Syngas Production from Catalytic CO2 Reforming of CH4 over CaFe2O4 Supported Ni and Co Catalysts: Full Factorial Design Screening

M. Anwar Hossain -  Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang Kuantan, Pahang, Malaysia
Bamidele Victor Ayodele -  Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang Kuantan, Pahang, Malaysia
Chin Kui Cheng -  1Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang Kuantan, Pahang, Malaysia 2Rare Earth Research Centre, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang Kuantan, Pahang 3Center of Excellence for Advanced Research in Fluid Flow, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang Kuantan, Pahang, Malaysia
*Maksudur R Khan -  1Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang Kuantan, Pahang, Malaysia 2Rare Earth Research Centre, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang Kuantan, Pahang, Malaysia
Received: 5 May 2017; Published: 2 Apr 2018.
Open Access Copyright (c) 2018 Bulletin of Chemical Reaction Engineering & Catalysis
Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Citation Format:
Cover Image
Article Info
Section: Original Research Articles
Language: EN
Full Text:
In 2018: BCREC Volume 13 Issue 1 Year 2018 (SCOPUS and Web of Science Indexed, April 2018)
Statistics: 2655 432

Abstract

In this study, the potential of dry reforming reaction over CaFe2O4 supported Ni and Co catalysts were investigated. The Co/CaFe2O4 and Ni/CaFe2O4 catalysts were synthesized using wet impregnation method by varying the metal loading from 5-15 %. The synthesized catalysts were tested in methane dry reforming reaction at atmospheric pressure and reaction temperature ranged 700-800 oC. The catalytic performance of the catalysts based on the initial screening is ranked as 5%Co/CaFe2O4 < 10%Co/CaFe2O4 < 5%Ni/CaFe2O4 < 10%Ni/CaFe2O4 according to their performance. The Ni/CaFe2O4 catalyst was selected for further investigation using full factorial design of experiment. The interaction effects of three factors namely metal loading (5-15 %), feed ratio (0.4-1.0), and reaction temperature (700-800 oC) were evaluated on the catalytic activity in terms of CH4 and CO2 conversion as well as H2 and CO yield. The interaction between the factors showed significant effects on the catalyst performance at metal loading, feed ratio and reaction temperature of 15 %, 1.0, and 800 oC. respectively. The 15 wt% Ni/CaFe2O4 was subsequently characterized by Thermogravimetric (TGA), X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray Spectroscopy (EDX), X-ray Photoelectron Spectroscopy (XPS), N2-physisorption, Temperature Programmed Desorption (TPD)-NH3, TPD-CO2, and Fourier Transform Infra Red (FTIR) to ascertain its physiochemical properties.  This study demonstrated that the CaFe2O4 supported Ni catalyst has a good potential to be used for syngas production via methane dry reforming. Copyright © 2018 BCREC Group. All rights reserved

Received: 5th May 2017; Revised: 8th August 2017; Accepted: 9th August 2017; Available online: 22nd January 2018; Published regularly: 2nd April 2018

How to Cite: Hossain, M.A., Ayodele, B.V., Cheng, C.K., Khan, M.R. (2018). Syngas Production from Catalytic CO2 Reforming of CH4 over CaFe2O4 Supported Ni and Co Catalysts: Full Factorial Design Screening. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (1): 57-74 (doi:10.9767/bcrec.13.1.1197.57-74)

 

Keywords
Cobalt; Nickel; CaFe2O4; Methane dry reforming; Syngas

Article Metrics:

