DOI: https://doi.org/10.9767/bcrec.13.1.1197.57-73

Syngas Production from Catalytic CO2 Reforming of CH4 over CaFe2O4 Supported Ni and Co Catalysts: Full Factorial Design Screening

1Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang Kuantan, Pahang, Malaysia

2Rare Earth Research Centre, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang Kuantan, Pahang, Malaysia

3Center of Excellence for Advanced Research in Fluid Flow, Universiti Malaysia Pahang, Lebuhraya Tun Razak, 26300 Gambang Kuantan, Pahang, Malaysia

Received: 5 May 2017; Revised: 8 Aug 2017; Accepted: 9 Aug 2017; Available online: 22 Jan 2018; Published: 2 Apr 2018.
Editor(s): Y. H. Taufiq-Yap
Open Access Copyright (c) 2018 by Authors, Published by BCREC Group under http://creativecommons.org/licenses/by-sa/4.0.

Citation Format:
Cover Image
Abstract

In this study, the potential of dry reforming reaction over CaFe2O4 supported Ni and Co catalysts were investigated. The Co/CaFe2O4 and Ni/CaFe2O4 catalysts were synthesized using wet impregnation method by varying the metal loading from 5-15 %. The synthesized catalysts were tested in methane dry reforming reaction at atmospheric pressure and reaction temperature ranged 700-800 oC. The catalytic performance of the catalysts based on the initial screening is ranked as 5%Co/CaFe2O4 < 10%Co/CaFe2O4 < 5%Ni/CaFe2O4 < 10%Ni/CaFe2O4 according to their performance. The Ni/CaFe2O4 catalyst was selected for further investigation using full factorial design of experiment. The interaction effects of three factors namely metal loading (5-15 %), feed ratio (0.4-1.0), and reaction temperature (700-800 oC) were evaluated on the catalytic activity in terms of CH4 and CO2 conversion as well as H2 and CO yield. The interaction between the factors showed significant effects on the catalyst performance at metal loading, feed ratio and reaction temperature of 15 %, 1.0, and 800 oC. respectively. The 15 wt% Ni/CaFe2O4 was subsequently characterized by Thermogravimetric (TGA), X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray Spectroscopy (EDX), X-ray Photoelectron Spectroscopy (XPS), N2-physisorption, Temperature Programmed Desorption (TPD)-NH3, TPD-CO2, and Fourier Transform Infra Red (FTIR) to ascertain its physiochemical properties.  This study demonstrated that the CaFe2O4 supported Ni catalyst has a good potential to be used for syngas production via methane dry reforming. 

Fulltext View|Download
Keywords: Cobalt; Nickel; CaFe2O4; Methane dry reforming; Syngas
Funding: Ministry of Science, Technology and Innovation, Malaysia

Article Metrics:

