Synthesis and Evaluation of ABO3 Perovskites (A=La and B=Mn, Co) with Stoichiometric and Over-stoichiometric Ratios of B/A for Catalytic Oxidation of Trichloroethylene

DOI: https://doi.org/10.9767/bcrec.13.1.1188.47-56
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Submitted: 28-04-2017
Published: 02-04-2018
Section: Original Research Articles
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In this contribution, perovskite catalysts (ABO3) were probed that site A and site B were occupied by lanthanum and transition metals of manganese or cobalt, respectively, with stoichiometric ratios as well as 20 % over-stoichiometric ratios of B/A. The perovskite samples were synthesized using a gel-combustion method and characterized by BET, XRD, SEM and O2-TPD analyses. After mounting in a fixed bed reactor, the catalysts were examined in atmospheric pressure conditions at different temperatures for oxidation of 1000 ppm trichloroethylene in the air. Evaluation of over-stoichiometric catalysts activity showed that the increased ratio of B/A in the catalysts compared to the stoichiometric one led to BET surface area, oxygen mobility, and consequently catalytic performance improvement. The lanthanum manganite perovskite with 20 % excess manganese yielded the best catalytic performance among the probed perovskites. Copyright © 2018 BCREC Group. All rights reserved

Received: 28th April 2017; Revised: 31st July 2017; Accepted: 4th August 2017; Available online: 22nd January 2018; Published regularly: 2nd April 2018

How to Cite: Alagheband, R., Maghsoodi, S., Kootenaei, A.S., Kianmanesh, H. (2018). Synthesis and Evaluation of ABO3 Perovskites (A=La and B=Mn, Co) with Stoichiometric and Over-stoichiometric Ratios of B/A for Catalytic Oxidation of Trichloroethylene. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (1): 47-56 (doi:10.9767/bcrec.13.1.1188.47-56)

 

Keywords

Oxidation; Volatile Organic Compound; Perovskite; Gel-combustion; Catalyst

  1. Razieh Alagheband 
    Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran, Islamic Republic of
  2. Sarah Maghsoodi 
    Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran, Islamic Republic of
  3. Amirhossein Shahbazi Kootenaei 
    Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran, Islamic Republic of
  4. Hassan Kianmanesh 
    Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran, Islamic Republic of
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