Crystal Structure and Catalytic Activity of A Novel Cd(II) Coordination Polymer Formed by Dicarboxylic Ligand

DOI: https://doi.org/10.9767/bcrec.13.2.1178.220-226
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Submitted: 25-04-2017
Published: 11-06-2018
Section: Original Research Articles
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A new Cd(II) coordination polymer, {[Cd3(L)2(DMF)2(H2O)2]·H2O}n (H2L = 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid) was synthesized by one-pot synthesis method from 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid, NaOH, DMF, and Cd(NO3)2·4H2O. Its structure was determined by elemental analysis and single crystal X-ray diffraction. Structural analysis shows that three Cd(II) ions are all six-coordinated with four oxygen atoms of four 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylate ligands and two O atoms from two DMF molecules (Cd1) or two oxygen atoms of two coordinated H2O molecules (Cd2 and Cd3) to form an octahedral coordination geometry. The Cd(II) coordination polymer displays a 1D chained structure by the bridging carboxylate groups from 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylate ligands. The conversion of benzaldehyde is 90.9%, which is 40~50% higher than those of the other three aldehydes (4-methylbenzaldehyde, p-methoxybenzaldehyde and 3-chlorobenzaldehyde), so the Cd(II) coordination polymer catalyst shows better catalytic activity for the coupling reaction of benzaldehyde, phenylacetylene, and piperidine than the other three aldehydes. Copyright © 2018 BCREC Group. All rights reserved

Received: 25th April 2017; Revised: 11st September 2017; Accepted: 1st November 2017; Available online: 11st June 2018; Published regularly: 1st August 2018

How to Cite: Ji, Z.X., Li, P.F. (2018). Crystal Structure and Catalytic Activity of A Novel Cd(II) Coordination Polymer Formed by Dicarboxylic Ligand. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (2): 220-226 (doi:10.9767/bcrec.13.2.1178.220-226)

 

Keywords

1,3-Bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid; Cd(II) coordination polymer; Synthesis; Structural characterization; Catalytic property

