Fe/Indonesian Natural Zeolite as Hydrodeoxygenation Catalyst in Green Diesel Production from Palm Oil

Riandy Putra  -  Master of Chemistry Program, Graduate School, Sebelas Maret University, Jl. Ir. Sutami No.36A, Kentingan, Jebres Surakarta, 57126, Indonesia
*Witri Wahyu Lestari orcid scopus  -  Chemistry Department, Faculty of Mathematics and Natural Sciences, Sebelas Maret University, Jl. Ir. Sutami No. 36 A, Kentingan, jebres, Surakarta, Indonesia
Fajar Rakhman Wibowo scopus  -  Master of Chemistry Program, Graduate School, Sebelas Maret University, Jl. Ir. Sutami No.36A, Kentingan, Jebres Surakarta, 57126, Indonesia
Bambang Heru Susanto scopus  -  Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus UI Depok, Depok, 16424, Indonesia
Received: 24 Jul 2017; Revised: 10 Nov 2017; Accepted: 15 Nov 2017; Published: 1 Aug 2018; Available online: 11 Jun 2018.
Open Access Copyright (c) 2018 Bulletin of Chemical Reaction Engineering & Catalysis
License URL: http://creativecommons.org/licenses/by-sa/4.0

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The Petroleum diesel-based fossil fuel remains the primary source of energy consumption in Indonesia. The utilization of this unrenewable fuel depletes fossil fuels; thus, an alternative, renewable fuel, such as one based on biohydrocarbon from biomass-green diesel-could be an option. In this work, green diesel was produced through the hydrodeoxygenation from palm oil and processed in a batch-stirred autoclave reactor over natural zeolite (NZ) and NZ modified with 3 wt.% Fe metal (Fe/NZ) as heterogeneous catalyst. NZ showed high crystallinity and suitability to the simulated pattern of the mordenite and clinoptilolite phases according to X-ray diffraction (XRD) analysis. The presence of Fe metal was further confirmed by XRD, with an additional small diffraction peak of Fe0 that appeared at 2θ = 44-45°. Meanwhile, NZ and Fe/NZ were also characterized by Scanning electron microscopy (SEM) with Energy Dispersive X-ray (EDX), X-ray Fluorescence (XRF), and Surface Area Analyzer (SAA). The obtained materials were tested for the conversion of palm oil into diesel-range hydrocarbons (C15-C18) under conditions of 375 °C and 12 bar H2 for 2 h. NZ and Fe/NZ produced a liquid hydrocarbon with straight-chain (C15-C18) alkanes as the most abundant products. Based on Gas Chromatography-Mass Spectrometry (GC-MS) measurement, a higher conversion of palm oil into diesel-like hydrocarbons reached more than 58% and 89%, when NZ and Fe modified NZ (Fe/NZ), respectively were used as catalysts. Copyright © 2018 BCREC Group. All rights reserved

Received: 24th July 2017; Revised: 10th November 2017; Accepted: 15th November 2017; Available online: 11st June 2018; Published regularly: 1st August 2018

How to Cite: Putra, R., Lestari, W.W., Wibowo, F.R., Susanto, B.H. (2018). Fe/Indonesian Natural Zeolite as Hydrodeoxygenation Catalyst in Green Diesel Production from Palm Oil. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (2): 245-255 (doi:10.9767/bcrec.13.2.1382.245-255)


Keywords: Indonesian Natural Zeolite; Iron Metal; Hydrodeoxygenation; Palm Oil; Green Diesel
Funding: L’Oréal-UNESCO for Women in Science (FWIS National Fellowship 2014 Awarded to W.W.L) and Hibah MRG PNBP UNS 2017 project number 623/UN.27.21/PP/2017

Article Metrics:

