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Cellulose and TiO2–ZrO2 Nanocomposite as a Catalyst for Glucose Conversion to 5-EMF

Fitriyah Wulan Diniscopus Helmiyati Helmiyati scopus Yuni K. Krisnandiorcid scopus

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok 16424, West Java, Indonesia

Received: 8 Feb 2021; Revised: 15 Apr 2021; Accepted: 16 Apr 2021; Published: 30 Jun 2021; Available online: 18 Apr 2021.
Open Access Copyright (c) 2021 by Authors, Published by BCREC Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

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Abstract

This work demonstrated the use of green material catalysts, produced from Sengon sawdust waste, to obtain nanocellulose biopolymers. The green material catalysts were utilized as catalysts support of TiO2−ZrO2 binary oxide in the form of nanocomposite materials with superior synergistic properties. The isolation of nanocellulose was achieved using a hydrolysis method with a yield of 63.40%. The TiO2 and ZrO2 nanoparticles have average particle sizes of around 25 and 15 nm, respectively, and the binary oxides of TiO2–ZrO2 pretained an average particle size of 30 nm were used. Furthermore, the nanocellulose combined with the TiO2−ZrO2 binary oxide had formed a cellulose/TiO2−ZrO2 nanocomposite with an average particle size of 30 nm. This indicates that the supporting nanocellulose can stabilize the nanoparticles and avoid aggregation. Moreover, the nanocomposites can be used as a catalyst for the conversion of glucose to 5-ethoxymethylfurfural (5-EMF). The catalytic activity increased with the nanoparticle effect obtained ZrO2, TiO2, TiO2-ZrO2, and cellulose and TiO2-ZrO2 nanocomposite, in 15.50%, 20.20%, 35.20%, and 45.50% yields, respectively. The best yield of 5-EMF was 45.50%, with reaction conditions of 1:1 TiO2–ZrO2 ratio, 4 h reaction time, and 160 °C reaction temperature. The use of nanocellulose biopolymer generated from Sengon sawdust waste in Indonesia provides a promising catalyst support material as an alternative green catalyst. In addition, the glucose carbohydrates can be converted to biofuel feedstocks in the development of a renewable alternative energy. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

 

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Keywords: Catalyst; Glucose; Nanocellulose; Nanocomposite; 5-ethoxymethylfurfural
Funding: Ministry of Research and Technology/National Research and Innovation under contract PDUPT Grant No. NKB-170/UN2.RST/ HKP.05.00/2021

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Section: The 3rd International Conference on Chemistry, Chemical Process and Engineering 2020) (IC3PE 2020)
Language : EN
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