, V., Aggeliki, K. (2009). Catalytic Hydrocracking of Fresh and Used Cooking Oil. Industrial & Engineering Chemistry Research, 48(18), 8402–8406 . DOI: 10.1021/ie900445m
  16. Yakout, S.M., El-Deen, G.S. (2011). Characterization of activated carbon prepared by phosphoric acid activation of olive stones. Arabian Journal of Chemistry, 9(2), S1155-S1162. DOI: 10.1016/j.arabjc.2011.12.002
  17. Saleem, J., Shahid, U.B., Hijab, M., Mackey, H., McKay, G. (2019). Production and applications of activated carbons as adsorbents from olive stones. Biomass Conversion and Biorefinery, 9(4), 775–802. DOI: 10.1007/s13399-019-00473-7
  18. Omer, S., Cafer, S. (2013). Preparation and characterization of activated carbon from acorn shell by physical activation with H2O–CO2 in two-step pretreatment. Bioresource Technology, 136, 163-168. DOI: 10.1016/j.biortech.2013.02.074
  19. Lingeswarran, M., Farook, A., Rahman, M.A., Eng-Poh, N. (2014). The synthesis and characterization of high purity mixed microporous/mesoporous activated carbon from rice husk using chemical activation with NaOH and KOH. Microporous and Mesoporous Materials, 197, 316-323. DOI: 10.1016/j.micromeso.2014.06.020
  20. Kadarwati, S., Wahyuni, S. (2015). Polymerisation and Coke Formation during Mild Hydrotreatment of Bio-Oil over Pre-sulphided Co-Mo/γ-Al2O3 Catalyst. International Journal of Renewable Energy Development, 4(1), 32-38. DOI: 10.14710/ijred.4.1.32-38
  21. Kikhtyanin, O., Pospelova, V., Aubrecht, J., Lhotka, M., Kubička, D. (2018). Effect of Calcination Atmosphere and Temperature on the Hydrogenolysis Activity and Selectivity of Copper-Zinc Catalysts. Catalysts, 8(10), 446. DOI: 10.3390/catal8100446
  22. Kaminski, T., Anis, S.F., Husein, M.M., Hashaikeh, R. (2018). Hydrocracking of Athabasca VR using NiO-WO3 Zeolite Based Catalysts. Energy & Fuels, 32(2), 2224–2233. DOI: 10.1021/acs.energyfuels.7b03754
  23. Sriatun, S., Susanto, H., Widayat, W., Darmawan, A. (2021). Hydrocracking of Coconut Oil on the NiO/Silica Rich Zeolite Synthesized Using a Quaternary Ammonium Surfactant. Indonesian Journal of Chemistry, 21(2), 361-375. DOI: 10.22146/ijc.55522
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  25. Bajpai, P. (2020). Chapter 6 - Products of conversion technology. In: P. Bajpai (Ed.) Biomass to Energy Conversion Technologies, p. 153–167. DOI: 10.1016/b978-0-12-818400-4.00006-2
  26. Al-Muttaqii, M., Kurniawansyah, F., Prajitno, D.H., Roesyadi, A. (2019). Hydrocarbon Biofuel Production by Hydrocracking Process with Nickel-Iron Supported on HZSM-5 Catalyst. IOP Conference Series: Materials Science and Engineering, 543, 012055. DOI: 10.1088/1757-899X/543/1/012055
  27. Randhawa, N.S., Gharami, K., Kumar, M. (2016). Leaching kinetics of spent nickel–cadmium battery in sulphuric acid. Hydrometallurgy, 165, 191-198. DOI: 10.1016/j.hydromet.2015.09.011
  28. Fanning, P.E., Vannice, M.A. (1993). A DRIFTS study of the formation of surface groups on carbon by oxidation. Carbon, 31(5), 721-730. DOI: 10.1016/0008-6223(93)90009-y
  29. Bezergianni, S., Kalogianni, A. (2009). Hydrocracking of used cooking oil for biofuels production. Bioresource Technology, 100(17), 3927-3932. DOI: 10.1016/j.biortech.2009.03.039

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