  1. Orozco, L.M., Echeverri, D.A., Sánchez, L., Rios, L.A. (2017). Second-generation Green Diesel from Castor Oil: Development of a New and Efficient Continuous-production Process. Chem. Eng. J., 322: 149-156
  2. Kusuma, R.I., Hadinoto, J.P., Ayucitra, A., Soetaredjo, F.E. (2013). Natural Zeolite from Pacitan Indonesia, as Catalyst Support for Transesterification of Palm Oil. Appl. Clay Sci., 74: 121-126
  3. Wang, Q., Gupta, N., Wen, G., Bee, S. (2017). Palladium and Carbon Synergistically Catalyzed Room-temperature Hydrodeoxygenation (HDO) of Vanillyl Alcohol-A Typical Lignin Model Molecule. J. Energy Chem., 26: 8-16
  4. de Sousa, F.P., Cardoso, C.C., Pasa, V.M.D. (2016). Producing Hydrocarbons for Green Diesel and Jet Fuel Formulation from Palm Kernel Fat over Pd/C. Fuel Process. Technol., 143: 35-42
  5. Veriansyah, B., Han, J.Y., Kim, S.K., Hong, S.A. (2012). Production of Renewable Diesel by Hydroprocessing of Soybean Oil: Effect of Catalysts. Fuel 94: 578-585
  6. Kaewmeesri, R., Srifa, A., Itthibenchapong, V., Faungnawakij, K. (2015). Deoxygenation of Waste Chicken Fats to Green Diesel over Ni/Al2O3: Effect of Water and Free Fatty Acid Content. Energ. Fuel. 29: 833-840
  7. Susanto, B.H., Nasikin, M., Wiyo, A. (2014). Synthesis of Renewable Diesel through Hydrodeoxygenation Using Pd/Zeolite Catalysts. Procedia Chem., 9: 139-150
  8. Soni, V.K., Sharma, P.R., Choudhary, G., Pandey, S., Sharma, R.K. (2017). Ni/Co-Natural Clay as Green Catalysts for Microalgae Oil to Diesel-Grade Hydrocarbons Conversion. ACS Sustain. Chem. Eng., 5(6): 5351-5359
  9. Wang, Z., Wang, L., Jiang, Y., Hunger, M. (2014). Cooperativity of Brønsted and Lewis Acid Sites on Zeolite for Glycerol Dehydration. ACS Catal., 4: 1144-1147
  10. Cubillas, P., Anderson, M.W., Strohmaier, K.G., Wright, P.A. (2011). Zeolites and Catalysis. Reactions, 50: 5425-5426
  11. Kandel, K., Anderegg, J.W., Nelson, N.C., Chaudhary, U. (2014). Supported Iron Nanoparticles for the Hydrodeoxygenation of Microalgal Oil to Green Diesel. J. Catal., 314: 142-148
  12. Zhou, H., Zhu, W., Shi, L., Liu, H. (2015). Promotion Effect of Fe in Mordenite Zeolite on Carbonylation of Dimethyl Ether to Methyl Acetate. Catal. Sci. Technol., 5: 1961-1968
  13. Calsavara, V., Luciano, M. (2008). Transformation of Ethanol into Hydrocarbons on ZSM-5 Zeolites Modified with Iron in Different Ways. Fuel. 87: 1628-1636
  14. Sriningsih, W., Saerodji, M.G., Trisunaryanti, W., Armunanto, R. (2014). Fuel Production from LDPE Plastic Waste over Natural Zeolite Supported Ni, Ni-Mo, Co, and Co-Mo Metals. Procedia Environ. Sci., 20: 215-224
  15. Nasser, G.A., Kurniawan, T., Tago, T, Bakare, I.A. (2015). Cracking of n-hexane over hierarchical MOR zeolites derived from natural minerals. J. Taiwan Inst. Chem. Eng. 61: 20-25
  16. Syamsiro, M., Saptoadi, H., Norsujianto, T., Noviasri, P. (2014). Fuel oil production from municipal plastic wastes in sequential pyrolysis and catalytic reforming reactors. Energy Procedia 47: 180-188
  17. Mudasir, M., Karelius, K., Aprilita, N.H., Wahyuni, E.T. (2016). Adsorption of mercury(II) on dithizone-immobilized natural zeolite. J. Environ. Chem. Eng. 4: 1839-1849
  18. Trisunaryanti, W., Syoufian, A., Purwono, S. (2013). Characterization and Modification of Indonesian Natural Zeolite for Hydrocracking of Waste Lubricant Oil into Liquid Fuel Fraction. J. Chem. Chem. Eng. 7: 175-180
  19. Trisunaryanti, W., Triwahyuni, E., Sudiono, S. (2005). Preparasi, Modifikasi dan Karakterisasi Katalis Ni-Mo/zeolit alam dan Mo-Ni/Zeolit alam. Teknoin, 10: 269-282
  20. Trisunaryanti, W., Triwahyuni, E., Sudiono, S. (2005). Preparation, Characterizations and Modification of Ni-Pd/Natural Zeolite Catalysts. Indo. J. Chem. 5: 48-53
  21. Trisunaryanti, W., Purwono, S., Putranto, A. (2008). Catalytic Hydrocracking of Waste Lubricant Oil into Liquid Fuel Fraction using ZnO, Nb2O5, Activated Natural Zeolite, and Their Modification. Indonesian Journal of Chemistry 8: 342-347
