Fe/Indonesian Natural Zeolite as Hydrodeoxygenation Catalyst in Green Diesel Production from Palm Oil

Riandy Putra -  Master of Chemistry Program, Graduate School, Sebelas Maret University, Jl. Ir. Sutami No.36A, Kentingan, Jebres Surakarta, 57126, Indonesia
*Witri Wahyu Lestari -  Chemistry Department, Faculty of Mathematics and Natural Sciences, Sebelas Maret University, Jl. Ir. Sutami No. 36 A, Kentingan, jebres, Surakarta, Indonesia
Fajar Rakhman Wibowo -  Master of Chemistry Program, Graduate School, Sebelas Maret University, Jl. Ir. Sutami No.36A, Kentingan, Jebres Surakarta, 57126, Indonesia
Bambang Heru Susanto -  Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus UI Depok, Depok, 16424, Indonesia
Received: 24 Jul 2017; Published: 11 Jun 2018.
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Abstract

The Petroleum diesel-based fossil fuel remains the primary source of energy consumption in Indonesia. The utilization of this unrenewable fuel depletes fossil fuels; thus, an alternative, renewable fuel, such as one based on biohydrocarbon from biomass-green diesel-could be an option. In this work, green diesel was produced through the hydrodeoxygenation from palm oil and processed in a batch-stirred autoclave reactor over natural zeolite (NZ) and NZ modified with 3 wt.% Fe metal (Fe/NZ) as heterogeneous catalyst. NZ showed high crystallinity and suitability to the simulated pattern of the mordenite and clinoptilolite phases according to X-ray diffraction (XRD) analysis. The presence of Fe metal was further confirmed by XRD, with an additional small diffraction peak of Fe0 that appeared at 2θ = 44-45°. Meanwhile, NZ and Fe/NZ were also characterized by Scanning electron microscopy (SEM) with Energy Dispersive X-ray (EDX), X-ray Fluorescence (XRF), and Surface Area Analyzer (SAA). The obtained materials were tested for the conversion of palm oil into diesel-range hydrocarbons (C15-C18) under conditions of 375 °C and 12 bar H2 for 2 h. NZ and Fe/NZ produced a liquid hydrocarbon with straight-chain (C15-C18) alkanes as the most abundant products. Based on Gas Chromatography-Mass Spectrometry (GC-MS) measurement, a higher conversion of palm oil into diesel-like hydrocarbons reached more than 58% and 89%, when NZ and Fe modified NZ (Fe/NZ), respectively were used as catalysts. Copyright © 2018 BCREC Group. All rights reserved

Received: 24th July 2017; Revised: 10th November 2017; Accepted: 15th November 2017; Available online: 11st June 2018; Published regularly: 1st August 2018

How to Cite: Putra, R., Lestari, W.W., Wibowo, F.R., Susanto, B.H. (2018). Fe/Indonesian Natural Zeolite as Hydrodeoxygenation Catalyst in Green Diesel Production from Palm Oil. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (2): 245-255 (doi:10.9767/bcrec.13.2.1382.245-255)

 

Keywords
Indonesian Natural Zeolite; Iron Metal; Hydrodeoxygenation; Palm Oil; Green Diesel

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