Article Info
Section: Original Research Articles
Language : EN
Recent articles
Green Polymerization of Hexadecamethylcyclooctasiloxane Using an Algerian Proton Exchanged Clay Called Maghnite-H+ Syngas Production from Catalytic CO2 Reforming of CH4 over CaFe2O4 Supported Ni and Co Catalysts: Full Factorial Design Screening Methyl Violet Degradation Using Photocatalytic and Photoelectrocatalytic Processes Over Graphite/PbTiO3 Composite Cu2+ Montmorillonite K10 Clay Catalyst as a Green Catalyst for Production of Stearic Acid Methyl Ester: Optimization Using Response Surface Methodology (RSM) Comparison of Five Advanced Oxidation Processes for Degradation of Pesticide in Aqueous Solution CeO2-TiO2 Photocatalyst: Ionic Liquid-Mediated Synthesis, Characterization, and Performance for Diisopropanolamine Visible Light Degradation Frontmatter (Front Cover, Editorial Team, Indexing, and Table of Contents) Backmatter Author Guideline (2017) More recent articles
  1. Anderson, T.R., Hawkins, E., Jones, P.D., (2016). CO2, the Greenhouse Effect and Global Warming : from the Pioneering Work of Arrhenius and Callendar to Today’s Earth System Models. Endeavour. 40(3): 178-187. doi: 10.1016/j.endeavour.2016.07.002
  2. Basha, M.N., Malik, A., Peedikakkal, P. (2016). Carbon Capture by Physical Adsorption : Materials, Experimental Investigations and Numerical Modeling and Simulation-A Review. Appl Energy, 161: 225-255
  3. Ayodele, B.V., Khan, M.R., Cheng, C.K. (2016). Greenhouse Gases Mitigation by CO2 Reforming of Methane to Hydrogen-Rich Syngas Using Praseodymium Oxide Supported Cobalt Catalyst. Clean Technol. Environ, Policy, 19: 1-13
  4. Ayodele, B.V., Khan, M.R., Cheng, C.K. (2017). Greenhouse Gases Abatement by Catalytic Dry Reforming of Methane to Syngas over Samarium Oxide-Supported Cobalt Catalyst. Int J Environ Sci Technol, 1-14. 14(12): 2769-2782
  5. Ayodele, B.V., Khan, M.R., Cheng, C.K. (2016). Production of CO-rich Hydrogen Gas from Methane Dry Reforming over Co/CeO2 Catalyst. Bull. Chem. React. Eng. Catal., 11: 210-219
  6. Sidik, S.M., Triwahyono, S., Jalil, A.A., Majid, Z.A., Salamun, N., Talib, N.B. (2016). CO2 Reforming of CH4 over Ni-Co/MSN for Syngas Production: Role of Co as a Binder and Optimization Using RSM. Chem. Eng. J., 295: 1-10
  7. Abatzoglou, N., Fauteux-lefebvre, C. (2016). Review of Catalytic Syngas Production Through Steam or Dry Reforming and Partial Oxidation of Studied Liquid Compounds. WIREs Energy Env. 5(2): 169-187
  8. Lee, J.H., You, Y-W., Ahn, H.C., Hong, J.S., Kim, S.B., Chang, T.S. (2014). The Deactivation Study of Co–Ru–Zr Catalyst Depending on Supports in the Dry Reforming of Carbon Dioxide. J. Ind. Eng. Chem., 20: 284-289
  9. Ayodele, B.V., Cheng, C.K. (2015). Process Modelling, Thermodynamic Analysis and Optimization of Dry Reforming, Partial Oxidation and Auto-Thermal Methane Reforming for Hydrogen and Syngas Production. Chem. Prod. Process Model., 10: 211-220
  10. Pakhare, D., Spivey, J. (2014). A Review of Dry (CO2) Reforming of Methane over Noble Metal Catalysts. Chem. Soc. Rev., 43(22): 7813-7837
  11. Budiman, A.W., Song, S.H., Chang, T.S., Choi, M.J. (2016). Preparation of a High Performance Cobalt Catalyst for CO2 Reforming of Methane. Adv. Powder Technol. 27(2): 584-590
  12. Luu, Q., Ha, M., Armbruster, U., Atia, H., Schneider, M., Lund, H. (2017). Development of Active and Stable Low Nickel Content Catalysts for Dry Reforming of Methane. Catalysts, 7: 1-17
  13. Budiman, A.W., Song, S-H., Chang, T-S., Shin, C-H., Choi, M-J. (2012). Dry Reforming of Methane Over Cobalt Catalysts: A Literature Review of Catalyst Development. Catal. Surv. Asia, 16: 183-197
