Comparison of Five Advanced Oxidation Processes for Degradation of Pesticide in Aqueous Solution

*Augustine Chioma Affam  -  Department of Civil Engineering, School of Engineering and Technology, University College of Technology Sarawak, 96000, Sibu, Sarawak, Malaysia
Malay Chaudhuri  -  Department of Civil Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak, Malaysia
Shamsul Rahman M. Kutty  -  Department of Civil Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak, Malaysia
Received: 26 Jul 2017; Revised: 26 Sep 2017; Accepted: 27 Sep 2017; Published: 2 Apr 2018; Available online: 22 Jan 2018.
Open Access Copyright (c) 2018 Bulletin of Chemical Reaction Engineering & Catalysis
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Citation Format:
Cover Image
Abstract

The study compared the technical efficiency and economic cost of five advanced oxidation processes (Fenton, UV photo-Fenton, solar photo-Fenton, UV/TiO2/H2O2 and FeGAC/H2O2) for degradation of the pesticides chlorpyrifos cypermethrin and chlorothalonil in aqueous solution. The highest degradation in terms of COD and TOC removals and improvement of the biodegradability (BOD5/COD ratio) index (BI) were observed to be (i) Fenton - 69.03% (COD), 55.61% (TOC), and 0.35 (BI); (ii) UV photo-Fenton -78.56% (COD), 63.76% (TOC) and 0.38 (BI);  (iii) solar photo-Fenton - 74.19% (COD), 58.32% (TOC) and 0.36 (BI); (iv) UV/TiO2/H2O2 - 53.62% (COD), 21.54% (TOC), and 0.26 (BI); and  (v) the most technical efficient and cost effective process was FeGAC/H2O2. At an optimum condition (FeGAC 5 g/L, H2O2 100 mg/L, and reaction time of 60 min at pH 3), the COD and TOC removal efficiency were 96.19 and 85.60%, respectively, and the biodegradation index was 0.40. The degradation rate constant and cost were 0.0246 min-1 and $0.74/kg TOC, respectively. The FeGAC/H2O2 process is the most technically efficient and cost effective for pretreatment of the pesticide wastewater before biological treatment. Copyright © 2018 BCREC Group. All rights reserved

Received: 26th July 2017; Revised: 26nd September 2017; Accepted: 27th September 2017; Available online: 22nd January 2018; Published regularly: 2nd April 2018

How to Cite: Affam, A.C., Chaudhuri, M., Kutty, S.R.M. (2018). Comparison of Five Advanced Oxidation Processes for Degradation of Pesticide in Aqueous Solution. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (1): 179-186 (doi:10.9767/bcrec.13.1.1394.179-186)

 

Keywords: Fenton; UV photo-Fenton; Solar photo-Fenton; UV/TiO2/H2O2; FeGAC/H2O2; Pesticide; biodegradability index (BI)

Article Metrics:

