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Hydrogen Desorption Properties of MgH2 + 10 wt% SiO2 + 5 wt% Ni Prepared by Planetary Ball Milling

Malahayati Malahayati1, 2, 3scopus Evi Yufita2, 3scopus Ismail Ismail2, 3scopus Mursal Mursal2, 3scopus Rinaldi Idroes4orcid scopus Zulkarnain Jalil2, 3 scopus

1Graduate School of Mathematics and Applied Sciences, Syiah Kuala University, Banda Aceh 23111, Indonesia., Indonesia

2Department of Physics, Faculty of Mathematics and Natural Sciences, Syiah Kuala University,, Indonesia

3Banda Aceh 23111, Indonesia

4 Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Syiah Kuala University, Banda Aceh 23111, Indonesia

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Received: 28 Jan 2021; Revised: 30 Apr 2021; Accepted: 30 Apr 2021; Published: 30 Jun 2021; Available online: 2 May 2021.
Open Access Copyright (c) 2021 by Authors, Published by BCREC Group
Creative Commons License This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

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MgH2 is a very hopeful material for application as hydrogen storage material in the solid form. This is due to its reversibility and its ability to store large amounts of hydrogen, which is 7.6 wt%. However, this material still has weaknesses, namely high operating temperature and slow kinetic reactions. Various attempts have been made to overcome this weakness, including downsizing and adding catalyst. In this study, double catalyst was used, namely natural silica extracted from rice husk ash and nickel nano powder, with a composition of MgH2 + 10 wt% SiO2 + 5 wt% Ni. The purpose of this research was to study the effect of downsizing and using these catalysts to the thermodynamic and kinetic properties of the hydrogen storage material MgH2. Samples were prepared by using High Energy Ball Milling (HEBM), with variations in milling time of 1, 5, 10, and 15 hours. The X-ray Diffraction (XRD) pattern showed the presence of an impurity phase in the samples milled for 10 and 15 hours. It also showed a reduction in grain size with increasing milling time. However, agglomeration has occurred in the samples milled for 15 hours. From the Scanning Electron Microscope (SEM) results can be seen that the sample with longer milling time, were homogeneously distribute. Thermal investigation showed that the lowest desorption temperature was achieved in samples with milling time of 5 and 10 hours, namely 287 °C and 288 °C. This study shows that natural silica catalyst plays a role in improving the thermodynamic characteristics of MgH2, while Ni plays a role in improving the kinetic characteristics of MgH2. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (


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Keywords: hydrogen storage material; planetary ball milling; natural silica; rice husk ash
Funding: Universitas Syiah Kuala