  1. Zhi Xiang Ji 
    College of Information and Engineering, Weifang University, Weifang 261061, China
  2. Peng Fei Li 
    College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China
  1. Yaghi, O.M. (2016). Reticular Chemistry-construction, Properties, and Precision Reactions of Frameworks. Journal of the American Chemical Society, 138: 15507-15509.
  2. Yan, K.K., Fujita, M. (2015). A Speedy Marriage in Supramolecular Catalysis. Science, 350: 1165-1166.
  3. Zhang, Y.B., Liu, Q., Jing, H.R., Cai, Y.J., Wang, Q., Li, Y.G. (2017). Synthesis, Characterization, and Antimicrobial Activity of Two Schiff Base Silver(I) Complexes Derived from 4-Carboxybenzaldehyde. Journal of Coordination Chemistry, 70: 1066-1076.
  4. Majumdar, D., Babu, M.S.S., Das, S., Biswas, J.K., Mondal, M., Hazra, S. (2017). Synthesis, X-ray Crystal Structure, Photoluminescent Property, Antimicrobial Activities and DFT Computational Study of Zn(II) Coordination Polymer Derived from Multisite N,O Donor Schiff base Ligand (H2L1). Journal of Molecular Structure, 1138: 161-171.
  5. Tai, X.S., Zhao, W.H. (2013). Synthesis, Crystal Structure and Antitumor Activity of Ca(II) Coordination Polymer Based on 1,5-Naphthalenedisulfonate. Journal of Inorganic and Organometallic Polymers and Materials, 23: 1354-1357.
  6. Wang, X.P., Han, L.L., Lin, S.J., Li, X.Y., Mei, K., Sun, D. (2016). Synthesis, Structure and Photoluminescence of Three 2D Cd(II) Coordination Polymers Based on Varied Dicarboxylate Ligand. Journal of Coordination Chemistry, 69: 286-294.
  7. Nawrot, I., Czerwińska, K., Machura, B., Kruszynski, R. (2017). Synthesis, Structural Diversity and Luminescent Properties of Cadmium(II) Coordination Assemblies with 2-(2-Aminophenyl)-1H-benzimidazole and Pseudohalide Ions. Journal of Luminescence, 181: 103-113.
  8. LaRose, C.J., LaDuca, R.L. (2017). Luminescent Cadmium 1,3-Adamantanedicarboxylate Coordination Polymers with Diverse Topologies Depending on Dipyridylamide Ligands. Inorganica Chimica Acta, 461: 92-101.
  9. He, Y.C., Xu, N., Zheng, X.F., Yu, Y., Ling, B.P., You, J.M. (2017). A Silver(I) Coordination Polymer Luminescent Thermometer. Dyes Pigments, 136: 577-582.
  10. Bagherzadeh, M., Ashouri, F., Đaković, M. (2014). Synthesis, Structural Characterization and Application of a 2D Coordination Polymer of Mn-terephthalate as a Heterogeneous Catalyst for Olefin Oxidation. Polyhedron, 69: 167-173.
  11. Wang, L.H., Liang, L., Wang, X. (2017). Synthesis, Structural Characterization and Catalytic Activity of A Cu(II) Coordination Polymer Constructed From 1,4-Phenylenediacetic Acid and 2,2’-Bipyridine. Bulletin of Chemical Reaction Engineering & Catalysis, 12(1): 113-118.
  12. Farzaneh, F., Moghzi, F., Rashtizadeh, E. (2016). Zn(II) Coordination Polymer as a Bifunctional Catalyst for Biodiesel Production from Soybean Oil. Reaction Kinetics Mechanisms and Catalysis, 118: 509-521.
  13. Cao, X.Y., Yang, D.D., Li, N., Huang, R.D. (2015). Ligands Effect on the Structures of a Series of Coordination Polymers: Syntheses, Structures, Luminescence and Magnetism. Inorganica Chimica Acta, 427: 285-292.
  14. Sharif, S., Şahin, O., Khan, B., Khan, I.U. (2015). Hydrothermal Synthesis, Structural Investigation, and Magnetic Properties of 2-D Layered Lanthanide (Ln = Pr, Eu, Gd, Tb, and Er) Coordination Polymers Possessing Infinite 1-D Nanosized Cavities. Journal of Coordination Chemistry, 68: 2725-2738.
  15. Liu, Y.L., Chen, F.Y., Di, Y.Q., Cao, J., Di, Y.Y., Zhou, C.S. (2016). Two Coordination Polymers Based on a Flexible Tritopic Pyridyldicarboxylate Ligand: Structures and Magnetic Properties. Zeitschrift fur Anorganische und Allgemeine Chemie, 642: 246-249.
  16. Ma, D.Y., Hu, P., Qin, L., Yan, J.J., Lin, W.J., Ding, W.Q., Lu, H.S., Lin, D.T., Sakiyama, H., Liang, F.L. (2016). Synthesis, Characterization, and Magnetic Properties of Two Transition Metal Coordination Polymers Based on 2,5-Furandicarboxylic Acid and N-donor Ligands. Journal of Inorganic and Organometallic Polymers and Materials, 26: 1053-1060.
  17. Liu, L., Zhang, G.M., Zhu, R.G., Liu, Y.H., Yao, H.M., Han, Z.B. (2014). Dinuclear Cd(II), Mn(II) and Cu(II) Complexes Derived from (Anthraquinone-1-diyl) benzoate: DNA Binding and Cleavage Studies. RSC Advances, 4: 46639-46645.
  18. Lu, J., Sun, Q., Li, J.L., Gu, W., Tian, J.L., Liu, X., Yan, S.P. (2013). Synthesis, Characterization, and DNA-binding of Two New Cd(II) Complexes with 8-[(2-Pyridylmethyl)amino]-quinoline. Journal of Coordination Chemistry, 66: 3280-3290.
  19. Shen, J.J., Li, M.X., Wang, Z.X., Duan, C.Y., Zhu, S.R., He, X.S. (2014). Unexpected 4-Fold [2+2] Interpenetration and Polycatenation Behaviors in Porous Luminescent Zinc Metal-organic Frameworks Constructed from Flexible 3,5-Bis(4-pyridylmethoxy)benzoate Ligand. Crystal Growth & Design, 14: 2818-2830.
  20. Yoon, M.Y., Moon, D.H. (2015). New Zr(IV) Based Metal-organic Framework Comprising a Sulfur-containing Ligand: Enhancement of CO2 and H2 Storage Capacity. Microporous and Mesoporous Materials, 215: 116-122.
  21. Meundaeng, N., Rujiwatra, A., Prior, T.J. (2017). Copper Coordination Polymers Constructed from Thiazole-5-carboxylic Acid: Synthesis, Crystal Structures, and Structural Transformation. Journal of Solid State Chemistry, 245: 138-145.
  22. Chakraborty, P., Mohanta, S. (2017). Syntheses, Crystal Structures, Lone Pair Functionality and Electrospray Ionization Mass Spectral Properties of Trinuclear, Dimer of Trinuclear and Trinuclear-based One-dimensional Systems of Copper(II) and Lead(II). Inorganica Chimica Acta, 455: 70-80.
  23. Mukherjee, G., Biradha, K. (2014). Topological Equivalences Between Coordination Polymer and Cocrystal: A Tecton Approach in Crystal Engineering. Crystal Growth & Design, 14: 419-422.
  24. Li, T., Huang, X.H., Zhao, Y.F., Li, H.H., Wu, S.T., Huang, C.C. (2012). An Unusual Double T5(2) Water Tape Trapped in Silver(I) Coordination Polymer Hosts: Influence of the Solvent on the Assembly of Ag(I)-4,4’-bipyridine Chains with Trans-cyclohexanedicarboxylate and Their Luminescent Properties. Dalton Transactions, 41: 12872-12881.
  25. Liu, C.B., Li, Q., Wang, X., Che, G.B., Zhang, X.J. (2014). A Series of Lanthanide(III) Coordination Polymers Derived via in Situ Hydrothermal Decarboxylation of Quinoline-2,3-dicarboxylic Acid. Inorganic Chemistry Communications, 39: 56-60.
  26. Xu, B., Zhang, T., Zhang, L., Li, C.C. (2014). Structures and Properties of Coordination Polymers Based on 5-Nitroisophthalic Acid and N,N′-Bis(4-pyridyl-methyl)piperazine. Zeitschrift fur Anorganische und Allgemeine Chemie, 640: 2503-2507.
  27. Ashiry, K.O., Zhao, Y.H., Shao, K.Z., Su, Z.M., Xu, G.J. (2009). Syntheses and Characterizations of Three Coordination Polymers Based on Dipyridylbenzoates and 1,4-Bezenedicarboxylate. Polyhedron, 28: 975-979.
  28. Tai, X.S., Zhao, W.H. (2015). Synthesis, Crystal Structure, and Antibacterial Activity of Magnesium(II) Coordination Polymers Formed by Hydrogen Bonding. Research on Chemical Intermediates, 41: 3471-3478.
  29. Tai, X.S., Wang, X. (2017). Synthesis, Structural Characterization and Antitumor Activity of a Ca(II) Coordination Polymer Based on 4-Formyl-1,3-benzenedisulfonate-2-furoic Acid Hydrazide Ligands. Crystallography Reports, 62: 242-245.
  30. Sheldrick, G.M. (2008). A Short History of SHELX. Acta Crystallographica, A64: 112-122