  14. Itkulova, S.S., Zakumbaeva, G.D., Nurmakanov, Y.Y., Mukazhanova, A.A., Yermaganbetova, A.K. (2014). Syngas Production by Bireforming of Methane over Co-based Alumina-Supported Catalysts. Catal. Today, 228: 194-198
  15. Ayodele, B.V., Khan, M.R., Cheng, C.K. (2015). Syngas Production from CO2 Reforming of Methane over Ceria Supported Cobalt Catalyst: Effects of Reactants Partial Pressure. J. Nat. Gas Sci. Eng. 27: 1016-1023
  16. Talkhoncheh, S.K., Haghighi, M. (2015). Syngas Production via Dry Reforming of Methane over Ni-Based Nanocatalyst over Various Supports of Clinoptilolite, Ceria and Alumina. J. Nat. Gas Sci. Eng., 23: 16-25
  17. Zhang, Z., Wang, W. (2014). Solution Combustion Synthesis of CaFe2O4 Nanocrystal as A Magnetically Separable Photocatalyst. Mater. Lett., 133: 212-215
  18. Xue, B., Luo, J., Zhang, F., Fang, Z. (2014). Biodiesel Production from Soybean and Jatropha Oils by Magnetic CaFe2O4-Ca2Fe2O5-based Catalyst. Energy, 68: 584-591
  19. Laosiripojana, N., Sutthisripok, W., Assabumrungrat, S. (2005). Synthesis Gas Production From Dry Reforming of Methane over CeO2 Doped Ni/Al2O3: Influence of the Doping Ceria on the Resistance toward Carbon Formation. Chem. Eng. J., 112: 13-22
  20. Verykios, X.E. (2003). Catalytic Dry Reforming of Natural Gas for the Production of Chemicals and Hydrogen. Int. J. Hydrogen Energy, 28: 1045-1063
  21. Du, X., Zhang, D., Shi, L., Gao, R., Zhang, J. (2011). Morphology Dependence of Catalytic Properties of Ni/CeO2 Nanostructures for Carbon Dioxide Reforming of Methane. J. Phys. Chem. C, 116: 10009-10016
  22. Sutthiumporn, K., Kawi, S. (2011). Promotional Effect of Alkaline Earth over Ni–La2O3 Catalyst for CO2 Reforming of CH4: Role of Surface Oxygen Species on H2 Production and Carbon Suppression. Int. J. Hydrogen Energy, 36: 14435-14446
  23. Haag, S., Burgard, M., Ernst, B. (2007). Beneficial Effects of the Use of A Nickel Membrane Reactor for the Dry Reforming of Methane: Comparison with Thermodynamic Predictions. J. Catal., 252: 190-204
  24. Brockner, W., Ehrhardt, C., Gjikaj, M. (2007). Thermal Decomposition of Nickel Nitrate Hexahydrate, Ni(NO3)2·6H2O, in Comparison to Co(NO3)2·6H2O and Ca(NO3)2·4H2O. Thermochim Acta, 456: 64-68
  25. Ikenaga, N.O., Ohgaito, Y., Suzuki, T. (2005). H2S Absorption Behavior of Calcium Ferrite Prepared in the Presence of Coal. Energy and Fuels, 19: 170-179
  26. Pino, L., Vita, A., Cipitì, F., Laganà, M., Recupero, V. (2011). Hydrogen Production by Methane Tri-reforming Process over Ni–ceria Catalysts: Effect of La-doping. Appl. Catal. B Environ., 104: 64-73
  27. Pakhare, D., Spivey, J. (2014). A Review of Dry (CO2) Reforming of Methane over Noble Metal Catalysts. Chem. Soc. Rev. 43(22): 7813-7837
  28. Khanna, L., Verma, N.K. (2013). Synthesis, Characterization and in Vitro Cytotoxicity Study of Calcium Ferrite Nanoparticles. Mater. Sci. Semicond. Process., 16: 1842-1848
  29. Šarić, A., Musić, S., Nomura, K., Popović, S. (1999). FT-IR and 57Fe Mössbauer Spectroscopic Investigation of Oxide Phases Precipitated from Fe(NO3)3 Solutions. J. Mol. Struct., 480-481: 633-636
  30. Clark, T.C., Dove, J.E. (1973). Examination of Possible Non-Arrhenius Behavior in the reactions. Can. J. Chem., 51:2147-2154
  31. Serrano-Lotina, A., Daza, L. (2014). Influence of the Operating Parameters over Dry Reforming of Methane to Syngas. Int. J. Hydrogen Energy, 39: 4089-4094

Last update:

No citation recorded.

Last update:

No citation recorded.