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  1. Barkhordarian, G., Klassen, T., Bormann, R. (2006). Catalytic mechanism of transition-metal compounds on Mg hydrogen sorption reaction. Journal of Physical Chemistry B, 110, 11020–11024. DOI: 10.1021/jp0541563
  2. Zhang, Q., Zang, L., Huang, Y., Gao, P., Jiao, L., Yuan, H., Wang, Y. (2017). Improved hydrogen storage properties of MgH2 with Ni-based compounds. International Journal of Hydrogen Energy, 42, 24247–24255. DOI: 10.1016/j.ijhydene.2017.07.220
  3. Khodaparast, V., Rajabi, M. (2015). Hydrogen Desorption Properties of MgH2-5 Wt% Ti-Mn-Cr Composite via Combined Melt Spinning and Mechanical Alloying. Procedia Materials Science, 11, 611–615. DOI: 10.1016/j.mspro.2015.11.092
  4. Milovanović, S., Matović, L., Drvendzija, M., Novaković, J.G. (2008). Hydrogen storage properties of MgH2-diatomite composites obtained by high-energy ball milling. Journal of Microscopy, 232(3), 522–525. DOI: 10.1111/j.1365-2818.2008.02113.x
  5. Yartis, V.A., Lototskyy, M.V., Akiba, E., Albert, R., Antonov, V.E., Ares, J.R., Baricco, M., Bourgeois, N., Buckley, C.E., Bolesta Von Colbe, J.M., Crivello, J.C., Cuevas, F., Denys, R.V., Dornheim, M., Felderhoff, M., Grant, D.M., Houback, B.C., Humpries, T.D., Jacob, I., Jensen, T.R., de Jongh, P.E., Joubert, J.M., Kuzovnokov, M.A., Latroche, M., Paskevicius, M., Pasquini, L., Popilevsky, L., Skripnyuk, V.M., Rabkin, E., Sofianos, M.V., Stuart, A., Walker, G., Wang, H., Webb, J.C., Zhu, M. (2019). Magnesium based materials for hydrogen based energy storage: Past, present and future. International Journal of Hydrogen Energy, 44, 7809–7859. DOI: 10.1016/j.ijhydene.2018.12.212
  6. Crivello, J.C., Denys, R. V., Dornheim, M., Felderhoff, M., Grant, D.M., Huot, J., Jensen, T.R., de Jongh, P., Latroche, M., Walker, G.S., Webb, C.J., Yartys, V.A., (2016). Mg-based compounds for hydrogen and energy storage. Applied Physics A: Materials Science and Processing, 122, 1–17. DOI: 10.1007/s00339-016-9601-1
  7. Aminorroaya, S., Ranjbar, A., Cho, Y.H., Liu, H.K., Dahle, A.K. (2011). Hydrogen storage properties of Mg-10 wt% Ni alloy co-catalysed with niobium and multi-walled carbon nanotubes. International Journal of Hydrogen Energy, 36, 571–579. DOI: 10.1016/j.ijhydene.2010.08.103
  8. Mustanir, M., Jalil, Z. (2009) Hydrogen Sorption Behavior of the MgH2-Ni Prepared by Reactive Mechanical Alloying. IPTEK The Journal for Technology and Science, 20(4), 133–135. DOI: 10.12962/j20882033.v20i4.19
  9. Khan, D., Zou, J., Zeng, X., Ding, W. (2018). Hydrogen storage properties of nanocrystalline Mg2Ni prepared from compressed 2MgH2–Ni powder. International Journal of Hydrogen Energy, 43, 22391–22400. DOI: 10.1016/j.ijhydene.2018.10.055
  10. Kwak, Y.J., Lee, S.H., Mumm, D.R., Song, M.Y. (2015). Development of a Mg-based hydrogen-storage material by addition of Ni and NbF5 via milling under hydrogen. International Journal of Hydrogen Energy, 40, 11908–11916. DOI: 10.1016/j.ijhydene.2015.04.111
  11. Jalil, Z., Rahwanto, A., Handoko, E., Mustanir, M. (2017). The role of nano-Ni catalyst in MgH2 obtained by reactive mechanical milling method for solid hydrogen storage application. AIP Conference Proceedings, 1826, 020002. DOI: 10.1063/1.4979218
  12. Ranjbar, A., Guo, Z.P., Yu, X.B., Attard, D., Calka, A., Liu, H.K. (2009). Effects of SiC nanoparticles with and without Ni on the hydrogen storage properties of MgH2. International Journal of Hydrogen Energy, 34, 7263–7268. DOI: 10.1016/j.ijhydene.2009.07.005
  13. Jalil, Z., Rahwanto, A., Malahayati, M., Mursal, M., Handoko, E., Akhyar, H. (2018). Hydrogen storage properties of mechanical milled MgH2-nano Ni for solid hydrogen storage material. IOP Conference Series: Materials Science and Engineering, 432, 012034. DOI: 10.1088/1757-899X/432/1/012034