  1. Anderson, T.R., Hawkins, E., Jones, P.D., (2016). CO2, the Greenhouse Effect and Global Warming : from the Pioneering Work of Arrhenius and Callendar to Today’s Earth System Models. Endeavour. 40(3): 178-187. doi:10.1016/j.endeavour.2016.07.002.
  2. Basha, M.N., Malik, A., Peedikakkal, P. (2016). Carbon Capture by Physical Adsorption : Materials, Experimental Investigations and Numerical Modeling and Simulation-A Review. Appl Energy, 161: 225-255.
  3. Ayodele, B.V., Khan, M.R., Cheng, C.K. (2016). Greenhouse Gases Mitigation by CO2 Reforming of Methane to Hydrogen-Rich Syngas Using Praseodymium Oxide Supported Cobalt Catalyst. Clean Technol. Environ, Policy, 19: 1-13.
  4. Ayodele, B.V., Khan, M.R., Cheng, C.K. (2017). Greenhouse Gases Abatement by Catalytic Dry Reforming of Methane to Syngas over Samarium Oxide-Supported Cobalt Catalyst. Int J Environ Sci Technol, 1-14. 14(12): 2769-2782
  5. Ayodele, B.V., Khan, M.R., Cheng, C.K. (2016). Production of CO-rich Hydrogen Gas from Methane Dry Reforming over Co/CeO2 Catalyst. Bull. Chem. React. Eng. Catal., 11: 210-219.
  6. Sidik, S.M., Triwahyono, S., Jalil, A.A., Majid, Z.A., Salamun, N., Talib, N.B. (2016). CO2 Reforming of CH4 over Ni-Co/MSN for Syngas Production: Role of Co as a Binder and Optimization Using RSM. Chem. Eng. J., 295: 1-10.
  7. Abatzoglou, N., Fauteux-lefebvre, C. (2016). Review of Catalytic Syngas Production Through Steam or Dry Reforming and Partial Oxidation of Studied Liquid Compounds. WIREs Energy Env. 5(2): 169-187
  8. Lee, J.H., You, Y-W., Ahn, H.C., Hong, J.S., Kim, S.B., Chang, T.S. (2014). The Deactivation Study of Co–Ru–Zr Catalyst Depending on Supports in the Dry Reforming of Carbon Dioxide. J. Ind. Eng. Chem., 20: 284-289.
  9. Ayodele, B.V., Cheng, C.K. (2015). Process Modelling, Thermodynamic Analysis and Optimization of Dry Reforming, Partial Oxidation and Auto-Thermal Methane Reforming for Hydrogen and Syngas Production. Chem. Prod. Process Model., 10: 211-220.
  10. Pakhare, D., Spivey, J. (2014). A Review of Dry (CO2) Reforming of Methane over Noble Metal Catalysts. Chem. Soc. Rev., 43(22): 7813-7837
  11. Budiman, A.W., Song, S.H., Chang, T.S., Choi, M.J. (2016). Preparation of a High Performance Cobalt Catalyst for CO2 Reforming of Methane. Adv. Powder Technol. 27(2): 584-590
  12. Luu, Q., Ha, M., Armbruster, U., Atia, H., Schneider, M., Lund, H. (2017). Development of Active and Stable Low Nickel Content Catalysts for Dry Reforming of Methane. Catalysts, 7: 1-17.
  13. Budiman, A.W., Song, S-H., Chang, T-S., Shin, C-H., Choi, M-J. (2012). Dry Reforming of Methane Over Cobalt Catalysts: A Literature Review of Catalyst Development. Catal. Surv. Asia, 16: 183-197.
  14. Itkulova, S.S., Zakumbaeva, G.D., Nurmakanov, Y.Y., Mukazhanova, A.A., Yermaganbetova, A.K. (2014). Syngas Production by Bireforming of Methane over Co-based Alumina-Supported Catalysts. Catal. Today, 228: 194-198.
  15. Ayodele, B.V., Khan, M.R., Cheng, C.K. (2015). Syngas Production from CO2 Reforming of Methane over Ceria Supported Cobalt Catalyst: Effects of Reactants Partial Pressure. J. Nat. Gas Sci. Eng. 27: 1016-1023
  16. Talkhoncheh, S.K., Haghighi, M. (2015). Syngas Production via Dry Reforming of Methane over Ni-Based Nanocatalyst over Various Supports of Clinoptilolite, Ceria and Alumina. J. Nat. Gas Sci. Eng., 23: 16-25.
  17. Zhang, Z., Wang, W. (2014). Solution Combustion Synthesis of CaFe2O4 Nanocrystal as A Magnetically Separable Photocatalyst. Mater. Lett., 133: 212-215.
  18. Xue, B., Luo, J., Zhang, F., Fang, Z. (2014). Biodiesel Production from Soybean and Jatropha Oils by Magnetic CaFe2O4-Ca2Fe2O5-based Catalyst. Energy, 68: 584-591.
  19. Laosiripojana, N., Sutthisripok, W., Assabumrungrat, S. (2005). Synthesis Gas Production From Dry Reforming of Methane over CeO2 Doped Ni/Al2O3: Influence of the Doping Ceria on the Resistance toward Carbon Formation. Chem. Eng. J., 112: 13-22.
  20. Verykios, X.E. (2003). Catalytic Dry Reforming of Natural Gas for the Production of Chemicals and Hydrogen. Int. J. Hydrogen Energy, 28: 1045-1063.
  21. Du, X., Zhang, D., Shi, L., Gao, R., Zhang, J. (2011). Morphology Dependence of Catalytic Properties of Ni/CeO2 Nanostructures for Carbon Dioxide Reforming of Methane. J. Phys. Chem. C, 116: 10009-10016.
  22. Sutthiumporn, K., Kawi, S. (2011). Promotional Effect of Alkaline Earth over Ni–La2O3 Catalyst for CO2 Reforming of CH4: Role of Surface Oxygen Species on H2 Production and Carbon Suppression. Int. J. Hydrogen Energy, 36: 14435-14446.
  23. Haag, S., Burgard, M., Ernst, B. (2007). Beneficial Effects of the Use of A Nickel Membrane Reactor for the Dry Reforming of Methane: Comparison with Thermodynamic Predictions. J. Catal., 252: 190-204.
  24. Brockner, W., Ehrhardt, C., Gjikaj, M. (2007). Thermal Decomposition of Nickel Nitrate Hexahydrate, Ni(NO3)2·6H2O, in Comparison to Co(NO3)2·6H2O and Ca(NO3)2·4H2O. Thermochim Acta, 456: 64-68.
  25. Ikenaga, N.O., Ohgaito, Y., Suzuki, T. (2005). H2S Absorption Behavior of Calcium Ferrite Prepared in the Presence of Coal. Energy and Fuels, 19: 170-179.
  26. Pino, L., Vita, A., Cipitì, F., Laganà, M., Recupero, V. (2011). Hydrogen Production by Methane Tri-reforming Process over Ni–ceria Catalysts: Effect of La-doping. Appl. Catal. B Environ., 104: 64-73.
  27. Pakhare, D., Spivey, J. (2014). A Review of Dry (CO2) Reforming of Methane over Noble Metal Catalysts. Chem. Soc. Rev. 43(22): 7813-7837
  28. Khanna, L., Verma, N.K. (2013). Synthesis, Characterization and in Vitro Cytotoxicity Study of Calcium Ferrite Nanoparticles. Mater. Sci. Semicond. Process., 16: 1842-1848.
  29. Šarić, A., Musić, S., Nomura, K., Popović, S. (1999). FT-IR and 57Fe Mössbauer Spectroscopic Investigation of Oxide Phases Precipitated from Fe(NO3)3 Solutions. J. Mol. Struct., 480-481: 633-636.
  30. Clark, T.C., Dove, J.E. (1973). Examination of Possible Non-Arrhenius Behavior in the reactions. Can. J. Chem., 51:2147-2154.
  31. Serrano-Lotina, A., Daza, L. (2014). Influence of the Operating Parameters over Dry Reforming of Methane to Syngas. Int. J. Hydrogen Energy, 39: 4089-4094.