Article Info
Section: The International Conference on Fluids and Chemical Engineering (FluidsChE 2017)
Language: EN
In 2018: BCREC Volume 13 Issue 1 Year 2018 (SCOPUS and Web of Science Indexed, April 2018)
Statistics: 2843 823
Others articles
Synthesis, Structure, and Catalytic Activity of A New Mn(II) Complex with 1,4-Phenylenediacetic Acid and 1,10-Phenanthroline Electrochemical Study of Copper Ferrite as a Catalyst for CO2 Photoelectrochemical Reduction Preparation and Characterization of Anadara Granosa Shells and CaCO3 as Heterogeneous Catalyst for Biodiesel Production Synthesis of Chitosan/Zinc Oxide Nanoparticles Stabilized by Chitosan via Microwave Heating Fe/Indonesian Natural Zeolite as Hydrodeoxygenation Catalyst in Green Diesel Production from Palm Oil The Impact of Hydrogen Peroxide as An Oxidant for Solvent-free Liquid Phase Oxidation of Benzyl Alcohol using Au-Pd Supported Carbon and Titanium Catalysts
  1. Oller, I., Malato, S., Sánchez-Pérez, J.A. (2010). Review: Combination of advanced oxidation processes and biological treatments for wastewater decontamination - A review, Science of The Total Environment, 409(20): 4141-4166 (doi: 10.1016/j.scitotenv.2010.08.061)
  2. Chamarro, E., Marco, A., Esplugas, S. (2001). Use of Fenton reagent to improve organic biodegradability, Water Research, 35 (4)1047-1051 (doi: 10.1016/S0043-1354(00)00342-0)
  3. Pignatello, J.J., Liu, D., Houston, P. (1999) Evidence for an additional oxidant in the photo assisted Fenton reaction, Environmental Science & Technology 33(11): 1832-1839. (doi: 10.1021/es980969b)
  4. Lorret, O., Francová, D., Waldner, G., Stelzer Stelzer, N. (2009). W-doped titania nanoparticles for UV and visible-light photocatalytic reactions. Appl. Catal. B 91(1-2): 39-46 (doi: 10.1016/j.apcatb.2009.05.005
  5. Pekakis, P.A., Xekoukoulotakis, N.P., Mantzavinos, D. (2006). Treatment of textile dyehouse wastewater by TiO2 photocatalysis, Water Research, 40(6): 1276-1286. (doi: 10.1016/j.watres.2006.01.019)
  6. Sadik, W.A., Nashed, A.W., El-Demerdash, A.G.M. (2007). Photodecolourization of ponceau 4R by heterogeneous photocatalysis, Journal of Photochemical & Photobiology A. 189(1):135-140
  7. Fan, H., Shua, H., Tajima, K. (2006). Decolorization of acid black 24 by the FeGAC/H2O2 process, Journal of Hazardous Materials, 128(2-3): 192-200
  8. APHA, AWWA, WPCF, Standard Methods for the Examination of Water and Wastewater, 21st ed. American Public Health Association, Washington, DC, 2005
  9. Talinli, I., Anderson, G.K. (1992). Interference of hydrogen peroxide on the standard COD test, Water Research, 26(1): 107-110 (doi: 10.1016/0043-1354(92)90118-N)
  10. Kang, Y.W., Cho, M.J. Hwang, K.Y. (1999). Correction of hydrogen peroxide interference on standard chemical oxygen demand test, Water Research, 33(5): 1247-1251 (doi: 10.1016/S0043-1354(98)00315-7)
  11. Hach. (2002). Water Analysis Handbook (4th Edition.) Loveland, CO: Hach Company
  12. Lu, C., Liu, C., Rao, G. P. (2008) Comparisons of sorbent cost for the removal of Ni2+ from aqueous solution by carbon nanotubes and granular activated carbon, Journal of Hazardous Materials, 151(1): 239-246 (doi: 10.1016/j.jhazmat.2007.05.078)
  13. Cañizares, P., Paz, R., Sáez, C., Rodrigo, M.A. (2009). Costs of the electrochemical oxidation of wastewaters: A comparison with ozonation and Fenton oxidation processes, Journal of Environmental Management, 90(1): 410-420
  14. (doi: 10.1016/j.jenvman.2007.10.010)
  15. Körbahti, B., Artut, K. (2010). Electrochemical oil/water demulsification and purification of bilge water using Pt/Ir electrodes. Desalination 258: 219-228
  16. Affam, A.C., Chaudhuri, M., Kutty, S.R.M.(2012). Fenton treatment of combined Chlorpyrifos, cypermethrin and chlorothalonil pesticides in aqueous solution, Journal of Environmental Science Technology, 5(6): 407- 418 (doi: 10.3923/jest.2012.407.418)
  17. Abderrazik, N.B., Al Momani, F., Sans, C., Esplugas S. (2002). Combined advanced oxi-dation with biological treatment. Afinidad -Barcelona 59(498): 141-146
  18. Martín M.M.B., Pérez, J.A.S., López, J.LC. Oller, I., Rodríguez, S.M.M. (2009). Degradation of a four-pesticide mixture by combined photo-Fenton and biological oxidation, Water Research. 43(3): 653-660. (doi: 10.1016/j.watres.2008.11.020)
  19. Scott, J.P., Ollis, D.F. (1995). Integration of chemical and biological oxidation processes for water treatment: Review and recommendation Environmental Progress & Sustainable Energy, 14(2): 88-103 (doi: 10.1002/ep.670140212)
  20. Shen, Y.S., Ku, Y., Lee, K.C. (1995). The effect of light absorbance on the decomposition of chlorophenols by ultraviolet radiation and UV/H2O2 processes, Water Research, 29 (3) 907-914 (doi: 10.1016/0043-1354(94)00198-G)
  21. Zhang, Y., Xiao, Z., Chen, F., Ge, Y., Wu, J., Hu, X.(2010). Degradation behavior and products of malathion and chlorpyrifos spiked in apple juice by ultrasonic treatment, Ultrasonics Sonochemistry, 17(1): 72-77. (doi: 10.1016/j.ultsonch.2009.06.003)
  22. Bansal, R.C., Donnet, J.B., Stoeckli, F. (1998). Active Carbon. New York: Marcel Dekker
  23. Andreozzi, R., Caprio, V., Insola, A., Marotta, R. (1999). Advanced oxidation processes (AOP) for water purification and recovery, Catalysis Today. 53(1): 51-59 doi: 10.1016/S0920-5861(99)00102-9
  24. Integra Chemical, http://www.integrachem.com/product_catalog_search.asp assessed on 1st January, 2013

Last update: 2021-04-20 07:32:02

No citation recorded.