  22. Trisunaryanti, W, Rizki, C.N., Saptoadi, H., Syamsiro, M. (2013). Characteristics of Metal Supported-Zeolite Catalysts for Hydrocracking of Polyethylene Terephthalat. IOSR J. Appl. Chem. 3: 29-34
  23. Liu, J., He, J., Wang, L., Li, R. (2016). NiO-PTA Supported on ZIF-8 as a Highly Effective Catalyst for Hydrocracking of Jatropha Oil. Sci. Rep. 6: 23667
  24. Arean, C.O., Nachtigall, P., Thang, V., Bula, R. (2014). Measuring the Brønsted Acid Strength of Zeolites-Does It Correlate with the O–H Frequency Shift Probed by a Weak Base? Phys. Chem. Chem. Phys. 16: 10129-10141
  25. Sommer, J., Louis, B. (2004). Quantitative Determination of Brønsted Acid Sites on Zeolites: A New Approach towards the Chemical Composition of Zeolites. Catal. Letters. 93: 81-82
  26. Ko, Y.S., Jang, H.T., Ahn, W.S. (2008). Hydrothermal synthesis and characterization of Fe(III)-substituted mordenites. Korean J. Chem. Eng. 25: 1286-1291
  27. Deng, J., Liu, J., Song, W., Zhao, Z. (2017). Selective Catalytic Reduction of NO with NH3 over Mo-Fe/Beta Catalysts: The Effect of Mo Loading Amounts. RSC Adv. 7: 7130-7139
  28. Sazegar, M.R., Dadvand, A., Mahmoudi, A. (2017). Novel Protonated Fe-containing Mesoporous Silica Nanoparticle Catalyst: excellent performance cyclohexane oxidation. RSC Adv. 7: 27506-27514
  29. Mat, R., Amin, N.A.S. (2015). Fe/HY Zeolite as an Effective Catalyst for Levulinic Acid Production from Glucose: Characterization and Catalytic Performance. Appl. Catal. B Environ. 163: 487-498
  30. Kragović, M., Daković, A., Marković, M., Krstić, J. (2013). Characterization of Lead Sorption by the Natural and Fe(III)-modified Zeolite. Appl. Surf. Sci. 283: 764-774
  31. Rostamizadeh, M, Yaripour, F. (2016). Bifunctional and bimetallic Fe/ZSM-5 nanocatalysts for methanol to olefin reaction. Fuel 181: 537-546
  32. Zhou, L., Lawal, A. (2016). Hydrodeoxygenation of Microalgae Oil to Green Diesel over Pt, Rh and Presulfided NiMo Catalysts. Catal. Sci. Technol. 6: 1442-1454
  33. Huang, H.J., Yuan, X.Z., Zeng, G.M., Liu, Y. (2013). Thermochemical liquefaction of rice husk for bio-oil production with sub-and supercritical ethanol as solvent. J. Anal. Appl. Pyrolysis. 102: 60-67
  34. Zhao, X., Wei, L., Cheng, S., Huang, Y. (2015). Catalytic cracking of camelina oil for hydrocarbon biofuel over ZSM-5-Zn catalyst. Fuel Process. Technol. 139: 117-126
  35. Deliy, I.V., Vlasova, E.N., Nuzhdin, A.L., Gerasimov, E.Y. (2014). Hydrodeoxygenation of Methyl Palmitate over Sulfided Mo/Al2O3, CoMo/Al2O3 and NiMo/Al2O3 Catalysts. RSC Adv. 4: 2242-2250
  36. Xin, H., Guo, K., Li, D., Yang, H. (2016). Production of high-grade diesel from palmitic acid over activated carbon-supported nickel phosphide catalysts. Appl. Catal. B Environ. 187: 375-385
  37. Zhao, X., Wei, L., Cheng, S., Julson, J. (2017). Review of Heterogeneous Catalysts for Catalytically Upgrading Vegetable Oils into Hydrocarbon Biofuels. Catalysts. 7: 83
  38. Hong, Y., Wang, Y. (2017). Elucidation of reaction mechanism for m-cresol hydrodeoxygenation over Fe based catalysts: A kinetic study. Catal. Commun. 100: 43-47
  39. Duan, J., Han, J., Sun, H., Chen, P. (2012). Diesel-like Hydrocarbons Obtained by Direct Hydrodeoxygenation of Sunflower Oil over Pd/Al-SBA-15 Catalysts. Catal. Commun. 17: 76-80
  40. da Mota, S.D.P., Mancio, A.A., Lhamas, D.E.L., de Abreu, D.H. (2014). Production of Green Diesel by Thermal Catalytic Cracking of Crude Palm oil (Elaeis guineensis Jacq) in a Pilot Plant. J. Anal. Appl. Pyrolysis. 110: 1-11
  41. Huber, G.W., O’Connor, P., Corma, A. (2007). Processing Biomass in Conventional Oil Refineries: Production of High Quality Diesel by Hydrotreating Vegetable Oils in Heavy Vacuum Oil Mixtures. Appl. Catal. A Gen. 329: 120-129

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