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Photocatalytic Degradation of Malachite Green by Layered Double Hydroxide Based Composites

1Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang Prabumulih Km.32 Ogan Ilir 30662, Indonesia

2Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang Prabumulih Km.32 Ogan Ilir 30662, Indonesia

3Magister Programme Graduate School of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa No. 524 Ilir Barat 1, Palembang 30139, Indonesia

4 Doctoral Program, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Padang Selasa No. 524 Ilir Barat 1, Palembang 30139, Indonesia

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Received: 22 Jan 2022; Revised: 22 Feb 2022; Accepted: 22 Feb 2022; Available online: 2 Mar 2022; Published: 30 Jun 2022.
Editor(s): Istadi Istadi
Open Access Copyright (c) 2022 by Authors, Published by BCREC Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

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Abstract

Studies of LDH materials to be applied as photocatalyst for dye pollutant degradation have been developed. These interesting efforts are inseparable from the investigation of degradation performance and competitive synthetic methods. Composites based on Zn/Al and Mg/Al layered double hydroxides (LDHs) with ZnO and TiO2 were prepared by coprecipitation-impregnation method following by calcination at 300 °C to forms Zn/Al-ZnO, Mg/Al-ZnO, Zn/Al-TiO2, and Mg/Al-TiO2. Composites were characterized by XRD, FTIR, SEM and UV-DRS. Photodegradation of malachite green (MG) was carried out, after optimization of pH, catalyst loading and contact time in batch system under UV irradiation. XRD and spectroscopic data shows composites were successfully formed indicated by formation of both pristine materials. Degradation of malachite green showed that composites as photocatalyst have higher catalytic activity than pristine LDHs. LDH-ZnO composite have better activity, energy band gap and degradation reusability than LDH-TiO2. The Zn/Al-ZnO and Zn/Al-TiO2 composites degraded 97.1% and 96.3% MG, whereas the Mg/Al-ZnO and Mg/Al-TiO2 composites were able to degrade 99.8% and 98.6% MG, respectively. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

 

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Keywords: Malachite Green; Layered Double Hydroxide; Photocatalytic
Funding: Universitas Sriwijaya

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