Last update: 2021-04-20 07:32:03

  1. Photo-Fenton disinfection at near neutral pH: Process, parameter optimization and recent advances

    O'Dowd K.. Journal of Environmental Chemical Engineering, 8 (5), 2020. doi: 10.1016/j.jece.2020.104063

  2. Hazard assessment using an in-silico toxicity assessment of the transformation products of boscalid, pyraclostrobin, fenbuconazole and glyphosate generated by exposure to an advanced oxidative process

    Skanes B.. Toxicology in Vitro, 70 , 2021. doi: 10.1016/j.tiv.2020.105049

  3. Removal of the heavy metal ion nickel (II) via an adsorption method using flower globular magnesium hydroxide

    Jiang D.. Journal of Hazardous Materials, 127 , 2019. doi: 10.1016/j.jhazmat.2019.01.096

  4. Tracking the degradation pathway of three model aqueous pollutants in a heterogeneous Fenton process

    Cohen M.. Journal of Environmental Chemical Engineering, 7 (2), 2019. doi: 10.1016/j.jece.2019.102987

  5. Recent advances on the removal of priority organochlorine and organophosphorus biorecalcitrant pesticides defined by Directive 2013/39/EU from environmental matrices by using advanced oxidation processes: An overview (2007-2018)

    Vagi M.C.. Journal of Environmental Chemical Engineering, 8 (1), 2020. doi: 10.1016/j.jece.2019.102940

  6. Self-assembling 2D/2D (MXene/LDH) materials achieve ultra-high adsorption of heavy metals Ni2+ through terminal group modification

    Feng X.. Separation and Purification Technology, 127 , 2020. doi: 10.1016/j.seppur.2020.117525

  7. Pilot-plant scaled water treatment technologies, standards for the removal of contaminants of emerging concern based on photocatalytic materials

    Veréb G.. Advanced Nanostructures for Environmental Health: Micro and Nano Technologies, 2019. doi: 10.1016/B978-0-12-815882-1.00012-4

  8. Cultivating microalgae in wastewater for biomass production, pollutant removal, and atmospheric carbon mitigation; a review

    Shahid A.. Science of the Total Environment, 127 , 2020. doi: 10.1016/j.scitotenv.2019.135303

  9. Effect of Ag and Mn doping for methylene blue photodegradation performance

    Jessica . IOP Conference Series: Materials Science and Engineering, 127 (1), 2021. doi: 10.1088/1757-899X/1011/1/012043
Copyright (c) 2018 Bulletin of Chemical Reaction Engineering & Catalysis
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Journal Author(s) Rights

In order for BCREC Group to publish and disseminate research articles, we need publishing rights (transfered from author(s) to publisher). This is determined by a publishing agreement between the Author(s) and BCREC Group. This agreement deals with the transfer or license of the copyright of publishing to BCREC Group, while Authors still retain significant rights to use and share their own published articles. BCREC Group supports the need for authors to share, disseminate and maximize the impact of their research and these rights, in any databases.

As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including:

  • use for classroom teaching by Author or Author's institution and presentation at a meeting or conference and distributing copies to attendees; 
  • use for internal training by author's company; 
  • distribution to colleagues for their reseearch use; 
  • use in a subsequent compilation of the author's works; 
  • inclusion in a thesis or dissertation; 
  • reuse of portions or extracts from the article in other works (with full acknowledgement of final article); 
  • preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article); 
  • voluntary posting on open web sites operated by author or author’s institution for scholarly purposes, 
(but it should follow the open access license of Creative Common CC-by-SA License).

Authors/Readers/Third Parties can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (the name of the creator and attribution parties (authors detail information), a copyright notice, an open access license notice, a disclaimer notice, and a link to the material), provide a link to the license, and indicate if changes were made (Publisher indicates the modification of the material (if any) and retain an indication of previous modifications using a CrossMark Policy and information about Erratum-Corrigendum notification).

Authors/Readers/Third Parties can read, print and download, redistribute or republish the article (e.g. display in a repository), translate the article, download for text and data mining purposes, reuse portions or extracts from the article in other works, sell or re-use for commercial purposes, remix, transform, or build upon the material, they must distribute their contributions under the same license as the original Creative Commons Attribution-ShareAlike (CC BY-SA).

Copyright Transfer Agreement for Publishing (Publishing Right)

The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright for publishing (publishing right) of the article shall be assigned/transferred to Publisher of Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) (or BCREC Group).

Upon acceptance of an article, authors will be asked to complete a 'Copyright Transfer Agreement for Publishing (CTAP)'. An e-mail will be sent to the Corresponding Author confirming receipt of the manuscript together with a 'Copyright Transfer Agreement for Publishing' form by online version of this agreement.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University/Masyarakat Katalis Indonesia-Indonesian Catalyst Society (MKICS), the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of copyright for publishing (CTAP), our journal Author(s) retain (or are granted back) significant scholarly rights as mentioned before.

The Copyright Transfer Agreement for Publishing (CTAP) Form can be downloaded here: [Copyright Transfer Agreement for Publishing (CTAP) Form BCREC 2020] 


The copyright form should be signed electronically and send to the Editorial Office in the form of original e-mail below:  

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering & Catalysis
Laboratory of Plasma-Catalysis (R3.5), UPT Laboratorium Terpadu, Universitas Diponegoro
Jl. Prof. Soedarto, Semarang, Central Java, Indonesia 50275
Telp/Whatsapp: +62-81-316426342
E-mail: bcrec[at]live.undip.ac.id

(This policy statements has been updated at 24th December 2020)