  14. Jalil, Z., Rahwanto, A., Sofyan, H., Usman, M., Handoko, E. (2018). The use of Silica from beach sand as catalyst in Magnesium based hydrides for Hydrogen storage materials. IOP Conference Series: Earth and Environmental Science, 105, 012093. DOI: 10.1088/1755-1315/105/1/012093
  15. Jain, I.P., Lal, C., Jain, A. (2010). Hydrogen storage in Mg: A most promising material. International Journal of Hydrogen Energy, 35, 5133–5144. DOI: 10.1016/j.ijhydene.2009.08.088
  16. Niemann, M.U., Srinivasan, S.S., Phani, A.R., Kumar, A., Goswami, D.Y., Stefanakos, E.K. (2008). Nanomaterials for hydrogen storage applications: A review. Journal of Nanomaterials, 2008, 950967. DOI: 10.1155/2008/950967
  17. Wang, Y., Wang, Y. (2017). Recent advances in additive-enhanced magnesium hydride for hydrogen storage. Progress in Natural Science: Materials International, 27, 41–49. DOI: 10.1016/j.pnsc.2016.12.016
  18. Shao, H., He, L., Lin, H., Li, H.W. (2018). Progress and Trends in Magnesium-Based Materials for Energy-Storage Research: A Review. Energy Technology, 6, 445–458. DOI: 10.1002/ente.201700401
  19. Li, J., Li, B., Shao, H., Li, W., Lin, H. (2018). Catalysis and downsizing in Mg-based hydrogen storage materials. Catalysts, 8(2), 89. DOI: 10.3390/catal8020089
  20. Luo, Q., Li, J., Li, B., Liu, B., Shao, H., Li, Q. (2019). Kinetics in Mg-based hydrogen storage materials: Enhancement and mechanism. Journal of Magnesium and Alloys, 7, 58–71. DOI: 10.1016/j.jma.2018.12.001
  21. Sun, Z., Lu, X., Nyahuma, F.M., Yan, N., Xiao, J., Su, S., Zhang, L. (2020). Enhancing Hydrogen Storage Properties of MgH2 by Transition Metals and Carbon Materials: A Brief Review. Frontiers in Chemistry, 8, 1–14. DOI: 10.3389/fchem.2020.00552
  22. Chen, M., Xiao, X., Zhang, M., Liu, M., Huang, X., Zheng, J., Zhang, Y., Jiang, L., Chen, L. (2019). Excellent synergistic catalytic mechanism of in-situ formed nanosized Mg2Ni and multiple valence titanium for improved hydrogen desorption properties of magnesium hydride. International Journal of Hydrogen Energy, 44, 1750–1759. DOI: 10.1016/j.ijhydene.2018.11.118
  23. Rajabpour, F., Raygan, S., Abdizadeh, H. (2016). The synergistic effect of catalysts on hydrogen desorption properties of MgH2–TiO2–NiO nanocomposite. Materials for Renewable and Sustainable Energy, 5, 1–9. DOI: 10.1007/s40243-016-0084-y
  24. Rahwanto, A., Jalil, Z., Akhyar, A., Handoko, E. (2020). Desorption properties of mechanically milled MgH2 with double catalysts Ni and SiC. IOP Conference Series: Materials Science and Engineering, 931, 012012. DOI: 10.1088/1757-899X/931/1/012012
  25. Kou, H., Hou, X., Zhang, T., Hu, R., Li, J., Xue, X. (2013). On the amorphization behavior and hydrogenation performance of high-energy ball-milled Mg2Ni alloys. Materials Characterization, 80, 21–27. DOI: 10.1016/j.matchar.2013.03.009
  26. Patterson, A.L. (1939). The Scherrer Formula for X-Ray Particle Size Determination. Physical Review, 56(10), 978–982. DOI: 10.1103/PhysRev.56.978
  27. Patah, A., Takasaki, A., Szmyd, J.S. (2008). The effect of Cr2O3/ZnO on hydrogen desorption properties of MgH2. Materials Research Society Symposium Proceedings, 1148, 190–195. DOI: 10.13140/RG.2.1.4047.2802
  28. Malahayati, M., Ismail, I., Mursal, M., Jalil, Z. (2018). The use of silicon oxide extracted from rice husk ash as catalyst in magnesium hydrides (MgH2) prepared by mechanical alloying method. Journal of Physics: Conference Series, 1120, 012061. DOI: 10.1088/1742-6596/1120/1/012061

Last update: 2021-06-13 20:27:54

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Last update: 2021-06-13 20:27:54

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