Crystal Structure and Catalytic Activity of A Novel Cd(II) Coordination Polymer Formed by Dicarboxylic Ligand

*Zhi Xiang Ji -  College of Information and Engineering, Weifang University, Weifang 261061, China
Peng Fei Li -  College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China
Received: 25 Apr 2017; Published: 11 Jun 2018.
Open Access Copyright (c) 2018 Bulletin of Chemical Reaction Engineering & Catalysis
Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

A new Cd(II) coordination polymer, {[Cd3(L)2(DMF)2(H2O)2]·H2O}n (H2L = 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid) was synthesized by one-pot synthesis method from 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid, NaOH, DMF, and Cd(NO3)2·4H2O. Its structure was determined by elemental analysis and single crystal X-ray diffraction. Structural analysis shows that three Cd(II) ions are all six-coordinated with four oxygen atoms of four 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylate ligands and two O atoms from two DMF molecules (Cd1) or two oxygen atoms of two coordinated H2O molecules (Cd2 and Cd3) to form an octahedral coordination geometry. The Cd(II) coordination polymer displays a 1D chained structure by the bridging carboxylate groups from 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylate ligands. The conversion of benzaldehyde is 90.9%, which is 40~50% higher than those of the other three aldehydes (4-methylbenzaldehyde, p-methoxybenzaldehyde and 3-chlorobenzaldehyde), so the Cd(II) coordination polymer catalyst shows better catalytic activity for the coupling reaction of benzaldehyde, phenylacetylene, and piperidine than the other three aldehydes. Copyright © 2018 BCREC Group. All rights reserved

Received: 25th April 2017; Revised: 11st September 2017; Accepted: 1st November 2017; Available online: 11st June 2018; Published regularly: 1st August 2018

How to Cite: Ji, Z.X., Li, P.F. (2018). Crystal Structure and Catalytic Activity of A Novel Cd(II) Coordination Polymer Formed by Dicarboxylic Ligand. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (2): 220-226 (doi:10.9767/bcrec.13.2.1178.220-226)


Other format:

1,3-Bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid; Cd(II) coordination polymer; Synthesis; Structural characterization; Catalytic property
Cover Image

Article Metrics:

  1. Yaghi, O.M. (2016). Reticular Chemistry-construction, Properties, and Precision Reactions of Frameworks. Journal of the American Chemical Society, 138: 15507-15509.
  2. Yan, K.K., Fujita, M. (2015). A Speedy Marriage in Supramolecular Catalysis. Science, 350: 1165-1166.
  3. Zhang, Y.B., Liu, Q., Jing, H.R., Cai, Y.J., Wang, Q., Li, Y.G. (2017). Synthesis, Characterization, and Antimicrobial Activity of Two Schiff Base Silver(I) Complexes Derived from 4-Carboxybenzaldehyde. Journal of Coordination Chemistry, 70: 1066-1076.
  4. Majumdar, D., Babu, M.S.S., Das, S., Biswas, J.K., Mondal, M., Hazra, S. (2017). Synthesis, X-ray Crystal Structure, Photoluminescent Property, Antimicrobial Activities and DFT Computational Study of Zn(II) Coordination Polymer Derived from Multisite N,O Donor Schiff base Ligand (H2L1). Journal of Molecular Structure, 1138: 161-171.
  5. Tai, X.S., Zhao, W.H. (2013). Synthesis, Crystal Structure and Antitumor Activity of Ca(II) Coordination Polymer Based on 1,5-Naphthalenedisulfonate. Journal of Inorganic and Organometallic Polymers and Materials, 23: 1354-1357.
  6. Wang, X.P., Han, L.L., Lin, S.J., Li, X.Y., Mei, K., Sun, D. (2016). Synthesis, Structure and Photoluminescence of Three 2D Cd(II) Coordination Polymers Based on Varied Dicarboxylate Ligand. Journal of Coordination Chemistry, 69: 286-294.
  7. Nawrot, I., Czerwińska, K., Machura, B., Kruszynski, R. (2017). Synthesis, Structural Diversity and Luminescent Properties of Cadmium(II) Coordination Assemblies with 2-(2-Aminophenyl)-1H-benzimidazole and Pseudohalide Ions. Journal of Luminescence, 181: 103-113.
  8. LaRose, C.J., LaDuca, R.L. (2017). Luminescent Cadmium 1,3-Adamantanedicarboxylate Coordination Polymers with Diverse Topologies Depending on Dipyridylamide Ligands. Inorganica Chimica Acta, 461: 92-101.
  9. He, Y.C., Xu, N., Zheng, X.F., Yu, Y., Ling, B.P., You, J.M. (2017). A Silver(I) Coordination Polymer Luminescent Thermometer. Dyes Pigments, 136: 577-582.
  10. Bagherzadeh, M., Ashouri, F., Đaković, M. (2014). Synthesis, Structural Characterization and Application of a 2D Coordination Polymer of Mn-terephthalate as a Heterogeneous Catalyst for Olefin Oxidation. Polyhedron, 69: 167-173.
  11. Wang, L.H., Liang, L., Wang, X. (2017). Synthesis, Structural Characterization and Catalytic Activity of A Cu(II) Coordination Polymer Constructed From 1,4-Phenylenediacetic Acid and 2,2’-Bipyridine. Bulletin of Chemical Reaction Engineering & Catalysis, 12(1): 113-118.
  12. Farzaneh, F., Moghzi, F., Rashtizadeh, E. (2016). Zn(II) Coordination Polymer as a Bifunctional Catalyst for Biodiesel Production from Soybean Oil. Reaction Kinetics Mechanisms and Catalysis, 118: 509-521.
  13. Cao, X.Y., Yang, D.D., Li, N., Huang, R.D. (2015). Ligands Effect on the Structures of a Series of Coordination Polymers: Syntheses, Structures, Luminescence and Magnetism. Inorganica Chimica Acta, 427: 285-292.
  14. Sharif, S., Şahin, O., Khan, B., Khan, I.U. (2015). Hydrothermal Synthesis, Structural Investigation, and Magnetic Properties of 2-D Layered Lanthanide (Ln = Pr, Eu, Gd, Tb, and Er) Coordination Polymers Possessing Infinite 1-D Nanosized Cavities. Journal of Coordination Chemistry, 68: 2725-2738.
  15. Liu, Y.L., Chen, F.Y., Di, Y.Q., Cao, J., Di, Y.Y., Zhou, C.S. (2016). Two Coordination Polymers Based on a Flexible Tritopic Pyridyldicarboxylate Ligand: Structures and Magnetic Properties. Zeitschrift fur Anorganische und Allgemeine Chemie, 642: 246-249.
  16. Ma, D.Y., Hu, P., Qin, L., Yan, J.J., Lin, W.J., Ding, W.Q., Lu, H.S., Lin, D.T., Sakiyama, H., Liang, F.L. (2016). Synthesis, Characterization, and Magnetic Properties of Two Transition Metal Coordination Polymers Based on 2,5-Furandicarboxylic Acid and N-donor Ligands. Journal of Inorganic and Organometallic Polymers and Materials, 26: 1053-1060.
  17. Liu, L., Zhang, G.M., Zhu, R.G., Liu, Y.H., Yao, H.M., Han, Z.B. (2014). Dinuclear Cd(II), Mn(II) and Cu(II) Complexes Derived from (Anthraquinone-1-diyl) benzoate: DNA Binding and Cleavage Studies. RSC Advances, 4: 46639-46645.
  18. Lu, J., Sun, Q., Li, J.L., Gu, W., Tian, J.L., Liu, X., Yan, S.P. (2013). Synthesis, Characterization, and DNA-binding of Two New Cd(II) Complexes with 8-[(2-Pyridylmethyl)amino]-quinoline. Journal of Coordination Chemistry, 66: 3280-3290.
  19. Shen, J.J., Li, M.X., Wang, Z.X., Duan, C.Y., Zhu, S.R., He, X.S. (2014). Unexpected 4-Fold [2+2] Interpenetration and Polycatenation Behaviors in Porous Luminescent Zinc Metal-organic Frameworks Constructed from Flexible 3,5-Bis(4-pyridylmethoxy)benzoate Ligand. Crystal Growth & Design, 14: 2818-2830.
  20. Yoon, M.Y., Moon, D.H. (2015). New Zr(IV) Based Metal-organic Framework Comprising a Sulfur-containing Ligand: Enhancement of CO2 and H2 Storage Capacity. Microporous and Mesoporous Materials, 215: 116-122.
  21. Meundaeng, N., Rujiwatra, A., Prior, T.J. (2017). Copper Coordination Polymers Constructed from Thiazole-5-carboxylic Acid: Synthesis, Crystal Structures, and Structural Transformation. Journal of Solid State Chemistry, 245: 138-145.
  22. Chakraborty, P., Mohanta, S. (2017). Syntheses, Crystal Structures, Lone Pair Functionality and Electrospray Ionization Mass Spectral Properties of Trinuclear, Dimer of Trinuclear and Trinuclear-based One-dimensional Systems of Copper(II) and Lead(II). Inorganica Chimica Acta, 455: 70-80.
  23. Mukherjee, G., Biradha, K. (2014). Topological Equivalences Between Coordination Polymer and Cocrystal: A Tecton Approach in Crystal Engineering. Crystal Growth & Design, 14: 419-422.
  24. Li, T., Huang, X.H., Zhao, Y.F., Li, H.H., Wu, S.T., Huang, C.C. (2012). An Unusual Double T5(2) Water Tape Trapped in Silver(I) Coordination Polymer Hosts: Influence of the Solvent on the Assembly of Ag(I)-4,4’-bipyridine Chains with Trans-cyclohexanedicarboxylate and Their Luminescent Properties. Dalton Transactions, 41: 12872-12881.
  25. Liu, C.B., Li, Q., Wang, X., Che, G.B., Zhang, X.J. (2014). A Series of Lanthanide(III) Coordination Polymers Derived via in Situ Hydrothermal Decarboxylation of Quinoline-2,3-dicarboxylic Acid. Inorganic Chemistry Communications, 39: 56-60.
  26. Xu, B., Zhang, T., Zhang, L., Li, C.C. (2014). Structures and Properties of Coordination Polymers Based on 5-Nitroisophthalic Acid and N,N′-Bis(4-pyridyl-methyl)piperazine. Zeitschrift fur Anorganische und Allgemeine Chemie, 640: 2503-2507.
  27. Ashiry, K.O., Zhao, Y.H., Shao, K.Z., Su, Z.M., Xu, G.J. (2009). Syntheses and Characterizations of Three Coordination Polymers Based on Dipyridylbenzoates and 1,4-Bezenedicarboxylate. Polyhedron, 28: 975-979.
  28. Tai, X.S., Zhao, W.H. (2015). Synthesis, Crystal Structure, and Antibacterial Activity of Magnesium(II) Coordination Polymers Formed by Hydrogen Bonding. Research on Chemical Intermediates, 41: 3471-3478.
  29. Tai, X.S., Wang, X. (2017). Synthesis, Structural Characterization and Antitumor Activity of a Ca(II) Coordination Polymer Based on 4-Formyl-1,3-benzenedisulfonate-2-furoic Acid Hydrazide Ligands. Crystallography Reports, 62: 242-245.
  30. Sheldrick, G.M. (2008). A Short History of SHELX. Acta Crystallographica, A64: 112-122