Copyright (c) 2018 Bulletin of Chemical Reaction Engineering & Catalysis Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

As a journal Author, you have rights for a large range of uses of your article, including use by your employing institute or company. These Author rights can be exercised without the need to obtain specific permission. 

Authors publishing in BCREC journals have wide rights to use their works for teaching and scholarly purposes without needing to seek permission, including: use for classroom teaching by Author or Author's institutionand presentation at a meeting or conference and distributing copies to attendees; use for internal training by author's company; distribution to colleagues for their reseearch use; use in a subsequent compilation of the author's works; inclusion in a thesis or dissertation; reuse of portions or extrcats from the article in other works (with full acknowledgement of final article); preparation of derivative works (other than commercial purposes) (with full acknowledgement of final article); voluntary posting on open web sites operated by author or author’s institution for scholarly purposes (follow CC by SA License).

Authors and readers can copy and redistribute the material in any medium or format, as well as remix, transform, and build upon the material for any purpose, even commercially, but they must give appropriate credit (cite to the article or content), provide a link to the license, and indicate if changes were made. If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.

Copyright Transfer Agreement

The Authors submitting a manuscript do so on the understanding that if accepted for publication, copyright publishing of the article shall be assigned to Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University as publisher of the journal.

Copyright encompasses exclusive rights to reproduce and deliver the article in all form and media, including reprints, photographs, microfilms and any other similar reproductions, as well as translations. The reproduction of any part of this journal, its storage in databases and its transmission by any form or media, such as electronic, electrostatic and mechanical copies, photocopies, recordings, magnetic media, etc., will be allowed only with a written permission from Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University.

Bulletin of Chemical Reaction Engineering & Catalysis journal and Department of Chemical Engineering Diponegoro University, the Editors and the Advisory International Editorial Board make every effort to ensure that no wrong or misleading data, opinions or statements be published in the journal. In any way, the contents of the articles and advertisements published in the Bulletin of Chemical Reaction Engineering & Catalysis are sole and exclusive responsibility of their respective authors and advertisers.

Remember, even though we ask for a transfer of copyright, our journal authors retain (or are granted back) significant scholarly rights.

The Copyright Transfer Form can be downloaded here: [Copyright Transfer Form BCREC 2016] 


The copyright form should be signed originally and send to the Editorial Office in the form of original mail, scanned document or fax :  

Prof. Dr. I. Istadi (Editor-in-Chief)
Editorial Office of Bulletin of Chemical Reaction Engineering and Catalysis
Department of Chemical Engineering, Diponegoro University
Jl. Prof. Soedarto, Kampus Undip Tembalang, Semarang, Central Java, Indonesia 50275
Telp.: +62-24-7460058, Fax.: +62-24-76480675
E-mail: bcrec[at]live.undip.ac.id